Chronic NOEC for Algae / Aquatic Plants

Hazard statements (CLP)

H301, H310, H330

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

Regulation EC 1272/2008 (CLP) Wear airtight protective goggles (see standard EN 166). Does not meet the classification criteria for this hazard class - PEL: Predicted exposure level None RESPIRATORY PROTECTION - PNEC: Predicted no effect concentration Information not available 7.1. Precautions for safe handling SECTION 4. First aid measures None required, unless indicated otherwise in the chemical risk assessment. STOT - REPEATED EXPOSURE - REACH: EC Regulation 1907/2006

2.1 Classification of the substance or mixture

Substances subject to the Rotterdam Convention: ENVIRONMENTAL EXPOSURE CONTROLS 2-Imidazolidone - RID: Regulation concerning the international transport of dangerous goods by train None 4.1. Description of first aid measures

TOXICOLOGICAL INFORMATION

Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure Does not meet the classification criteria for this hazard class Partition coefficient: soil/water - TLV: Threshold Limit Value < 19 The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). environment. Do not eat, drink or smoke during use. compliance with environmental standards. - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Substances subject to the Stockholm Convention: However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data

Results of PBT and vPvB assessment

EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it

Aspiration hazard

TWA STEL: Short-term exposure limit sheet with appropriate information, compliant to (EU) Regulation 2015/830. None sheet with appropriate information, compliant to (EU) Regulation 2015/830. persists, seek medical advice. contains, using the criteria specified in the applicable regulation for classification. - TWA: Time-weighted average exposure limit SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash Product for professional use. Always read the technical datasheet before using. Wear protective gloves and garments, and in the event of It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the Does not meet the classification criteria for this hazard class On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. - VOC: Volatile organic Compounds Hazard classification and indication: Healthcare controls Hazard classification and indication: -- SECTION 9. Physical and chemical properties contaminated clothing before using it again. contact with the skin wash with plenty of water and soap. During use, ventilate the room well and use water to clean tools. toxicological effects of exposure to the product.

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation Information not available INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately.

Other hazards

WGK: Water hazard classes (German). 7.2. Conditions for safe storage, including any incompatibilities 11.1. Information on toxicological effects

ECOLOGICAL INFORMATION

INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious

2.2 Label elements

9.1. Information on basic physical and chemical properties 15.2. Chemical safety assessment person, unless authorised by a doctor. Information not available No specific data are available for this product. Handle it according to good working practices. Avoid littering. Do not contaminate soil and Keep the product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details. Metabolism, toxicokinetics, mechanism of action and other information Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. GENERAL BIBLIOGRAPHY Properties waterways. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation. Please take all the A chemical safety assessment has not been performed for the preparation/for the substances indicated in section 3. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Value Information 4.2. Most important symptoms and effects, both acute and delayed 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament 7.3. Specific end use(s) SECTION 13. Disposal considerations Appearance proper measures to reduce harmful effects on aquifers. Information not available pasty liquid

Hazard pictograms

2. Regulation (EC) 1272/2008 (CLP) of the European Parliament Colour -- characteristic for each colour

Further information

Information not available 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament 12.1. Toxicity 13.1. Waste treatment methods Odour Information not available Information on likely routes of exposure characteristic

Signal word

4. Regulation (EU) 2015/830 of the European Parliament Odour threshold -- Not available 4.3. Indication of any immediate medical attention and special treatment needed Text of hazard (H) indications mentioned in section 2-3 of the sheet: 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament pH Reuse, when possible. Neat product residues should be considered special non-hazardous waste. Information not available 7-9 SECTION 8. Exposure controls/personal protection

Hazard statements

6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament Melting point / freezing point 2-Imidazolidone Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. Not available Information not available 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament Acute Tox. 2 Acute toxicity, category 2 Initial boiling point LC50 - for Fish CONTAMINATED PACKAGING EUH210 Safety data sheet available on request. Not available > 122 mg/l/96h Oncorhynchus mykiss Delayed and immediate effects as well as chronic effects from short and long-term exposure 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament Acute Tox. 3 Acute toxicity, category 3 8.1. Control parameters Boiling range EC50 - for Crustacea Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. EUH208

Contains

reaction mass of 5-chloro-2- methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3- one Not available > 985 mg/l/48h Dafnia magna 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament Acute Tox. 4 Acute toxicity, category 4 SECTION 5. Firefighting measures Flash point EC50 - for Algae / Aquatic Plants (3:1) > (3:1) 60 > 119 mg/l/72h Pseudokirchneriella subcapitata °C Information not available 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament STOT RE 2 Specific target organ toxicity - repeated exposure, category 2 Evaporation Rate 2-methylisothiazol-3(2H)-one Not available 5.1. Extinguishing media SECTION 14. Transport information 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament Skin Corr. 1B Skin corrosion, category 1B Flammability of solids and gases 1,2-benzisothiazol-3(2H)-one not flammable Interactive effects 12. Regulation (EU) 2016/1179 (IX Atp. CLP) Eye Dam. 1 Serious eye damage, category 1 Lower inflammability limit LC50 - for Fish May produce an allergic reaction. Not available 1,6 mg/l/96h The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail SUITABLE EXTINGUISHING EQUIPMENT 13. Regulation (EU) 2017/776 (X Atp. CLP) Eye Irrit. 2 Eye irritation, category 2 Upper inflammability limit EC50 - for Crustacea Information not available (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. Skin Irrit. 2 Skin irritation, category 2 Not available 3,27 mg/l/48h The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. 14. Regulation (EU) 2018/669 (XI Atp. CLP) Lower explosive limit EC50 - for Algae / Aquatic Plants Not available 0,11 mg/l/72h UNSUITABLE EXTINGUISHING EQUIPMENT 15. Regulation (EU) 2018/1480 (XIII Atp. CLP) Skin Sens. 1 Skin sensitization, category 1

Precautionary statements

Upper explosive limit EC10 for Algae / Aquatic Plants -- Not available 0,04 mg/l/72h

UN Number

ACUTE TOXICITY None in particular. 16. Regulation (EU) 2019/521 (XII Atp. CLP) Skin Sens. 1A Skin sensitization, category 1A Vapour pressure Chronic NOEC for Fish Aquatic Acute 1 Hazardous to the aquatic environment, acute toxicity, category 1 Not available 0,21 mg/l 28d Vapour density Chronic NOEC for Crustacea LC50 (Inhalation) of the mixture: Not applicable Aquatic Chronic 1 Hazardous to the aquatic environment, chronic toxicity, category 1 Not available 1,2 mg/l 21d Not classified (no significant component) 5.2. Special hazards arising from the substance or mixture - The Merck Index. - 10th Edition Relative density 1,4-1,6 14.2. UN proper shipping name LD50 (Oral) of the mixture: - Handling Chemical Safety Aquatic Chronic 2 Hazardous to the aquatic environment, chronic toxicity, category 2 Not classified (no significant component)

2.3 Other hazards

Solubility 2-methylisothiazol-3(2H)-one Not available LD50 (Dermal) of the mixture: - INRS - Fiche Toxicologique (toxicological sheet) H310 Fatal in contact with skin. Not classified (no significant component) HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Partition coefficient: n-octanol/water LC50 - for Fish Not available 6 mg/l/96h Not applicable - Patty - Industrial Hygiene and Toxicology Do not breathe combustion products. H330 Fatal if inhaled. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Auto-ignition temperature EC50 - for Crustacea On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Not available 1,68 mg/l/48h - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition H301 Toxic if swallowed. Decomposition temperature EC50 - for Algae / Aquatic Plants Not available 0,157 mg/l/72h EPY 9.11.3 - SDS 1004.13