PS 403

Hazard statements (CLP)

H301, H302, H310, H311, H314, H317, H318, H330, H400, H410, H412

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

SECTION 6. Accidental release measures Pyrithione zinc Odour This product is dangerous for the environment and the aquatic organisms. In the long term, it have negative effects on aquatic environment. Healthcare controls VLA ESP 0,1 characteristic RESP Information not available - VOC: Volatile organic Compounds CAS Odour threshold Information not available VLEP 13463-41-7 0 ≤ x < 0,025 FRA 0,1 Acute Tox. 2 H330, Acute Tox. 3 H301, Eye Dam. 1 H318, Aquatic Acute 1 H400 M=100, Not available RESP Information on likely routes of exposure

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation

2.1 Classification of the substance or mixture

12.1. Toxicity pH WEL GBR 0,1 Aquatic Chronic 1 H410 M=10 8-10 RESP 6.1. Personal precautions, protective equipment and emergency procedures - WGK: Water hazard classes (German). SECTION 13. Disposal considerations EC Melting point / freezing point Information not available AK 236-671-3 HUN 0,15 Not available RESP The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation

2.2 Label elements

Legend: Upper explosive limit Eye Dam. 1 H318, Skin Sens. 1A H317, Aquatic Acute 1 H400 M=100, Not available

Further information

7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. Vapour pressure 2-octyl-2H-isothiazol-3- one Aquatic Chronic 1 H410 M=100, EUH071 Not available SECTION 14. Transport information Confine using earth or inert material. Collect as much material as possible and eliminate the rest using jets of water. Contaminated material ACUTE TOXICITY 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament Hazard labelling pursuant to EC Regulation fraction of fine particles from becoming airborne (for example, products in liquid form), this will be taken into consideration in the classification EC50 - for Algae / Aquatic Plants (3:1) 0,157 mg/l/72h 14.3. Transport hazard class(es) Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the - Handling Chemical Safety Aquatic Acute 1 LD50 (Oral) Hazardous to the aquatic environment, acute toxicity, category 1 > 2000 mg/kg assessment. Therefore, industrial mineral manufacturers consider that, when a mineral classified as STOT RE1 or STOT RE2 due to its fine Chronic NOEC for Fish 2-octyl-2H-isothiazol-3- one 2,1 mg/l 28d

Hazard pictograms

2-methylisothiazol-3(2H)-one Notes on respirable crystalline silica: Since 2010, in accordance with the European CLP Regulation, as no harmonised classification is Solubility EC50 - for Algae / Aquatic Plants -- Not available 0,084 mg/l/72h 6.4. Reference to other sections LD50 (Oral) of the mixture: (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament Acute Tox. 2 Acute toxicity, category 2 Not classified (no significant component) CAS available for silica, industrial mineral manufacturers have jointly assessed the GHS classification for quartz (fine fraction) and cristobalite (fine Partition coefficient: n-octanol/water Chronic NOEC for Fish LD50 (Dermal) of the mixture: Acute Tox. 3 2682-20-4 0,00015 ≤ x < 0,0015Acute Tox. 2 H330, Acute Tox. 3 H301, Acute Tox. 3 H311, Skin Corr. 1B H314, Acute toxicity, category 3 Not available 0,022 mg/l 28d Not classified (no significant component)

Signal word

12. Regulation (EU) 2016/1179 (IX Atp. CLP) fraction) to be STOT RE category 1 as regards silicosis risk. As a consequence of this classification, substances and mixtures containing Auto-ignition temperature Chronic NOEC for Crustacea -- Eye Dam. 1 H318, Skin Sens. 1A H317, Aquatic Acute 1 H400 M=10, Not available 0,002 mg/l 21d

UN Number

Any information on personal protection and disposal is given in sections 8 and 13. 13. Regulation (EU) 2017/776 (X Atp. CLP) Acute Tox. 4 Acute toxicity, category 4 crystalline silica (fine fraction), in the form of identified impurities, additives or individual ingredients, are classed as: Decomposition temperature Chronic NOEC for Algae / Aquatic Plants STOT RE 1 Specific target organ toxicity - repeated exposure, category 1 Aquatic Chronic 1 H410 M=1, EUH071 Not available 0,004 mg/l 72h -STOT RE 1, if the

Hazard statements

14. Regulation (EU) 2018/669 (XI Atp. CLP) EC concentration of quartz (fine fraction) or cristobalite (fine fraction) is greater than or equal to 10%; Viscosity 220-239-6 Not available -STOT RE 2, if the concentration of quartz Not applicable 15. Regulation (EU) 2018/1480 (XIII Atp. CLP) Skin Corr. 1B Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl, chlorides Skin corrosion, category 1B SECTION 7. Handling and storage INDEX (fine fraction) or cristobalite (fine fraction) is between 1 and 10%; Explosive properties 2-methylisothiazol-3(2H)-one H412 613-326-00-9 Harmful to aquatic life with long lasting effects. not applicable -If the quartz (fine fraction) or cristobalite (fine fraction) content in mixtures 14.2. UN proper shipping name 16. Regulation (EU) 2019/521 (XII Atp. CLP) Eye Dam. 1 LD50 (Oral) Serious eye damage, category 1 344 mg/kg (rat) and substances is below 1%, no classification is required by law. Oxidising properties LC50 - for Fish EUH208

Contains

2-methylisothiazol-3(2H)-one Not available 6 mg/l/96h The assessments regarding the classification of products containing 7.1. Precautions for safe handling Skin Sens. 1A Skin sensitization, category 1A The full wording of hazard (H) phrases is given in section 16 of the sheet. crystalline silica (fine fraction) takes into account the free availability of these fine particles. If a product exists in a form that prevents the EC50 - for Crustacea reaction mass of 5-chloro-2- methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3- one 1,68 mg/l/48h Not applicable - The Merck Index. - 10th Edition Skin Sens. 1B QUARTZ (FINE FRACTION) Skin sensitization, category 1B