Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
26447-40-5
Name of the chemical
Methylenediphenyl diisocyanate (see also specific isomers)
Concentration
<10
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
<55
General Information
Revision date
2014-03-20
Product name
Liquid Foam, A-Side
1.2.1 Relevant identified uses
Isocyante side of 2 part Polyurethane foam prodcuts
Manufacturer Name
Fiberglass Coatings Inc
Emergency telephone
(800) 255-3924
Icons in SDS
Company Information
company name
Fiberglass Coatings Inc
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
2.1 Classification of the substance or mixture
Health: Acute Toxicity (Inhalation), Category 4 Eye Irritation, Category 2 Skin Irritation, Category 2 Respiratory Sensitization, Category 1 Target Organ Toxicity (Repeated exposure), Category 2 Carcinogenicity, Category 2 Skin Sensitization, Category 1 Target Organ Toxicity (Single exposure), Category 3
2.2 Label elements
Exclamation
Health hazards
mark
Signal word
DANGER
Hazard statements
H332: Harmful if inhaled. H319: Causes serious eye irritation. H315: Causes skin irritation. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H373: May cause damage to organs through prolonged or repeated exposure. H317: May cause an allergic skin reaction. Page 2 of 7 H335: May cause respiratory irritation. H351: Suspected of causing cancer.
Prevention
P271: Use only outdoors or in a well-ventilated area. P260: Do not breathe fumes. P284: Wear respiratory protection. P280: Wear protective gloves, protective clothing, eye protection and face protection. P264: Wash skin thoroughly after handling.
Response
P312: Call a POISON CENTER or physician if you feel unwell. P304+P340 IF INHALED Remove to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice P302+P352 IF ON SKIN Wash with plenty of soap and water P332+P313 If skin irritation occurs Get medical attention P362: Take off contaminated clothing and wash before reuse. P321 Specific treatment (see Section 4 First Aid)
Disposal
P501: Dispose of container and its contents in accordance with all Federal, State, and local regulations. EMERGENCY OVERVIEW PHYSICAL APPEARANCE: Liquid, Brown, faint aromatic odor. IMMEDIATE CONCERNS: CONTAINS DIPHENYLMETHANE DIISOCYANATE (MDI) CAS No. 101-68-8. INHALATION OF MDI MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. AVOID CONTACT WITH SKIN AND EYES. SKIN OR EYE CONTACT MAY CAUSE IRRITATION. SKIN CONTACT WITH MDI MAY CAUSE RESPIRATORY SENSITIZATION.
Potential health effects
EYES: Causes eye irritation. SKIN: Irritating to the skin. INGESTION: Harmful if swallowed. May cause nausea and vomiting. INHALATION: Inhalation can cause dizziness, drowsiness, headache, nausea, and irritation of nose, throat and respiratory tract. Can also cause respiratory sensitization. CARCINOGENICITY: This mixture is not listed as a carcinogen, however, some of the components may be suspected to cause cancer in humans.
Medical Conditions Generally Aggravated by Exposure
The isocyanate component is a respiratory sensitizer. It may cause allergic reaction leading to asthma-like spasms of the bronchial tubes and difficulty in breathing. Contact may aggravate pulmonary disorders.
Principle Routes of Exposure
Inhalation, ingestion, skin and eye contact TARGET ORGAN STATEMENT: Skin, Lungs. Page 3 of 7 IRRITANCY: Irritating to eyes, respiratory system and skin. SENSITIZATION: The substance may cause sensitization of the respiratory tract. Sensitization after skin contact possible.