Free All

Hazard statements (CLP)

H226, H304, H332, H336, H351

Code

Statements

H226

Flammable liquid and vapour

2.2 Label elements

GHS-CA labelling

Signal word

Danger

Hazard statements

H226 - Flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways H332 - Harmful if inhaled H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer

Precautionary statements

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor P331 - Do NOT induce vomiting P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P308+P313 - IF exposed or concerned: Get medical advice/attention P403+P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation

2.3 Other hazards

No additional information available

Ingredient(s) with unknown acute toxicity

72% of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Dust/Mist)) 02/29/2024 EN (English) Page 1 3.1. Substances Not applicable 3.2. Mixtures Name

Product definition

% Distillates, petroleum, hydrotreated heavy naphthenic (CAS-No.) 64742-52-5 35 2-Pentanone, 4-methyl- (CAS-No.) 108-10-1 24 Petroleum distillates, hydrotreated light (CAS-No.) 64742-47-8 15 4.1. Description of first aid measures First-aid measures after inhalation IF INHALED: Remove person to fresh air and keep comfortable for breathing. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact If skin irritation occurs: Wash skin with plenty of water. Take off contaminated clothing and wash it before reuse. Obtain medical attention if irritation persists. First-aid measures after eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion IF SWALLOWED: immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after inhalation Harmful if inhaled. May cause irritation to the respiratory tract. May cause drowsiness or dizziness. Symptoms/effects after skin contact May cause skin irritation. Repeated exposure may cause skin dryness or cracking. Symptoms/effects after eye contact May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/effects after ingestion May be fatal if swallowed and enters airways. May result in aspiration into the lungs, causing chemical pneumonia. May cause gastrointestinal irritation, nausea, vomiting and diarrhea. 4.3. Immediate medical attention and special treatment, if necessary Other medical advice or treatment Symptoms may be delayed. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 5.1. Suitable extinguishing media Suitable extinguishing media Dry chemical. Carbon dioxide. Halons. Foam. Cool closed containers exposed to fire with water spray. Halon may decompose into toxic materials and carbon dioxide will displace oxygen, take proper precautions when using these materials. 5.2. Unsuitable extinguishing media Unsuitable extinguishing media None known. 5.3. Specific hazards arising from the hazardous product Fire hazard Products of combustion may include, and are not limited to: oxides of carbon. Could be ignited by heat sparks or flame. Vapours are heavier than air. Explosion hazard Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. 5.4. Special protective equipment and precautions for fire-fighters Protection during firefighting Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Prevent unauthorised access. 6.1. Personal precautions, protective equipment and emergency procedures General measures Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate every possible source of ignition. Use only non-sparking tools. Use special care to avoid static electric charges. 6.2. Methods and materials for containment and cleaning up For containment Absorb and/or contain spill with inert material (sand, vermiculite or other appropriate material), then place in suitable container. Wear recommended personal protective equipment. Do not flush into surface water or sewer system. Avoid dispersal or spilled material and runoff and contact with soil, waterways, drains and sewers. 02/29/2024 EN (English) 2/6 Methods for cleaning up Sweep or shovel spills into appropriate container for disposal. Clean up small spills by using a nonflammable absorbent or flushing sparingly with water. Contain larger spills with nonflammable diking or absorbent. 6.3. Reference to other sections For further information refer to section 8: "Exposure controls/personal protection" 7.1. Precautions for safe handling Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid contact with skin, eyes and clothing. Use only outdoors or in a well-ventilated area. Always open containers slowly to allow any excess pressure to vent. Hygiene measures Wash contaminated clothing before reuse. Always wash hands after handling the product. Additional hazards when processed Keep away from sources of ignition - No smoking. Hazardous waste due to potential risk of explosion. Do not spray on an open flame or other ignition source. Empty containers or liners may retain some product residue. 7.2. Conditions for safe storage, including any incompatibilities Technical measures Proper grounding procedures to avoid static electricity should be followed. Storage conditions Keep out of the reach of children. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. Keep in fireproof place. Keep away from incompatible materials. Incompatible materials Heat sources. 8.1. Control parameters 2-Pentanone, 4-methyl- (108-10-1) USA - ACGIH ACGIH TWA (ppm) 20 ppm USA - ACGIH ACGIH STEL (ppm) 75 ppm 8.2. Appropriate engineering controls Appropriate engineering controls Ensure good ventilation of the work station. Local exhaust and general ventilation must be adequate to meet exposure standards. Environmental exposure controls Avoid release to the environment. 8.3. Individual protection measures/Personal protective equipment Hand protection: Wear suitable gloves Eye protection: Safety glasses or goggles are recommended when using product. Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Further information

Handle in accordance with good industrial hygiene and safety procedures. Do not eat, drink or smoke when using this product. Provide readily accessible eye wash stations and safety showers. 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance Clear, mist Colour No data available Odour No data available Odour threshold No data available pH No data available 02/29/2024 EN (English) 3/6 Relative evaporation rate (butylacetate=1) No data available Relative evaporation rate (ether=1) Slower than Ether. Melting point No data available Freezing point No data available Boiling point Not available Flash point No data available Auto-ignition temperature No data available Decomposition temperature No data available Flammability (solid, gas) Flammable liquid Vapour pressure No data available Vapour pressure at 50 °C No data available Relative vapour density at 20 °C > 1 (Air=1) Relative density < 1 Solubility Water: Negligible. Partition coefficient n-octanol/water No data available Viscosity, kinematic No data available Explosive limits No data available VOC content 24 % SECTION 10: Stability and reactivity 10.1. Reactivity Reactivity No dangerous reactions known under normal conditions of use. Chemical stability Stable under normal conditions. Container may explode if heated. Do not puncture. Do not burn. Extreme risk of explosion by shock, friction, fire or other sources of ignition. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. Conditions to avoid Heat. Incompatible materials. Sparks. Open flame. Direct sunlight. Incompatible materials Strong oxidizing agents. Hazardous decomposition products May include, and are not limited to: oxides of carbon. hydrocarbons. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity (oral) Not classified. Acute toxicity (dermal) Not classified. Acute toxicity (inhalation) Harmful if inhaled. ATE CA (gases) 4500 ppmv/4h ATE CA (vapours) 11 mg/l/4h ATE CA (dust,mist) 1.5 mg/l/4h Unknown acute toxicity (GHS-CA) 72% of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Dust/Mist)) Distillates, petroleum, hydrotreated heavy naphthenic ( 64742-52-5) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg 2-Pentanone, 4-methyl- ( 108-10-1) LD50 oral rat 2080 mg/kg LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat 8.2 mg/l/4h Petroleum distillates, hydrotreated light ( 64742-47-8) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5.2 mg/l/4h Skin corrosion/irritation Not classified. Serious eye damage/irritation Not classified. Respiratory or skin sensitization Not classified. Germ cell mutagenicity Not classified. 02/29/2024 EN (English) 4/6 Carcinogenicity Suspected of causing cancer. Reproductive toxicity Not classified. STOT-single exposure May cause drowsiness or dizziness. STOT-repeated exposure Not classified. Aspiration hazard May be fatal if swallowed and enters airways. Free All Vaporizer Liquid Symptoms/effects after inhalation Harmful if inhaled. May cause irritation to the respiratory tract. May cause drowsiness or dizziness. Symptoms/effects after skin contact May cause skin irritation. Repeated exposure may cause skin dryness or cracking. Symptoms/effects after eye contact May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/effects after ingestion May be fatal if swallowed and enters airways. May result in aspiration into the lungs, causing chemical pneumonia. May cause gastrointestinal irritation, nausea, vomiting and diarrhea. Other information Likely routes of exposure: ingestion, inhalation, skin and eye. 12.1. Toxicity Ecology - general May cause long-term adverse effects in the aquatic environment. Distillates, petroleum, hydrotreated heavy naphthenic ( 64742-52-5) LC50 fish 1 5000 mg/l (Exposure time 96 h - Species Oncorhynchus mykiss) EC50 Daphnia 1 1000 mg/l (Exposure time 48 h - Species Daphnia magna) 2-Pentanone, 4-methyl- ( 108-10-1) LC50 fish 1 496 - 514 mg/l (Exposure time 96 h - Species Pimephales promelas [flow-through]) EC50 Daphnia 1 170 mg/l (Exposure time 48 h - Species Daphnia magna) Petroleum distillates, hydrotreated light ( 64742-47-8) LC50 fish 1 45 mg/l (Exposure time 96 h - Species Pimephales promelas [flow-through]) LC50 fish 2 mg/l (Exposure time 96 h - Species Lepomis macrochirus [static]) 12.2. Persistence and degradability Free All Persistence and degradability Readily biodegradable. 12.3. Bioaccumulative potential Free All Bioaccumulative potential Not established. 2-Pentanone, 4-methyl- ( 108-10-1) Partition coefficient n-octanol/water 1.19 Petroleum distillates, hydrotreated light (64742-47-8) BCF fish 1 61 - 159 12.4. Mobility in soil 2-Pentanone, 4-methyl- (108-10-1)

2.1 Classification of the substance or mixture

Flam. Liq. 3 H226 Asp. Tox. 1 H304 Acute Tox. 4 (Inhalation) H332 STOT SE 3 H336 Carc. 2 H351