H411

Hazard statements (CLP)

H310

Code

Statements

H310

Fatal in contact with skin

SECTION 2: Hazards identification

Regulation EC 1272/2008 (CLP) (fine fraction) or cristobalite (fine fraction) is between 1 and 10%; Does not meet the classification criteria for this hazard class 1,2-benzisothiazol-3(2H)-one - PEL: Predicted exposure level There are no particular risks of reaction with other substances in normal conditions of use. None -If the quartz (fine fraction) or cristobalite (fine fraction) content in mixtures SECTION 4. First aid measures and substances is below 1%, no classification is required by law. Partition coefficient: n-octanol/water - PNEC: Predicted no effect concentration 0,7 Log Kow The assessments regarding the classification of products containing 7.1. Precautions for safe handling crystalline silica (fine fraction) takes into account the free availability of these fine particles. If a product exists in a form that prevents the CARCINOGENICITY BCF - REACH: EC Regulation 1907/2006 6,95 -

2.1 Classification of the substance or mixture

10.2. Chemical stability Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: 4.1. Description of first aid measures fraction of fine particles from becoming airborne (for example, products in liquid form), this will be taken into consideration in the classification - RID: Regulation concerning the international transport of dangerous goods by train None Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the 12.4. Mobility in soil The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). assessment. Therefore, industrial mineral manufacturers consider that, when a mineral classified as STOT RE1 or STOT RE2 due to its fine Does not meet the classification criteria for this hazard class - TLV: Threshold Limit Value The product is stable in normal conditions of use and storage. The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem environment. Do not eat, drink or smoke during use. fraction of crystalline silica is incorporated into a mixture in liquid form, such fine fraction is no longer freely available and the classification - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Substances subject to the Rotterdam Convention: However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data persists, seek medical advice. would not be justified. [IMA Europe © 2014, http://www.crystallinesilica.eu/content] REPRODUCTIVE TOXICITY Information not available - TWA STEL: Short-term exposure limit 10.3. Possibility of hazardous reactions sheet with appropriate information, compliant to (EU) Regulation 2015/830. None sheet with appropriate information, compliant to (EU) Regulation 2015/830. SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash - TWA: Time-weighted average exposure limit 8.2. Exposure controls contaminated clothing before using it again. Product for professional use. Always read the technical datasheet before using. Wear protective gloves and garments, and in the event of Does not meet the classification criteria for this hazard class - VOC: Volatile organic Compounds Hazard classification and indication: No hazardous reactions are foreseeable in normal conditions of use and storage. Substances subject to the Stockholm Convention: Hazard classification and indication: --

Results of PBT and vPvB assessment

INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately. contact with the skin wash with plenty of water and soap. During use, ventilate the room well and use water to clean tools.

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation None INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious Comply with the safety measures usually applied when handling chemical substances. STOT - SINGLE EXPOSURE - WGK: Water hazard classes (German). 10.4. Conditions to avoid 7.2. Conditions for safe storage, including any incompatibilities person, unless authorised by a doctor.

2.2 Label elements

Exposure levels must be kept as low as possible to avoid significant build-up in the organism. Manage personal protective equipment so as to On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Healthcare controls guarantee maximum protection (e.g. reduction in replacement times). Does not meet the classification criteria for this hazard class None in particular. However the usual precautions used for chemical products should be respected. Information not available 4.2. Most important symptoms and effects, both acute and delayed

Other hazards

Keep the product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details. HAND PROTECTION GENERAL BIBLIOGRAPHY Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 10.5. Incompatible materials 15.2. Chemical safety assessment In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard EN 374). STOT - REPEATED EXPOSURE 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament 7.3. Specific end use(s) Information not available Work glove material must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity Information not available 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament

Hazard pictograms

reactions. Does not meet the classification criteria for this hazard class 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament Information not available A chemical safety assessment has not been performed for the preparation/for the substances indicated in section 3. 4.3. Indication of any immediate medical attention and special treatment needed Information not available SKIN PROTECTION 4. Regulation (EU) 2015/830 of the European Parliament

Signal word

SECTION 13. Disposal considerations Wear category I professional long-sleeved overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body

Aspiration hazard

5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament 10.6. Hazardous decomposition products Information not available 13.1. Waste treatment methods

Further information

SECTION 8. Exposure controls/personal protection

Hazard statements

with soap and water after removing protective clothing. 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament EYE PROTECTION Does not meet the classification criteria for this hazard class 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament Information not available EUH210 Safety data sheet available on request. Text of hazard (H) indications mentioned in section 2-3 of the sheet: 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament Wear airtight protective goggles (see standard EN 166). 8.1. Control parameters SECTION 5. Firefighting measures Reuse, when possible. Neat product residues should be considered special non-hazardous waste. EUH208

Contains

reaction mass of 5-chloro-2- methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3- one RESPIRATORY PROTECTION 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament (3:1)

ECOLOGICAL INFORMATION

Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. Acute Tox. 2 Acute toxicity, category 2 5.1. Extinguishing media

TOXICOLOGICAL INFORMATION

Regulatory References: None required, unless indicated otherwise in the chemical risk assessment. 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament CONTAMINATED PACKAGING 1,2-benzisothiazol-3(2H)-one ENVIRONMENTAL EXPOSURE CONTROLS 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament Acute Tox. 3 Acute toxicity, category 3 Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. May produce an allergic reaction. 11.1. Information on toxicological effects SUITABLE EXTINGUISHING EQUIPMENT ESP The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure 12. Regulation (EU) 2016/1179 (IX Atp. CLP) Acute Tox. 4 España Acute toxicity, category 4 LÍMITES DE EXPOSICIÓN PROFESIONAL PARA AGENTES QUÍMICOS EN ESPAÑA 2019 12.1. Toxicity STOT RE 1 Specific target organ toxicity - repeated exposure, category 1 The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. compliance with environmental standards. 13. Regulation (EU) 2017/776 (X Atp. CLP) (INSST) SECTION 14. Transport information Metabolism, toxicokinetics, mechanism of action and other information UNSUITABLE EXTINGUISHING EQUIPMENT FRA 14. Regulation (EU) 2018/669 (XI Atp. CLP) Skin Corr. 1B France Skin corrosion, category 1B Valeurs limites d'exposition professionnelle aux agents chimiques en France. ED 984 - INRS

Precautionary statements

None in particular. GBR 15. Regulation (EU) 2018/1480 (XIII Atp. CLP) Eye Dam. 1 United Kingdom Serious eye damage, category 1 EH40/2005 Workplace exposure limits (Third edition,published 2018) Pyrithione zinc Information not available The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail HUN 16. Regulation (EU) 2019/521 (XII Atp. CLP) Skin Irrit. 2 Magyarország Skin irritation, category 2 A pénzügyminiszter 7/2018. (VIII. 29.) PM rendelete a munkahelyek kémiai biztonságáról szóló SECTION 9. Physical and chemical properties LC50 - for Fish (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. Skin Sens. 1 Skin sensitization, category 1 0,0104 mg/l/96h 5.2. Special hazards arising from the substance or mixture EC50 - for Crustacea 25/2000. (IX. 30.) EüM–SZCSM együttes rendelet módosításáról 0,051 mg/l/48h Information on likely routes of exposure ITA - The Merck Index. - 10th Edition Skin Sens. 1A Italia Skin sensitization, category 1A DIRETTIVA (UE) 2017/164 DELLA COMMISSIONE del 31 gennaio 2017

2.3 Other hazards

EC50 - for Algae / Aquatic Plants 0,051 mg/l/72h

UN Number

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE POL - Handling Chemical Safety Aquatic Acute 1 Polska Hazardous to the aquatic environment, acute toxicity, category 1 ROZPORZĄDZENIE MINISTRA RODZINY, PRACY I POLITYKI SPOŁECZNEJ z dnia 12 czerwca 9.1. Information on basic physical and chemical properties Chronic NOEC for Fish Information not available Aquatic Chronic 1 Hazardous to the aquatic environment, chronic toxicity, category 1 0,00125 mg/l 28d On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Do not breathe combustion products. - INRS - Fiche Toxicologique (toxicological sheet) Chronic NOEC for Crustacea On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. 2018 r 0,0022 mg/l 21d Not applicable PRT - Patty - Industrial Hygiene and Toxicology Aquatic Chronic 2 Portugal Hazardous to the aquatic environment, chronic toxicity, category 2 Ministério da Economia e do Emprego Consolida as prescrições mínimas em matéria de protecção Properties Chronic NOEC for Algae / Aquatic Plants Delayed and immediate effects as well as chronic effects from short and long-term exposure H310 Fatal in contact with skin. Value 0,0149 mg/l 72h Information - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition Appearance dos trabalhadores contra os riscos para a segurança e a saúde devido à exposição a agentes pasty liquid EPY 9.11.3 - SDS 1004.13 Refer to section 8.1 for information on the quartz (fine fraction)