TLV

Hazard statements (CLP)

H315, H318, H319, H335

Code

Statements

H315

Causes skin irritation

Further information

Keep the product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details. 10.3. Possibility of hazardous reactions Does not meet the classification criteria for this hazard class - ECHA website 4.2. Most important symptoms and effects, both acute and delayed 8.2. Exposure controls The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail - Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy

2.1 Classification of the substance or mixture

7.3. Specific end use(s) (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. Text of hazard (H) indications mentioned in section 2-3 of the sheet: REPRODUCTIVE TOXICITY No hazardous reactions are foreseeable in normal conditions of use and storage. Specific information on symptoms and effects caused by the product are unknown. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments

UN Number

Information not available well aired through effective local aspiration. Does not meet the classification criteria for this hazard class Note for users: Eye Dam. 1 Serious eye damage, category 1 10.4. Conditions to avoid and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. 4.3. Indication of any immediate medical attention and special treatment needed When choosing personal protective equipment, ask your chemical substance supplier for advice. The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the Eye Irrit. 2 Eye irritation, category 2 Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Not applicable Personal protective equipment must be CE marked, showing that it complies with applicable standards. STOT - SINGLE EXPOSURE suitability and thoroughness of provided information according to each specific use of the product. Skin Irrit. 2 Skin irritation, category 2 SECTION 8. Exposure controls/personal protection None in particular. However the usual precautions used for chemical products should be respected. Information not available STOT SE 3 Specific target organ toxicity - single exposure, category 3 Hazard classification and indication: Provide an emergency shower with face and eye wash station. This document must not be regarded as a guarantee on any specific product property. Hazard classification and indication: 14.2. UN proper shipping name 8.1. Control parameters Does not meet the classification criteria for this hazard class The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health HAND PROTECTION H318 Eye irritation, category 2 Causes serious eye damage. 10.5. Incompatible materials H319 Causes serious eye irritation. SECTION 5. Firefighting measures In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard EN 374). and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Not applicable H315 Causes skin irritation.

2.2 Label elements

Regulatory References: Work glove material must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity STOT - REPEATED EXPOSURE Provide appointed staff with adequate training on how to use chemical products. Information not available 5.1. Extinguishing media reactions. H335 May cause respiratory irritation. 14.3. Transport hazard class(es) AUS SKIN PROTECTION Does not meet the classification criteria for this hazard class Österreich Grenzwerteverordnung 2011 - GKV 2011 10.6. Hazardous decomposition products Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. SUITABLE EXTINGUISHING EQUIPMENT BEL Wear category I professional long-sleeved overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body Product’s classification is based on the calculation methods set out in Annex I of the CLP Regulation, unless otherwise indicated in sections Belgique AR du 11/3/2002. La liste est mise à jour pour 2010 Not applicable LEGEND: The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. CHE with soap and water after removing protective clothing.

Aspiration hazard

11 and 12. Suisse / Schweiz Valeurs limites d’exposition aux postes de travail 2014. / Grenzwerte am Arbeitsplatz

Hazard pictograms

Information not available - ADR: European Agreement concerning the carriage of Dangerous goods by Road UNSUITABLE EXTINGUISHING EQUIPMENT ESP EYE PROTECTION The data for evaluation of chemical-physical properties are reported in section 9. España INSHT - Límites de exposición profesional para agentes químicos en España 2017 14.4. Packing group - CAS NUMBER: Chemical Abstract Service Number None in particular. FRA Wear airtight protective goggles (see standard EN 166). Does not meet the classification criteria for this hazard class France JORF n°0109 du 10 mai 2012 page 8773 texte n° 102

TOXICOLOGICAL INFORMATION

CE50: Effective concentration (required to induce a 50% effect) GBR RESPIRATORY PROTECTION Changes to previous review: United Kingdom EH40/2005 Workplace exposure limits 5.2. Special hazards arising from the substance or mixture Not applicable - CE NUMBER: Identifier in ESIS (European archive of existing substances) GRC Use a type P filtering facemask, whose class (1, 2 or 3) and effective need, must be defined according to the outcome of risk assessment The following sections were modified: Ελλάδα ΕΦΗΜΕΡΙΣ ΤΗΣ ΚΥΒΕΡΝΗΣΕΩΣ -ΤΕΥΧΟΣ ΠΡΩΤΟ Αρ. Φύλλου 19 - 9 Φεβρουαρίου 2012

ECOLOGICAL INFORMATION

In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it - CLP: EC Regulation 1272/2008 (see standard EN 149). 01 / 08 / 11. HUN Magyarország 50/2011. (XII. 22.) NGM rendelet a munkahelyek kémiai biztonságáról

Environmental hazards

contains, using the criteria specified in the applicable regulation for classification. - DNEL: Derived No Effect Level ENVIRONMENTAL EXPOSURE CONTROLS Changed TLVs in section 8.1 for following countries: HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE NLD Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or Nederland Databank of the social and Economic Concil of Netherlands (SER) Values, AF 2011:18 It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the - EmS: Emergency Schedule Do not breathe combustion products. SVK The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure AUS, Slovensko NARIADENIE VLÁDY Slovenskej republiky z 20. júna 2007 contaminate soil or vegetation. toxicological effects of exposure to the product. Not applicable - GHS: Globally Harmonized System of classification and labeling of chemicals EU compliance with environmental standards. OEL EU Directive (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; 5.3. Advice for firefighters - IATA DGR: International Air Transport Association Dangerous Goods Regulation

Signal word

Warning Directive 2004/37/EC; Directive 2000/39/EC; Directive 91/322/EEC. 12.1. Toxicity 11.1. Information on toxicological effects 14.6. Special precautions for user - IC50: Immobilization Concentration 50% TLV-ACGIH ACGIH 2019 SECTION 9. Physical and chemical properties - IMDG: International Maritime Code for dangerous goods

Hazard statements

GENERAL INFORMATION Calcium hydrate Metabolism, toxicokinetics, mechanism of action and other information Not applicable - IMO: International Maritime Organization Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for LC50 - Marine water fish = 457 mg/l; NOEC = 2000 mg/kg; NOEC = 1080 mg/kg (21d) H319 Causes serious eye irritation. - INDEX NUMBER: Identifier in Annex VI of CLP health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of 9.1. Information on basic physical and chemical properties 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Information not available - LC50: Lethal Concentration 50%

Precautionary statements

contaminated water used for extinction and the remains of the fire according to applicable regulations. Calcium hydrate - LD50: Lethal dose 50% SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Appearance LC50 - for Fish P280 Wear eye protection / face protection. powder 50,6 mg/l/96h (pesci d'acqua dolce) Information on likely routes of exposure Information not relevant - OEL: Occupational Exposure Level Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with Colour EC50 - for Crustacea P337+P313 If eye irritation persists: Get medical advice / attention. white 49,1 mg/l/48h

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). Odour EC50 - for Algae / Aquatic Plants P501 Dispose of contents/container in accordance with national regulation. odourless 184,57 mg/l/72h Information not available - PEC: Predicted environmental Concentration Odour threshold Chronic NOEC for Crustacea - PEL: Predicted exposure level Not available 32 mg/l 14d pH Chronic NOEC for Algae / Aquatic Plants Delayed and immediate effects as well as chronic effects from short and long-term exposure - PNEC: Predicted no effect concentration 11,5-13 48 mg/l 72h Melting point / freezing point Not available EPY 9.6.3 - SDS 1004.13 ... / >>

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.