Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
20-40%
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
10-20%
EC/CAS
13674-84-5
Name of the chemical
Tris(2-chloro-1-methylethyl) phosphate
Concentration
5-10%
EC/CAS
237-159-2/13674-87-8
Name of the chemical
Tris(1,3-dichloro-isopropyl)phosphate (TDCP)
Concentration
5-10%
General Information
Revision date
2016-01-01
Product name
Gasoila EFS Expanding Foam
1.2.2. Uses advised against
No further relevant information available
supplier name
Federal Process Corporation
Emergency telephone
(800) 424-9300, (703) 527-3887
Icons in SDS
Company Information
company name
Federal Process Corporation
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H223, H229, H315, H317, H319, H334, H335, H351, H373, H412
Hazard statements
Code
Statements
H223
Flammable aerosol
Section 2
SECTION 2: Hazards identification
NFPA Rating Classification of the substance or mixture
Health hazards
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Carc. 2 H351 Suspected of causing cancer STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure Skin Irrit. 2 H315 Causes skin irritation Eye Irrit. 2 H319 Causes serious eye irritation Skin Sens. 1 H317 May cause an allergic skin reaction STOT SE 3 H335 May cause respiratory irritation Contd. on page 2) 14 Contd. of page 1) Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xn; Harmful R40-20 Limited evidence of a carcinogenic effect. Harmful by inhalation Xn; Sensitising R42/43 May cause sensitisation by inhalation and skin contact Xi; Irritant R36/37/38 Irritating to eyes, respiratory system and skin F+; Extremely flammable R12 Extremely flammable R52/53 Harmful to aquatic organisms may cause long-term adverse effects in the aquatic environment. Information concerning particular hazards for human and environment The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version Warning! Pressurised container Classification system The classification is according to the latest editions of the EU-lists, and extended by company and literature data The classification is in accordance with the latest editions of international substances lists, and is supplemented by information from technical literature and by information provided by the company
Hazard pictograms
GHS02 GHS07 GHS08
Signal word
Danger
Hazardous Ingredients
diphenylmethanediisocyanate, isomers and homologues tris[2-chloro-1-(chloromethyl)ethyl] phosphate 4,4'-methylenediphenyl diisocyanate
Hazard statements
The following Hazard Statements are applicable only to the EU regulations and not the US GHS regulation: H412. H223-H229 Flammable aerosol. Pressurised container: May burst if heated. H315 Causes skin irritation. (Contd. on page 3) 14 (Contd. of page 2) H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. · WHMIS-symbols: A - Compressed gas B5 - Flammable aerosol D2A - Very toxic material causing other toxic effects · NFPA ratings (scale 0 - 4) Health = 2 4 Fire = 4 2 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH *2 Health = *2 4 Fire = 4 FIRE REACTIVITY 0 Reactivity = 0 * - Indicates a long term health hazard from repeated or prolonged exposures. · HMIS Long Term Health Hazard Substances 9016-87-9 diphenylmethanediisocyanate, isomers and homologues 101-68-8 4,4'-methylenediphenyl diisocyanate
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P251 Pressurized container: Do not pierce or burn, even after use. P260 Do not breathe mist/vapours/spray. P211 Do not spray on an open flame or other ignition source. P281 Use personal protective equipment as required. P314 Get medical advice/attention if you feel unwell. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Additional information
Contains isocyanates. May produce an allergic reaction. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use.
PBT Substances
Not applicable (Contd. on page 4) 40.0 (Contd. of page 3)
vPvB Substances
Not applicable
2.1 Classification of the substance or mixture
Classifications listed also are applicable to the OSHA GHS Hazard Communication Standard (29CFR1910.1200). The following Hazard Statements are applicable only to the EU regulations and not the US GHS regulation: H412. flame Flam. Aerosol 2 H223-H229 Flammable aerosol. Pressurised container: May burst if heated. health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation. (Contd. on page 2) 14 (Contd. of page 1) Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xn; Harmful R40-20: Limited evidence of a carcinogenic effect. Harmful by inhalation. Xn; Sensitising R42/43: May cause sensitisation by inhalation and skin contact. Xi; Irritant R36/37/38: Irritating to eyes, respiratory system and skin. F+; Extremely flammable R12: Extremely flammable. R52/53: Harmful to aquatic organisms may cause long-term adverse effects in the aquatic environment. · Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Warning! Pressurised container. · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. The classification is in accordance with the latest editions of international substances lists, and is supplemented by information from technical literature and by information provided by the company. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the Globally Harmonized System within the United States (GHS). The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS02 GHS07 GHS08 · Signal word Danger · Hazard-determining components of labelling: diphenylmethanediisocyanate, isomers and homologues