to identifier

SECTION 2: Hazards identification

Classification 1272/2008 were information modified: criteria for this hazard class Before CONTAMINATED handling the PACKAGING product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the Product Reg. 01 / 03. no. name 01-2120116875-52-XXXX 9078 BLACK environment. Contaminated Do packaging not eat, drink must or be smoke recovered during or use. disposed of in compliance with national waste management regulations. Information GERM CELL not MUTAGENICITY available LEGEND: 1.2. The Relevant 7.2. - ADR: Conditions full wording European identified for safe of hazard Agreement uses (H) of phrases

Storage

concerning the substance including the any is given or carriage in section incompatibilities mixture 16 and of Dangerous goods by Road of the uses sheet. advised against SECTION Does not meet - CAS NUMBER: 14. the Transport Chemical Abstract classification criteria information Service Number for this hazard class SECTION Intended use 10. Stability and reactivity Dye for foods, cosmetics and pharmaceuticals, subject to the regulations being in SECTION Keep - CE50: the Effective The product 4. product concentration is not First in clearly labelled dangerous aid measures under current provisions (required containers. to induce Keep a 50% containers effect) away from any incompatible materials, see section 10 for details. of International 10.1. - CE Reactivity CARCINOGENICITY NUMBER: Identifier in ESIS (European archive of existing substances) force of the in Code each country of use. Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. 4.1. 7.3. - CLP: Description Specific EC Regulation end of use(s)

2.1 Classification of the substance or mixture

normal conditions criteria for this hazard 20060 50% of use and storage. class protection Gessate (MI) 14.2. UN proper shipping name Italy Specific - IMDG: information Control International on Maritime parameters symptoms Code and for effects dangerous caused goods by the product are unknown. 8.1. STOT 10.3. - IMO: Possibility - SINGLE International of hazardous EXPOSURE Maritime Organization reactions Tel. +39 02-9592901 Not applicable Fax +39 02-95382688 4.3. - INDEX Indication the risk assessment NUMBER: of any Identifier immediate process, in Annex medical it is essential to take into consideration the ACGIH occupational exposure levels for inert particulate not VI of attention CLP and special treatment needed e-mail During address Does not meet the classification criteria for this hazard class of the competent person The - LC50: otherwise Transport powders Lethal are classified Concentration potentially explosive (PNOC class(es) respirable 50% when mixed with air. PNOC inhalable fraction: 10 mg/m3). For values above these limits, use a P type 14.3. responsible for hazard the Safety Data Sheet fraction: 3 mg/m3; sds@fioriocolori.com Information - LD50: Lethal filter, whose class (1, 2 or 3) must be chosen according to the outcome of risk assessment. not dose available 50% 10.4. - OEL: STOT - REPEATED EXPOSURE Conditions Occupational to avoid Exposure Level 1.4. Not Emergency applicable telephone number - PBT: Persistent bioaccumulative and toxic as REACH Regulation SECTION Does not meet 5. the Firefighting Avoid - PEC: environmental Predicted environmental classification criteria dust build-up. Concentration measures for this hazard class 8.2. 14.4. For Exposure Packing urgent inquiries group controls refer to NUE 112 5.1. Extinguishing media - PEL: Predicted exposure level 10.5. - PNEC: ASPIRATION HAZARD Incompatible Predicted materials no effect concentration Comply Not applicable with the safety measures usually applied when handling chemical substances. SECTION - REACH: EC SUITABLE HAND PROTECTION Does not meet the classification criteria for this hazard class EXTINGUISHING 2. Regulation Hazards 1907/2006 identification EQUIPMENT 14.5. The Information - RID: Regulation None Environmental extinguishing required. not available concerning the international transport of dangerous goods by train equipment hazards should be of the conventional kind: carbon dioxide, foam, powder and water spray. 2.1. - TLV: UNSUITABLE SKIN PROTECTION Classification Threshold of EXTINGUISHING EQUIPMENT Limit the Value substance or mixture 10.6. - TLV SECTION None Not applicable Hazardous in required. CEILING: decomposition particular. 12. Ecological information Concentration that products should not be exceeded during any time of occupational exposure. The - TWA product STEL: is Short-term not classified exposure as hazardous limit pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent EYE PROTECTION amendments Information Use - TWA: this Time-weighted product not and available according supplements). average to good exposure working limit practices. Avoid littering. Inform the competent authorities, should the product reach waterways or 5.2. 14.6. None Special required. hazards precautions arising for from user the substance or mixture contaminate - VOC: Volatile RESPIRATORY PROTECTION soil organic or vegetation. Compounds Hazard - vPvB: classification Very Persistent and and indication: very Bioaccumulative -- as for REACH Regulation SECTION 11. Toxicological information HAZARDS Use Not applicable a type CAUSED P filtering BY facemask, EXPOSURE whose IN class THE (1, EVENT 2 or 3) OF and FIRE effective need, must be defined according to the outcome of risk assessment 12.1. - WGK: Do (see not standard Toxicity breathe EN combustion Water hazard classes (German). 149). products. The product is combustible and, when the powder is released into the air in sufficient concentrations 14.7. and ENVIRONMENTAL According Transport in the presence to currently in bulk EXPOSURE of according available a source data, of CONTROLS to ignition, Annex this product it II can of Marpol create has not explosive and yet the produced IBC mixtures Code health with damages. air. Fires Anyway, may start it or must get be worse handled 2.2. Information by leakage product The industrial Label elements

UN Number

Not Information - EmS: specifically Emergency not necessary. available Schedule Observance of good industrial hygiene is recommended. Name REPRODUCTIVE TOXICITY Fiorio Colori SRL 10.2. - GHS: Chemical applicable Globally stability Harmonized System of classification and labeling of chemicals Full Not address Via Italia, 28 4.2. - IATA Most DGR: important International symptoms Air Transport and effects, Association both acute Dangerous and delayed Goods Regulation SECTION District Does not and meet The - IC50: product Immobilization Country 8. the Exposure is stable in Concentration classification controls/personal normal conditions criteria for this hazard 20060 50% of use and storage class protection Gessate MI) UN proper shipping name Italy Specific IMDG: information Control International on Maritime parameters symptoms Code and for effects dangerous caused goods by the product are unknown STOT IMO Possibility SINGLE International of hazardous EXPOSURE Maritime Organization reactions Tel 39 02-9592901 Not applicable Fax 39 02-95382688 INDEX Indication the risk assessment NUMBER of any Identifier immediate process, in Annex medical it is essential to take into consideration the ACGIH occupational exposure levels for inert particulate not VI of attention CLP and special treatment needed e-mail During address Does not meet the classification criteria for this hazard class of the competent person The LC50 otherwise Transport powders Lethal are classified Concentration potentially explosive PNOC class(es) respirable 50% when mixed with air PNOC inhalable fraction: 10 mg/m3). For values above these limits, use a P type responsible for hazard the Safety Data Sheet fraction: 3 mg/m3; sds@fioriocolori.com Information LD50: Lethal filter, whose class (1, 2 or 3) must be chosen according to the outcome of risk assessment not dose available 50% OEL STOT - REPEATED EXPOSURE Conditions Occupational to avoid Exposure Level Not Emergency applicable telephone number PBT: Persistent bioaccumulative and toxic as REACH Regulation SECTION Does not meet 5. the Firefighting Avoid PEC: environmental Predicted environmental classification criteria dust build-up Concentration measures for this hazard class 14.4. For Exposure Packing urgent inquiries group controls refer to NUE 112 Extinguishing media PEL: Predicted exposure level PNEC

Aspiration hazard

Incompatible Predicted materials no effect concentration Comply Not applicable with the safety measures usually applied when handling chemical substances SECTION REACH: EC SUITABLE HAND PROTECTION Does not meet the classification criteria for this hazard class EXTINGUISHING Regulation

2.2 Label elements

emissions according from practices. of the to solid not available the generated container, by when good manufacturing it reaches high processes, temperatures including or those through generated contact with by ventilation sources of equipment, ignition. should be checked to ensure GENERAL BIBLIOGRAPHY compliance Information with not relevant environmental standards.

Hazard pictograms

1. Regulation

Signal word

3. Regulation 15. (EU) Regulatory 790/2009 (I Atp. -- information CLP) of the European Parliament GENERAL Metabolism, INFORMATION toxicokinetics, mechanism of action and other information SECTION Information 4. Regulation not Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for 9. (EU) Physical available

Hazard statements

5. Regulation (EU) 286/2011 (II Atp. -- CLP) of the European Parliament 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture health. Information Always not wear available full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament contaminated water used for extinction and the remains of the fire according to applicable regulations. 9.1. 12.3. Precautionary 7. Information SPECIAL Information PROTECTIVE Regulation Bioaccumulative on likely routes EQUIPMENT (EU) on basic 487/2013 potential physical of exposure FOR FIRE-FIGHTERS (IV Atp. and -- CLP) chemical of the European properties Parliament Seveso Category - Directive 2012/18/EC: 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament None Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with Appearance Not available Information 9. Regulation not (EU) self-contained Information not open available 605/2014 (VI Atp. CLP) of the European Parliament circuit positive pressure compressed air breathing apparatus (BS EN 137). Colour Restrictions 10. Regulation relating (EU) 2015/1221 to the product (VII or Atp. contained CLP) of substances the European Not available pursuant Parliament

Contains

emergency available any SVHC procedures in percentage greater than 0,1%. Information not available SECTION Initial boiling 3. point Composition/information Not on applicable - The Merck Index. - 10th Edition ingredients Interactive effects Use Boiling Substances breathing range subject equipment to authorisation if fumes or (Annex powders XIV are REACH) released Not available into the air. These indications apply for both processing staff and those involved in 3.2. - Handling Mixtures Chemical Safety 12.5. - INRS emergency Flash None point procedures. Results - Fiche of PBT Toxicologique and vPvB (toxicological assessment sheet) Not applicable Information not available Evaporation Rate Not available - Patty - Industrial Hygiene and Toxicology 6.2. Flammability Substances On - N.I. the Sax basis Environmental - Dangerous subject of available properties of solids

Precautionary statements

to and exportation data, the of product gases reporting pursuant Not Industrial does Materials-7, not contain 1989 to (EC) available any Edition Reg. 649/2012: PBT or vPvB in percentage greater than 0,1%. ACUTE TOXICITY Lower None inflammability limit Not available Identification - IFA GESTIS website x = Conc. %