Incompatible with: oxidising substances,strong acids,alkaline metals

Environmental hazards

Oxidising properties Delayed and immediate effects as well as chronic effects from short and long-term exposure - EmS: Emergency Schedule INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately. antistatic footwear. Vigorous stirring and flow through the tubes and equipment may cause the formation and accumulation of electrostatic mg/l Not available - GHS: Globally Harmonized System of classification and labeling of chemicals Normal value for fresh water sediment 66,77 mg/kg/d

ECOLOGICAL INFORMATION

INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious charges. In order to avoid the risk of fires and explosions, never use compressed air when handling. Open containers with caution as they Normal value for marine water sediment 6,677

2.1 Classification of the substance or mixture

IATA DGR: International Air Transport Association Dangerous Goods Regulation mg/kg/d 1-METHOXY-2-PROPANOL person, unless authorised by a doctor. may be pressurised. Do not eat, drink or smoke during use. Avoid leakage of the product into the environment. Not applicable Normal value of STP microorganisms 10 mg/l - IC50: Immobilization Concentration 50% The main route of entry is the skin, whereas the respiratory route is less important due to the low vapour pressure of the product. 12.1. Toxicity The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). - IMDG: International Maritime Code for dangerous goods The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Normal value for the terrestrial compartment Above 100 ppm causes irritation of the eye, nose and oropharynx mucous membranes. At 1000 ppm, disturbance of equilibrium and 61,42 4.2. Most important symptoms and effects, both acute and delayed 7.2. Conditions for safe storage, including any incompatibilities 14.6. Special precautions for user Health - Derived no-effect level - DNEL / DMEL mg/kg/d However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Information not available - IMO: International Maritime Organization However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data severe eye irritation can be noticed. Clinical and biological examinations carried out on exposed volunteers revealed no anomalies. sheet with appropriate information, compliant to (EU) Regulation 2015/830. - INDEX NUMBER: Identifier in Annex VI of CLP sheet with appropriate information, compliant to (EU) Regulation 2015/830. Acetate produces greater skin and eye irritation with direct contact. No chronic effects on humans have been reported. Effects on consumers Effects on workers Specific information on symptoms and effects caused by the product are unknown. Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Store in a well ventilated Not applicable

Principle Routes of Exposure

Acute Chronic Acute Chronic Oxirane, mono[(C12-14-alkyloxy)methyl] derivs - LC50: Lethal Concentration 50% place, keep far away from sources of heat, naked flames and sparks and other sources of ignition. Keep containers away from any SECTION 10. Stability and reactivity Hazard classification and indication: Interactive effects LC50 - for Fish - LD50: Lethal dose 50% Hazard classification and indication: local systemic -- > 100 mg/l/96h Oncorhynchus mykiss local systemic local systemic local systemic 4.3. Indication of any immediate medical attention and special treatment needed 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code incompatible materials, see section 10 for details. Inhalation 2,9 7,6 1,46 0,87 9,8 29 0,98 3,8 10.1. Reactivity EC50 - for Crustacea - OEL: Occupational Exposure Level 7,2 mg/l/48h Daphnia magna Information not available EC50 - for Algae / Aquatic Plants

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation mg/m3 843,75 mg/l/72h Pseudokirchneriella subcapitata mg/m3 7.3. Specific end use(s) Information not available Information not relevant Skin 40 10 1 0,5 68 17

2.2 Label elements

PEC: Predicted environmental Concentration 1,7 1 There are no particular risks of reaction with other substances in normal conditions of use. mg/kg/d mg/kg bw/d mg/kg/d mg/kg 12.2. Persistence and degradability ACUTE TOXICITY - PEL: Predicted exposure level Information not available

Hazard pictograms

SECTION 5. Firefighting measures SECTION 15. Regulatory information - PNEC: Predicted no effect concentration 1-METHOXY-2-PROPANOL -- bw/d LC50 (Inhalation) of the mixture: - REACH: EC Regulation 1907/2006 Dissolves various plastic materials.Stable in normal conditions of use and storage. Not classified (no significant component) 5.1. Extinguishing media SECTION 8. Exposure controls/personal protection

Signal word

Legend: - RID: Regulation concerning the international transport of dangerous goods by train LD50 (Oral) of the mixture: 1-METHOXY-2-PROPANOL -- Not classified (no significant component) 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. LD50 (Dermal) of the mixture: Solubility in water - TLV: Threshold Limit Value 1000 - 10000 mg/l Not classified (no significant component) 8.1. Control parameters Absorbs and disolves in water and in organic solvents. With air it may slowly form explosive peroxides. SUITABLE EXTINGUISHING EQUIPMENT VND = hazard identified but no DNEL/PNEC available ; NEA = no exposure expected ; NPI = no hazard identified.

Hazard statements

Rapidly degradable - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. -- The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. Seveso Category - Directive 2012/18/EC: - TWA STEL: Short-term exposure limit None 10.2. Chemical stability 8.2. Exposure controls UNSUITABLE EXTINGUISHING EQUIPMENT Regulatory References: 12.3. Bioaccumulative potential

Precautionary statements

TWA: Time-weighted average exposure limit Phenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis[oxirane] -- None in particular. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 - VOC: Volatile organic Compounds LD50 (Oral) > 2000 mg/kg Rat The product is stable in normal conditions of use and storage. DEU As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Deutschland TRGS 900 (Fassung 4.11.2016) - Liste der Arbeitsplatzgrenzwerte und Kurzzeitwerte None LD50 (Dermal)

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation > 2000 mg/kg Rat

2.3 Other hazards

5.2. Special hazards arising from the substance or mixture

Other hazards

well aired through effective local aspiration. ESP 1-METHOXY-2-PROPANOL - WGK: Water hazard classes (German). España INSHT - Límites de exposición profesional para agentes químicos en España 2017 10.3. Possibility of hazardous reactions FRA Provide an emergency shower with face and eye wash station. Substances in Candidate List (Art. 59 REACH) Partition coefficient: n-octanol/water Oxirane, mono[(C12-14-alkyloxy)methyl] derivs France JORF n°0109 du 10 mai 2012 page 8773 texte n° 102 < 1 On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE GBR HAND PROTECTION On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. LD50 (Oral) United Kingdom EH40/2005 Workplace exposure limits > 2000 mg/kg Rat 12.4. Mobility in soil Do not breathe combustion products. GRC In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard EN 374). No hazardous reactions are foreseeable in normal conditions of use and storage. GENERAL BIBLIOGRAPHY LD50 (Dermal) Ελλάδα ΕΦΗΜΕΡΙΣ ΤΗΣ ΚΥΒΕΡΝΗΣΕΩΣ -ΤΕΥΧΟΣ ΠΡΩΤΟ Αρ. Φύλλου 19 - 9 Φεβρουαρίου 2012 > 4000 mg/kg Rabbit HRV Work glove material must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity Substances subject to authorisarion (Annex XIV REACH) 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament LC50 (Inhalation) Hrvatska NN13/09 - Ministarstvo gospodarstva, rada i poduzetništva > 0,15 mg/l/4h Rat 5.3. Advice for firefighters 1-METHOXY-2-PROPANOL HUN reactions. None Magyarország 50/2011. (XII. 22.) NGM rendelet a munkahelyek kémiai biztonságáról Information not available 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament May react dangerously with: strong oxidising agents,strong acids. ITA SKIN PROTECTION 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament 1-METHOXY-2-PROPANOL Italia Decreto Legislativo 9 Aprile 2008, n.81 EPY 9.6.3 - SDS 1004.9