ABEX 3027-108

SECTION 2: Hazards identification

Physical hazards

Not classified

Health hazards

Not classified

Hazard pictograms

None.

Signal word

None.

Hazard statements

Exempt (manufactured article).

Prevention

Observe good industrial hygiene practices.

Response

No specific first aid measures noted.

Storage

Store away from heat.

Disposal

Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise None known. classified (HNOC)

Additional information

None.

2.1 Classification of the substance or mixture

Not classified. OSHA defined hazards Not classified. Label elements Hazard symbol None. Signal word None. Hazard statement Exempt (manufactured article). Precautionary statement Prevention Observe good industrial hygiene practices. Response No specific first aid measures noted. Storage Store away from heat. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information None. 3. Composition/information on ingredients Mixtures Chemical name CAS number % Barium sulphate 1121-43-7 10-30 Glass Fiber 65997-17-3 10 - 30 Engineered mineral fibre 287922-11-6 8-15 Magnesium oxide 1309-48-4 7-13 Copper 7440-50-8 1-5 Zinc 7440-66-6 1-5 ABEX 3027-108 SDS US 941178 Version #: 01 Revision date:- Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. This product contains a variety of ingredients all of which have become part of a bound system both physically and chemically and do not necessarily exhibit the properties of the individual components. The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. 4. First-aid measures Inhalation Move injured person into fresh air and keep person calm under observation. If necessary, seek hospital and take along these instructions. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation develops and persists. Eye contact Dust in the eyes: Flush thoroughly with water for at least 15 minutes. Make sure to remove any contact lenses from the eyes before rinsing. Get medical attention if irritation develops and persists. Ingestion If swallowed, rinse mouth with water (only if the person is conscious). Get medical attention if any discomfort continues. Most important Exposed individuals may experience eye tearing, redness, and discomfort. symptoms/effects, acute and delayed Indication of immediate Treat symptomatically. medical attention and special treatment needed General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing None. media Specific hazards arising from By heating and fire, toxic vapors/gases may be formed. the chemical Special protective equipment Selection of respiratory protection for firefighting: follow the general fire precautions indicated in and precautions for firefighters the workplace. Fire fighting Use standard firefighting procedures and consider the hazards of other involved materials. equipment/instructions General fire hazards This product is not flammable. 6. Accidental release measures Personal precautions, Use explosion-proof electrical equipment if airborne dust levels are high. Avoid dust formation. protective equipment and Avoid inhalation of dust and contact with skin and eyes. Wear necessary protective equipment. emergency procedures See Section 8 of the SDS for Personal Protective Equipment. Methods and materials for In the event of a spill or accidental release, notify relevant authorities in accordance with all containment and cleaning up applicable regulations. Collect powder using special dust vacuum cleaner with particle filter or carefully sweep into closed container. Do not vacuum clean unless vacuum cleaners are equipped with HEPA filter. Environmental precautions Avoid discharge into drains, water courses or onto the ground. Collect and dispose of spillage as indicated in Section 13 of the SDS. 7. Handling and storage Precautions for safe handling Provide adequate ventilation. Avoid dust formation. Avoid inhalation of dust and contact with skin and eyes. Use work methods which minimize dust production. See Section 8 of the SDS for Personal Protective Equipment. Observe good industrial hygiene practices. Conditions for safe storage, Store in tightly closed original container. Avoid conditions which create dust. Store away from heat. including any incompatibilities ABEX 3027-108 SDS US 941178 Version #: 01 Revision date: - 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Form Barium sulphate (CAS PEL 5 mg/m3 Respirable fraction. 7727-43-7) 15 mg/m3 Total dust. Copper (CAS 7440-50-8) PEL 1 mg/m3 Dust and mist. 0.1 mg/m3 Fume. Magnesium oxide (CAS PEL 15 mg/m3 Total particulate. 1309-48-4) US. OSHA Table Z-3 (29 CFR 1910.1000) Components Type Value Form Barium sulphate (CAS TWA 5 mg/m3 Respirable fraction. 7727-43-7) 15 mg/m3 Total dust. 50 mppcf Total dust. 15 mppcf Respirable fraction. Magnesium oxide (CAS TWA 5 mg/m3 Respirable fraction. 1309-48-4) 15 mg/m3 Total dust. 50 mppcf Total dust. 15 mppcf Respirable fraction. US. ACGIH Threshold Limit Values Components Type Value Form Barium sulphate (CAS TWA 5 mg/m3 Inhalable fraction. 7727-43-7) Copper (CAS 7440-50-8) TWA 1 mg/m3 Dust and mist. 0.2 mg/m3 Fume. Glass Fiber (CAS TWA 1 fibers/cm3 Fiber. 65997-17-3) Magnesium oxide (CAS TWA 10 mg/m3 Inhalable fraction. 1309-48-4) US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form Barium sulphate (CAS TWA 5 mg/m3 Respirable. 7727-43-7) 10 mg/m3 Total Copper (CAS 7440-50-8) TWA 1 mg/m3 Dust and mist. 0.1 mg/m3 Fume. Glass Fiber (CAS TWA 3 fibers/cm3 Fibrous dust. 65997-17-3) 3 fibers/cm3 Fiber. 5 mg/m3 Fiber, total 5 mg/m3 fibers, total dust Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Use explosion-proof electrical equipment if airborne dust levels are high. Provide adequate controls ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of dust. Individual protection measures, such as personal protective equipment Eye/face protection Wear approved safety goggles. Skin protection Hand protection Wear protective gloves (i.e. latex, nitrile). Suitable gloves can be recommended by the glove supplier. Other Wear suitable protective clothing. ABEX 3027-108 SDS US 941178 Version#:01 Revisiondate:- Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. During dust-raising work: In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA 29 CFR 1910.134. Respirator type: Any powered, air-purifying respirator with a high-efficiency particulate filter. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Solid (article). Physical state Solid. Form Solid. Color Gray. Odor None. Odor threshold Not applicable. pH Not applicable. Melting point/freezing point Not applicable. Initial boiling point and boiling Not applicable. range Flash point Not applicable. Evaporation rate Not applicable. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Not applicable. (%) Flammability limit - upper Not applicable. (%) Vapor pressure Not applicable. Vapor density Not applicable. Relative density 1.5 - 3 (20 °C) Solubility(ies) Solubility (water) Not applicable. Partition coefficient Not applicable. (n-octanol/water) Auto-ignition temperature Not applicable. Decomposition temperature Not available. Viscosity Not applicable. Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. 10. Stability and reactivity Reactivity The product is stable and non reactive under normal conditions of storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Will not occur. reactions Conditions to avoid None known. Incompatible materials None known. Hazardous decomposition Carbon dioxide. Carbon monoxide. Metallic fumes. Zinc oxides. products ABEX 3027-108 SDS US 941178 Version#:01 Revisiondate:- 11. Toxicological information Information on likely routes of exposure Inhalation Dust may irritate respiratory system. Inhalation of powder or fumes may cause metal fume fever. Inhalation may lead to deposition in lung and in sufficient quantities produce baritosis. Skin contact Dust may irritate skin. Eye contact Dust may irritate the eyes. Ingestion May cause discomfort if swallowed. Symptoms related to the Exposed individuals may experience eye tearing, redness, and discomfort. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. Dust may cause eye, skin and respiratory tract irritation. Components Species Test Results Barium sulphate (CAS 7727-43-7) Acute Oral LD50 Rat 307 g/kg Copper (CAS 7440-50-8) Acute Inhalation LC50 Rat > 2.77 mg/l, 4 hours Oral LD50 Rat 481 mg/kg Magnesium oxide (CAS 1309-48-4) Acute Oral LD50 Rat 3870 - 3990 mg/kg Zinc (CAS 7440-66-6) Acute Inhalation LC50 Rat > 5410 mg/m3 Skin corrosion/irritation Dust may irritate skin. Serious eye damage/eye Dust may irritate the eyes. irritation Respiratory or skin sensitization Respiratory sensitization No data available. Skin sensitization Not a skin sensitizer. Germ cell mutagenicity No data available. Carcinogenicity Not classified. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. NTP Report on Carcinogens Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not regulated. Reproductive toxicity No data available. Specific target organ toxicity - No data available. single exposure Specific target organ toxicity - No data available. repeated exposure ABEX 3027-108 SDS US 941178 Version #: 01 Revision date:- Aspiration hazard No data available. Chronic effects The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. May cause damage to the liver and kidneys. 12. Ecological information Ecotoxicity Not relevant, due to the form of the product in its manufactured and shipped state. Components Species Test Results Zinc (CAS 7440-66-6) Aquatic Fish LC50 Rainbow trout,donaldson trout 0.24 mg/l, 96 hours (Oncorhynchus mykiss) Persistence and degradability §= The product contains inorganic compounds which are not biodegradable. Bioaccumulative potential No data available. Mobility in soil Not relevant, due to the form of the product. Mobility in general Not relevant, due to the form of the product. Other adverse effects No data available. 13. Disposal considerations Disposal instructions Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Local disposal regulations Dispose of in accordance with local regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. products Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to —_Not established. Annex Il of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations Under some use conditions, this material may be considered to be hazardous in accordance with OSHA 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Barium sulphate (CAS 7727-43-7) Listed. Copper (CAS 7440-50-8) Listed. Zinc (CAS 7440-66-6) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) SARA 302 Extremely hazardous substance Not listed. ABEX 3027-108 SDS US 941178 Version#:01 Revisiondate:- SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. Copper 7440-50-8 1-5 Zinc 7440-66-6 1-5 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) US state regulations US. Massachusetts RTK - Substance List Barium sulphate (CAS 7727-43-7) Copper (CAS 7440-50-8) Magnesium oxide (CAS 1309-48-4) Zinc (CAS 7440-66-6) US. New Jersey Worker and Community Right-to-Know Act Barium sulphate (CAS 7727-43-7) Copper (CAS 7440-50-8) Glass Fiber (CAS 65997-17-3) Magnesium oxide (CAS 1309-48-4) Zinc (CAS 7440-66-6) US. Pennsylvania Worker and Community Right-to-Know Law Barium sulphate (CAS 7727-43-7) Copper (CAS 7440-50-8) Magnesium oxide (CAS 1309-48-4) Zinc (CAS 7440-66-6) US. Rhode Island RTK Barium sulphate (CAS 7727-43-7) Copper (CAS 7440-50-8) Glass Fiber (CAS 65997-17-3) Magnesium oxide (CAS 1309-48-4) Zinc (CAS 7440-66-6) California Proposition 65 This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Copper (CAS 7440-50-8) Glass Fiber (CAS 65997-17-3) Magnesium oxide (CAS 1309-48-4) Zinc (CAS 7440-66-6) International Inventories Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 24-November-2017 Revision date Version # 01 ABEX 3027-108 SDS US 941178 Version #: 01 Revision date: - Further information Dash “-"“next to the NFPA ratings indicates Not Applicable. NFPA ratings List of abbreviations LC50: Lethal Concentration, 50%. LD50: Lethal Dose, 50%. References HSDB® - Hazardous Substances Data Bank Registry of Toxic Effects of Chemical Substances (RTECS) Disclaimer The information provided on this data sheet was abstracted from supplier material safety data sheets and standard references in occupational health and toxicology. Federal-Mogul makes no representation or warranty with respect to the information obtained from such references. The information is however, as of the date provided, true and accurate to the best of Federal-Mogul's knowledge, and should be used to make an independent determination of the methods to safeguard workers and the environment. ABEX 3027-108 SDS US 941178 Version #: 01 Revision date:- 1. Identification Product identifier FER 9223 Other means of identification SDS number 350 Recommended use Friction material, disc brake pad. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer/Supplier Federal-Mogul Motorparts World Headquarters 27300 West 11 Mile Road Southfield, Michigan 48034 USA Contact person: msds.request@federalmogul.com Emergency Telephone: 24hr EP (INFOTRAC): 1-800-535-5053 International: (001) 352-323-3500 2. Hazard(s) identification Physical hazards Not classified. Health hazards Not classified. OSHA defined hazards Not classified. Label elements Hazard symbol None. Signal word None. Hazard statement Exempt (manufactured article). Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash thoroughly after handling. Storage Store away from heat. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information None. 3. Composition/information on ingredients Mixtures Chemical name CAS number % Barium sulphate 7727-43-7 10 - 30 Zirconium dioxide