- CLP: EC Regulation 1272/2008

Fiorio Colori SRL

Revision date : 2018-05-29

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Health risk rating 1
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

223-339-8/3844-45-9

Name of the chemical

Benzenemethanaminium, N-ethyl-N-[4-[[4-[ethyl-[(3-sulfophenyl)-methyl]-amino]-phenyl](2-sulfophenyl)methylene]-2,5-cyclohexadien-1-ylidene]-3-sulfo, inner salts, disodium salt and its ammonium and aluminium salts (17); (CI 42090)

Concentration

5-9

General Information

Revision date

2018-05-29

Product name

- CLP: EC Regulation 1272/2008

Chemical name

Partition coefficient: n-octanol/water

CAS No.

3844-45-9

REACH No

01-2120740569-45-XXXX

Emergency telephone

14.4. Packing group

Icons in SDS

Company Information

company name

Fiorio Colori SRL

e-mail address of the competent person responsible for the Safety Data Sheet

sds@fioriocolori.com

GHS Information

Signal word

GENERAL

Section 2

SECTION 2: Hazards identification

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. - PEC: Predicted environmental Concentration UNSUITABLE EXTINGUISHING EQUIPMENT TLV of solvent mixture: 10 mg/m3 - PEL: Predicted exposure level None in particular. Not applicable

2.1 Classification of the substance or mixture

Does not meet the classification criteria for this hazard class Avoid environmental dust build-up. - PNEC: Predicted no effect concentration 5.2. Special hazards arising from the substance or mixture 8.2. Exposure controls 14.6. Special precautions for user - REACH: EC Regulation 1907/2006 10.5. Incompatible materials The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent - RID: Regulation concerning the international transport of dangerous goods by train The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent

ECOLOGICAL INFORMATION

amendments and supplements). - TLV: Threshold Limit Value amendments and supplements). HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Comply with the safety measures usually applied when handling chemical substances. Not applicable Information not available Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. Do not breathe combustion products. The product is combustible and, when the powder is released into the air in sufficient concentrations HAND PROTECTION Hazard classification and indication: contaminate soil or vegetation. - TWA STEL: Short-term exposure limit Hazard classification and indication: -- 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code and in the presence of a source of ignition, it can create explosive mixtures with air. Fires may start or get worse by leakage of the solid None required. 10.6. Hazardous decomposition products - TWA: Time-weighted average exposure limit product from the container, when it reaches high temperatures or through contact with sources of ignition. SKIN PROTECTION 12.1. Toxicity - VOC: Volatile organic Compounds None required. Information not relevant

2.2 Label elements

Information not available

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation 5.3. Advice for firefighters EYE PROTECTION Information not available - WGK: Water hazard classes (German). None required. SECTION 15. Regulatory information

TOXICOLOGICAL INFORMATION

GENERAL INFORMATION RESPIRATORY PROTECTION Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for Use a type P filtering facemask, whose class (1, 2 or 3) and effective need, must be defined according to the outcome of risk assessment 12.2. Persistence and degradability

Signal word

GENERAL BIBLIOGRAPHY -- health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of (see standard EN 149). A.D.I = 6 mg/kg b.w. Toxic Substance Control Act (TSCA). 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament contaminated water used for extinction and the remains of the fire according to applicable regulations. ENVIRONMENTAL EXPOSURE CONTROLS

Hazard statements

Information not available 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament -- 11.1. Information on toxicological effects 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with compliance with environmental standards.

Precautionary statements

4. Regulation (EU) 2015/830 of the European Parliament -- self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). Metabolism, toxicokinetics, mechanism of action and other information Seveso Category - Directive 2012/18/EC: None 12.3. Bioaccumulative potential 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament SECTION 9. Physical and chemical properties 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament Information not available SECTION 6. Accidental release measures This product is not subject to hazard labeling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 Information not available 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament This product is not subject to hazard labeling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. None 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament 6.1. Personal precautions, protective equipment and emergency procedures 9.1. Information on basic physical and chemical properties Information on likely routes of exposure

2.3 Other hazards

9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament 12.4. Mobility in soil Substances in Candidate List (Art. 59 REACH) 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament Information not available On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. If there are no contraindications, spray powder with water to prevent the formation of dust. Appearance On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. powder or granular Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent Colour Information not available 12. Regulation (EU) 2016/1179 (IX Atp. CLP) blue

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