VLA

Hazard statements (CLP)

H301, H302, H311, H314, H315, H317, H318, H330, H400, H410, H411, H412

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

2-octyl-2H-isothiazol-3-one None concentration of quartz (fine fraction) or cristobalite (fine fraction) is greater than or equal to 10%; - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. TLV-ACGIH LD50 (Oral) 0,025 Aquatic Chronic 1 H410 M=100 500 mg/kg rat -STOT RE 2, if the concentration of quartz 6.2. Environmental precautions 10.1. Reactivity SECTION 13. Disposal considerations EC LC50 - for Fish LD50 (Dermal) 212-950-5 0,036 mg/l/96h Oncorhynchus mykiss (OECD 210) S 93 > 900 mg/kg rat

2.1 Classification of the substance or mixture

fine fraction) or cristobalite (fine fraction) is between 1 and 10%; - TWA STEL: Short-term exposure limit INDEX EC50 - for Crustacea Healthcare controls 0,42 mg/l/48h Daphnia magna (OECD 202) S 95 -If the quartz (fine fraction) or cristobalite (fine fraction) content in mixtures and substances is below 1%, no classification is required by law. - TWA: Time-weighted average exposure limit 13.1. Waste treatment methods The assessments regarding the classification of products containing 1,2-Benzisothiazolin-3-one EC50 - for Algae / Aquatic Plants Information not available The product must not penetrate into the sewer system or come into contact with surface water or ground water. There are no particular risks of reaction with other substances in normal conditions of use. Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one [CE n° 247-500-7] and 2-methyl-2H-isothiazol-3-one [CE n° 220-239-6] (3 1) 0,084 mg/l/72h Scenedesmus subscicatus (OECD 201) S 63 crystalline silica (fine fraction) takes into account the free availability of these fine particles. If a product exists in a form that prevents the - VOC: Volatile organic Compounds The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments CAS Chronic NOEC for Fish LD50 (Oral) 26-34-33-5 0,005 ≤ x < 0,05 Acute Tox. 2 H330, Acute Tox. 4 H302, Eye Dam. 1 H318, Skin Irrit. 2 H315, Skin Sens. 1 H317, 0,022 mg/l Oncorhynchus mykiss (OECD 210) S 159 (28d) 66 mg/kg rat and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and fraction of fine particles from becoming airborne (for example, products in liquid form), this will be taken into consideration in the classification

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation Chronic NOEC for Crustacea Reuse, when possible. Neat product residues should be considered special non-hazardous waste. and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and LD50 (Dermal) Aquatic Acute 1 H400 M=1, Aquatic Chronic 2 H411 0,002 mg/l Daphnia magna) (OECD 211) S 96 (21d) > 141 mg/kg rat 6.3. Methods and material for containment and cleaning up 10.2. Chemical stability assessment. Therefore, industrial mineral manufacturers consider that, when a mineral classified as STOT RE1 or STOT RE2 due to its fine - WGK: Water hazard classes (German). subsequent amendments. EC Chronic NOEC for Algae / Aquatic Plants Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. Contains biocide with fungicide and algicide properties for dry films. Active substances: 2-octyl-2H-isothiazol-3-one (CAS 26530-20-1), zinc subsequent amendments. 220-120-9 0,004 mg/l Algae (OECD 201) S 63 (72h) Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. fraction of crystalline silica is incorporated into a mixture in liquid form, such fine fraction is no longer freely available and the classification INDEX CONTAMINATED PACKAGING pyrithione (CAS 13463-41-7) terbutryn (CAS 886-50-0). In accordance with art. 58 of Regulation no. 528/2012, this product is defined as a Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Terbutryn 613-088-00-6 Collect the leaked product into a suitable container. If the product is flammable, use explosion-proof equipment. Evaluate the compatibility of The product is stable in normal conditions of use and storage. would not be justified. [IMA Europe © 2014, http://www.crystallinesilica.eu/content] Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one [CE n° 247-500-7] and 2-methyl-2H-isothiazol-3-one [CE n° 220-239-6] (3 1) Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. “treated article” (not a biocidal product). the container to be used, by checking section 10. Absorb the remainder with inert absorbent material. LD50 (Oral) > 300 mg/kg rat Hazard classification and indication: GENERAL BIBLIOGRAPHY CAS LC50 - for Fish Hazard classification and indication: LD50 (Dermal) 55965-84-9 0,00015 ≤ x < 0,0015 Acute Tox. 2 H330, Acute Tox. 3 H301, Acute Tox. 3 H311, Skin Corr. 1B H314, 0,22 mg/l/96h Oncorhynchus mykiss - OECD 203 ( S6) > 2000 mg/kg rat 10.3. Possibility of hazardous reactions 8.2. Exposure controls Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. 1. Regulation (EU) 1907/2006 (REACH) of the European Parliament 15.2. Chemical safety assessment EC50 - for Crustacea Hazardous to the aquatic environment, chronic toxicity, Skin Sens. 1 H317, Aquatic Acute 1 H400 M=100, Aquatic Chronic 1 H410 M=10 0,1 mg/l/48h Daphnia magna - OECD 202 ( S52) H412 Harmful to aquatic life with long lasting effects. SECTION 14. Transport information 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament EC EC50 - for Algae / Aquatic Plants category 3 QUARTZ (FINE FRACTION) 611-341-5 0,048 mg/l/72h Pseudokirchneriella subcapitata - OECD 201 ( S1322) 6.4. Reference to other sections No hazardous reactions are foreseeable in normal conditions of use and storage. Comply with the safety measures usually applied when handling chemical substances. 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament INDEX Chronic NOEC for Fish No chemical safety assessment has been processed for the mixture and the substances it contains. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail LD50 (Oral) 613-167-00-5 0,098 mg/l 28d - Oncorhynchus mykiss - OECD 210 ( S117) > 2000 mg/kg

2.2 Label elements

Exposure levels must be kept as low as possible to avoid significant build-up in the organism. Manage personal protective equipment so as to 4. Regulation (EU) 2015/830 of the European Parliament Chronic NOEC for Crustacea LD50 (Dermal) 0,004 mg/l 21d - Daphnia magna - OECD 211 ( S52) > 2000 mg/kg 10.4. Conditions to avoid Any information on personal protection and disposal is given in sections 8 and 13. guarantee maximum protection (e.g. reduction in replacement times). (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament The full wording of hazard (H) phrases is given in section 16 of the sheet. Chronic NOEC for Algae / Aquatic Plants 0,0012 mg/l 72h - Pseudokirchneriella subcapitata - OECD 201 ( S1322)

Further information

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. HAND PROTECTION 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament SKIN CORROSION / IRRITATION Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements.

UN Number

In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard EN 374). None in particular. However the usual precautions used for chemical products should be respected. 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament SECTION 7. Handling and storage Values refer to the additive used in conc. <1% made from a mixture of terbutryn, 2-octyl-2H-isothiazol-3-one, zinc pyrithione and zinc oxide. Text of hazard (H) indications mentioned in section 2-3 of the sheet: Work glove material must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity

Hazard pictograms

8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament -- 10.5. Incompatible materials Does not meet the classification criteria for this hazard class Toxicity to fish Not applicable 7.1. Precautions for safe handling