Note: Ingredients listed on restricted chemical lists
EC/CAS
232-489-3/91-08-7
Name of the chemical
2,6-Diisocyanattoluol
Concentration
489-3
EC/CAS
202-039-0/584-84-9
Name of the chemical
2,4-Diisocyanattoluol
Concentration
039-0
General Information
Revision date
2010-12-01
Product name
Termination Caulk
Manufacturer Name
G Firestone Building Products Company
Icons in SDS
Company Information
company name
firestone building products
e-mail address of the competent person responsible for the Safety Data Sheet
genflexmsds@bfdp.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H227, H315, H317, H319, H332, H334, H351, H373
Hazard statements
Code
Statements
H227
Combustible liquid
Section 2
SECTION 2: Hazards identification
OSHA HCS 2012 EU/EEC According to Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD)
2.1 Classification of the substance or mixture
CLP G Skin Irritation 2 - H315 Skin Sensitization 1 - H317 Eye Irritation 2 - H319 Acute Toxicity Inhalation 4 - H332 Respiratory Sensitization 1 - H334 Carcinogenicity 2 - H351 DSD/DPD G Toxic (T) Irritant (Xi) Carcinogenic Substances - Category 3 R23, R36/37/38, R40, R42/43 OSHA HCS 2012 G Flammable Liquids 4 - H227 Skin Irritation 2 - H315 Caulk Skin Sensitization 1 - H317 Eye Irritation 2 - H319 Acute Toxicity Inhalation 4 - H332 Respiratory Sensitization 1 - H334 Carcinogenicity 2 - H351 Specific Target Organ Toxicity Repeated Exposure 2 - H373 Caulk WHMIS G Combustible Liquids - B3 Very Toxic - D1A Other Toxic Effects - D2A Other Toxic Effects - D2B
2.2 Label elements
CLP DANGER OSHA HCS 2012 DANGER WHMIS G Combustible Liquids - B3 Very Toxic - D1A Other Toxic Effects - D2A Other Toxic Effects - D2B
Hazard statements
G H315 - Causes skin irritation Caulk H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H332 - Harmful if inhaled H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H351 - Suspected of causing cancer. G R23 - Toxic by inhalation R36/37/38 - Irritating to eyes, respiratory system and skin. R42/43 - May cause sensitisation by inhalation and skin contact. R40 - Limited evidence of a carcinogenic effect. G Combustible liquid - H227 Causes skin irritation - H315 May cause an allergic skin reaction - H317 Causes serious eye irritation - H319 Harmful if inhaled - H332 May cause allergy or asthma symptoms or breathing difficulties if inhaled - H334 Suspected of causing cancer. - H351 May cause damage to organs - Liver/Kidneys through prolonged or repeated exposure - H373
Prevention
G P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood. P261 - Avoid breathing mist/vapours/spray. P264 - Wash thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P281 - Use personal protective equipment as required. P285 - In case of inadequate ventilation wear respiratory protection. G Obtain special instructions before use. - P201 Do not handle until all safety precautions have been read and understood. - P202 Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. - P210 Do not breathe mist/vapours/spray. - P260 Wash thoroughly after handling. - P264 Use only outdoors or in a well-ventilated area. - P271 Contaminated work clothing should not be allowed out of the workplace. - P272 Wear protective gloves/protective clothing/eye protection/face protection. - P280 In case of inadequate ventilation wear respiratory protection. - P285
Response
G P304+P341 - IF INHALED If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P362 - Take off contaminated clothing and wash before reuse. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P321 - Specific treatment, see supplemental first aid information. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P308+P313 - IF exposed or concerned: Get medical advice/attention. Storage/Disposal G P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. G In case of fire Use appropriate media for extinction. - P370+P378 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. - P304+P341 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. - P342+P311 If on skin: Wash with plenty of water . Take off contaminated clothing and wash before reuse. - P362 If skin irritation or rash occurs: Get medical advice/attention. - P333+P313 Specific treatment, see supplemental first aid information. - P321 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. - P305+P351+P338 If eye irritation persists: Get medical advice/attention. - P337+P313 IF exposed or concerned: Get medical advice/attention. - P308+P313 Get medical advice/attention if you feel unwell. - P314 Storage/Disposal G Store in a well-ventilated place. Keep cool. - P403+P235 Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. - P501
Additional information
G 11.5 percent of this product consists of an ingredient of unknown toxicity DSD/DPD G 12.55 percent of this product consists of an ingredient of unknown toxicity
Precautionary statements
G S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S37 - Wear suitable gloves. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S53 - Avoid exposure - obtain special instructions before use.
2.3 Other hazards
CLP G According to Regulation (EC) No. 1272/2008 (CLP) this material is considered hazardous. DSD/DPD G According to European Directive 1999/45/EC this material is considered dangerous. United States (US) According to OSHA 29 CFR 1910.1200 HCS WHMIS G In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS).
Other hazards
OSHA HCS 2012 G Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Canada According to WHMIS