Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
55% 38% 966-0 005-00-
General Information
Revision date
2012-01-06
Product name
I.S.O.Stick Insulation Adhesive Part 1
CAS No.
101-68-8
Manufacturer Name
Firestone Building Products Company
Icons in SDS
Company Information
company name
firestone building products
e-mail address of the competent person responsible for the Safety Data Sheet
firestonemsds@bfdp.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H331, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
OSHA HCS 2012 EU/EEC According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to: EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD)
2.1 Classification of the substance or mixture
CLP • Skin Irritation 2 - H315 Skin Sensitization 1 - H317 Eye Irritation 2 - H319 Acute Toxicity Inhalation 3 - H331 Respiratory Sensitization 1 - H334 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation - H335 Carcinogenicity 2 - H351 Specific Target Organ Toxicity Repeated Exposure 2 - H373 DSD/DPD • Harmful (Xn) Irritant (Xi) Carcinogenic Substances - Category 3 R20, R36/37/38, R40, R42/43, R48/20 OSHA HCS 2012 • Skin Irritation 2 Skin Sensitization 1A Eye Irritation 2 Acute Toxicity Inhalation 2 Respiratory Sensitization 1A Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation Specific Target Organ Toxicity Repeated Exposure 1 WHMIS • Very Toxic - D1A Other Toxic Effects - D2A Other Toxic Effects - D2B
2.2 Label elements
CLP DANGER OSHA HCS 2012 DANGER WHMIS • WHMIS • Very Toxic - D1A Other Toxic Effects - D2A Other Toxic Effects - D2B
Hazard statements
H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H331 - Toxic if inhaled H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 - May cause respiratory irritation H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. R20 - Harmful by inhalation R36/37/38 - Irritating to eyes, respiratory system and skin. R40 - Limited evidence of a carcinogenic effect. R42/43 - May cause sensitisation by inhalation and skin contact. R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation. Causes skin irritation May cause an allergic skin reaction Causes serious eye irritation Fatal if inhaled May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause respiratory irritation Causes damage to organs - Lungs through prolonged or repeated exposure
Prevention
P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe mist/vapours/spray. P264 - Wash thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P281 - Use personal protective equipment as required. P285 - In case of inadequate ventilation wear respiratory protection. Do not breathe mist/vapours/spray Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. In case of inadequate ventilation wear respiratory protection.
Response
P304+P341 - IF INHALED If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P311 - Call a POISON CENTER or doctor/physician. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P362 - Take off contaminated clothing and wash before reuse. P332+P313 - If skin irritation occurs: Get medical advice/attention. P321 - Specific treatment, see supplemental first aid information. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P308+P313 - IF exposed or concerned: Get medical advice/attention. P314 - Get medical advice/attention if you feel unwell. Storage/Disposal • P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. DSD/DPD IF INHALED If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Specific treatment is urgent (see supplemental first aid instructions on this label). If on skin: Wash with plenty of water. Take off contaminated clothing and wash before reuse. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment, see supplemental first aid information. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Get medical advice/attention if you feel unwell. Storage/Disposal • Store in a well-ventilated place. Keep container tightly closed. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.
Precautionary statements
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S37 - Wear suitable gloves. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S53 - Avoid exposure - obtain special instructions before use.
2.3 Other hazards
CLP • According to Regulation (EC) No. 1272/2008 (CLP) this material is considered hazardous. DSD/DPD • According to European Directive 1999/45/EC this material is considered dangerous. United States (US) According to: OSHA 29 CFR 1910.1200 HCS WHMIS • In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS).
Additional information
45.1 percent of this product consists of an ingredient of unknown toxicity
Other hazards
OSHA HCS 2012 • Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Canada According to: WHMIS