13. Regulation (EU) 2017/776 (X Atp. CLP)

Hazard statements (CLP)

H301, H310, H311, H314, H317, H318, H330, H400, H410

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

Not available 0,098 mg/l 28d RESP 11 and 12. 2-methylisothiazol-3(2H)-one Relative density Chronic NOEC for Crustacea VLEP QUARTZ (FINE FRACTION) ITA 0,025 1,45-1,55 0,004 mg/l 21d RESP 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code The data for evaluation of chemical-physical properties are reported in section 9.

2.1 Classification of the substance or mixture

CAS Solubility Chronic NOEC for Algae / Aquatic Plants LEGEND: NDS/NDSCh LD50 (Oral) 2682-20-4 POL 0,0015 ≤ x < 0,1 2 Acute Tox. 2 H330, Acute Tox. 3 H301, Acute Tox. 3 H311, Skin Corr. 1B H314, Not available 0,0012 mg/l 72h > 2000 mg/kg Tot The product must not penetrate into the sewer system or come into contact with surface water or ground water. Partition coefficient: n-octanol/water - ADR: European Agreement concerning the carriage of Dangerous goods by Road Information not relevant NDS/NDSCh LD50 (Dermal) POL 0,3 Eye Dam. 1 H318, Skin Sens. 1A H317, Aquatic Acute 1 H400 M=10, Not available > 2000 mg/kg RESP 12.2. Persistence and degradability The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments Auto-ignition temperature - CAS NUMBER: Chemical Abstract Service Number The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments VLE PRT 0,025 Aquatic Chronic 1 H410 M=1, EUH071 Not available RESP 6.3. Methods and material for containment and cleaning up and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. EC Decomposition temperature SKIN CORROSION / IRRITATION - CE50: Effective concentration (required to induce a 50% effect) and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. TLV 220-239-6 ROU 0,1 Not available RESP SECTION 15. Regulatory information Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Changes to previous review: INDEX Viscosity - CE NUMBER: Identifier in ESIS (European archive of existing substances) Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. NPEL 613-326-00-9 SVK 0,1 Not available RESP Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the The following sections were modified: reaction mass of 5-chloro-2- methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3- one (3:1) Explosive properties Does not meet the classification criteria for this hazard class 1,2-benzisothiazol-3(2H)-one - CLP: EC Regulation 1272/2008 remainder with inert absorbent material. TLV-ACGIH 0,025 not applicable Hazard classification and indication: 01 / 02 / 03 / 08 / 09 / 11 / 12 / 13 / 15 / 16. CAS Oxidising properties Rapidly degradable - DNEL: Derived No Effect Level Hazard classification and indication: 55965-84-9 0,00015 ≤ x < 0,0015Acute Tox. 2 H310, Acute Tox. 2 H330, Acute Tox. 3 H301, Skin Corr. 1B H314, Not available Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Legend: SERIOUS EYE DAMAGE / IRRITATION - EmS: Emergency Schedule Skin sensitization, category 1A Eye Dam. 1 H318, Skin Sens. 1A H317, Aquatic Acute 1 H400 M=100, H317 May cause an allergic skin reaction.

Further information

6.4. Reference to other sections (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. 2-methylisothiazol-3(2H)-one - GHS: Globally Harmonized System of classification and labeling of chemicals Aquatic Chronic 1 H410 M=100, EUH071

2.2 Label elements

Seveso Category - Directive 2012/18/EC: EC Does not meet the classification criteria for this hazard class Rapidly degradable - IATA DGR: International Air Transport Association Dangerous Goods Regulation 611-341-5 None INDEX - IC50: Immobilization Concentration 50% Any information on personal protection and disposal is given in sections 8 and 13. 613-167-00-5 Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 Notes on respirable crystalline silica: Since 2010, in accordance with the European CLP Regulation, as no harmonised classification is RESPIRATORY OR SKIN SENSITISATION reaction mass of 5-chloro-2- methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3- one (3:1) - IMDG: International Maritime Code for dangerous goods Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. The full wording of hazard (H) phrases is given in section 16 of the sheet. available for silica, industrial mineral manufacturers have jointly assessed the GHS classification for quartz (fine fraction) and cristobalite (fine Maximum VOC content limit values ( Directive 2004/42/CE). Category A/g, WB: Maximum VOC 30 g/l (January 2010); Maximum VOC content Rapidly degradable - IMO: International Maritime Organization Product SECTION 7. Handling and storage

Hazard pictograms

fraction) to be STOT RE category 1 as regards silicosis risk. As a consequence of this classification, substances and mixtures containing in product < 30 g/l Sensitising for the skin - INDEX NUMBER: Identifier in Annex VI of CLP Point 3 12.3. Bioaccumulative potential crystalline silica (fine fraction), in the form of identified impurities, additives or individual ingredients, are classed as: May produce an allergic reaction. - LC50: Lethal Concentration 50% 7.1. Precautions for safe handling