Solution of [D-Asp3]Microcystin LR

Hazard statements (CLP)

H225, H301, H311, H319, H331, H361, H370, H371, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

US OSHA 1910.1200 Overview The product Solution of [D-Asp3]Microcystin LR is a small quantity of a toxin of interest, dissolved in solvent Methanol. The toxin is present in the solution in so small concentration that it does not represent any considerable health hazard. The main source of hazards of Solution of [D-Asp3]Microcystin LR is the solvent Methanol. Classification of the Mixture/Solution

Hazard pictograms

{ None} Signal word:{Danger}

Hazard statements

H225 Highly flammable liquid and vapour. H301 Toxic if swallowed H311 Toxic in contact with skin H331 Toxic if inhalled H361 May damage fertility or the unborn child H319 Causes serious eye irritation H412 Harmful to aquatic life with long lasting effects H370 Causes damage to organs through single exposure

Precautionary statements

P203 Obtain, read and follow all safety instructions before use. P261 Avoid breathing dust or mist. P264 Wash {hands} thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection

Response

H225: P303+P361+P353 IF ON SKIN (or hair) Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower] P370+P378 In case of fire Use a dry chemical fire extinguisher... to extinguish. P301+P316 IF SWALLOWED Get emergency medical help immediately H301: P330: Rinse mouth. P302+P352 IF ON SKIN wash with plenty of water/P316 H311: P361+P364: Take off immediately all contaminated clothing and wash it before reuse. P304+P340 IF INHALED Remove person to fresh air and keep H331: comfortable for breathing. P316: Get emergency medical help immediately. H361: P318: if exposed or concerned, get medical advice. P305+P351+P338 P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses if present and easy H319: to do - continue rinsing. P337+P317 If eye irritation persists Get medical help H412: P273: Avoid release to the environment. P308+P316 IF exposed or concerned Get emergency medical help H370: immediately.

2.3 Other hazards

Nanforms: Not nanoform Endocrine disrupt. properties Pure Methanol is not considered an endocrine disruptor. [D-Asp3] Microcystin LR is present in negligible concentration and need not be reported

2.1 Classification of the substance or mixture

Flammable liquids (Category 2) Acute toxicity, Inhalation (Category 4) Acute toxicity, Dermal (Category 4) Acute toxicity, Oral (Category 4) Eye irritation (Category 2) Data source:<RTECS>RTECS; <Fer>Manufacturer’s estimation; <SF>Sci finder; <SDS>other authors; <J>Scientific publication; <PC>PubChem Flammable liquids Cat.2 H225 Highly flammable liquid and vapour. Accute toxicity: Oral Cat.3 H301 Toxic if swallowed Accute toxicity: Dermal Cat.3 H311 Toxic in contact with skin Serious eye damage/eye irritation Cat.2A H319 Causes serious eye irritation Accute toxicity: Inhalation Cat.1 H331 Toxic if inhalled Reproductive toxicity Cat.1B H361 May damage fertility or the unborn child STOT/se Eyes, Optic nerve, CNS, Gastrointestinal Tract, May cause damage to organs through single Cardiopulmonary System, Cat.1 H371 exposure Pancreas, Kidneys, Liver Chronic Aquatic Hazard Cat.3 H412 Harmful to aquatic life with long lasting effects 2.2. GHS Label elements, including precautionary statements