HEATING OIL

Potential health effects

Respiratory irritation, headache, dizziness, hausea, loss of consciousness, and in cases of extreme exposure, possibly death. Diesel exhaust may cause lung cancer. Prolonged, repeated skin contact may result in skin irritation or more serious skin disorders. Low viscosity material-if swallowed may enter the lungs and cause lung damage. Note: This product contains polycyclic aromatic hydrocarbons, some of which have been reported to cause skin cancer in test animals and in humans under conditions of poor personal hygiene and prolonged repeated contact. urther health effects/toxicological data, see Section 11. ce eee ee eee ee ee a ee ee ee et ee ee a ee ee i ee ee ee eee ee er ee ee ee ee ee ee ae a ee ee ee ee ee ee re ONTACT: Flush thoroughly with water. If irritation occurs, call a physician. CONTACT: Remove contaminated clothing. Dry wipe exposed skin and cleanse yourself with waterless hand cleaner and follow by washing thoroughly with soap and water. For those providing assistance, avoid further contact to yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard contaminated articles that cannot be laundered. (See Section 16 ~ Injection Injury} INHAUATION: Remove from further exposure. If respiratory irritation, dizziness, Nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with mechanical device or use mouth-to-mouth resuscitation. INGES TION: Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIANS: Material if aspirated into the lungs may cause chemical pneumonitis. PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE: Hydrocarbon Solvents/Petroleum Hydrocarbons- Skin contact may aggravate an existing dermatitis. ee ee ee ee es ee eee ee eee ie i EXTIN GUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Water may be ineffective, but water should be used to keep fire-exposed containers cool. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. SPECT AL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters must use self-contained breathing apparatus. UNUSD AL FIRE AND EXPLOSION HAZARDS: Material is combustible. Liquid MILES LUMBER CO 04 can release vapors that readily form flammable mixtures at or above the flash point. Product can accumulate a static charge which may cause a fire or explosion. COMBI ISTION PRODUCTS: Fumes, smoke, carbon monoxide, sulfur oxides, aldehydes and other decomposition products, in the case of incomplete combustion. Flask 4 Point C({F): > 56({133) (ASTM D-93). Flamyr hable Limits (approx.% vol.in air) - LEL: 0.68, UEL: 7.0% NEPA

SECTION 2: Hazards identification

ID: Health: 1, Flammability: 2, Reactivity: 0 rCIDENTAL RELEASE MEASURES bee me ee Ne re ee ee eee eee ee ee ee ee ee eee eo NOTTI} fICATION PROCEDURES: Report spills/releases as required to appropriate authorities. U.S. Coast Guard and EPA regulations require immediate reporting of spills/releases that could reach any waterway including intermittent dry creeks. Report spill/release to Coast Guard National Response Center toll free number (800)424-8802. In case of accident or road spill notify CHEMTREC (800) 424-9300. PROCH DURES IF MATERIAL IS RELEASED OR SPILLED: LAND SPILL: Eliminate sources of ignition. Shut off source taking normal safety precautions. Take measures to minimize the effects on ground water, Recover by pumping using explosion-proof equipment or contain spilled liquid with sand or other suitable absorbent and remove mechanically into containers. If necessary, dispose of adsorbed residues as directed in Section 13. WATER SPILL: Eliminate sources of ignition and warn other ships in the vicinity to stay clear. Notify port and other relevant authorities. Confine with booms if skimming equipment is avaliable to recover the spill. Otherwise disperse in unconfined waters, if permitted by local authorities and environmental agencies. If permitted by regulatory authorities the use of suitable dispersants should be considered where recommended in local oil spill procedures. ENVI? fONMENTAL

Precautionary statements

Prevent material from entering sewers, water sources or low lying areas; advise the relevant authorities if it has, or if it contaminates soil/vegetation. PERSONAL PRECAUTIONS: See Section 8 —— Se ee ree ee ee at ee ee ee ee ee ee ee i ae ee ee ee ei ee ee eee ee mee mmm mw ese ee ey eer mr see ee mr ee eee ee ee ee ee ee i ee ee ee ee ee HANDLING: Keep product away from high energy ignition sources, heat, sparks, pilot lights, static electricity, and open flame. Harmful in contact with or if absorbed through the skin. Avoid inhalation of vapors or mists. Use in well ventilated area away from all ignition sources. See Section 8 for additional personal protection advice when handling this product.

Storage

Store in a cool area, Avoid sparking conditions. Ground and bond all transfer equipment. SPECIAL PRECAUTIONS: To prevent and minimize fire or explosion risk from static accumulation and discharge, effectively bond and/or ground product transfer system. Do not use electronic devices (including but not limited to cellular phones, computers, calculators, pagers, etc.) in or around any fueling operation or area unless the devices are certified intrinsically safe MILES LUMBER CO 1] 05 by an approved national testing agency and to the safety standards required by national and/or local laws and regulations. Electrical equipment and fittings must comply with local fire prevention regulations for this class of product. Use the correct grounding procedures. Refer to national or local | regulations covering safety at petroleum handling and storage areas for this product. EMPTY CONTAINER WARNING: Empty containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. ee ee ee ee ee i ee eee es ee ee i 8. EXPOSURE CONTROLS/PERSONAL PROTECTION a eee een eee a a a i ee ee ee es ee ee occlu PATIONAL EXPOSURE LIMITS: Bxxo mMobil recommends an 8-hour time-weighted average (TWA) exposure of 500 mg/m3 total vapor (approx. 100 ppm) or 5 mg/m3 stable aerosols. ---TWA--- ---- STEL--- NOTE Subs tance Name (CAS-No. ) Source ppm mg/m3 ETHY IL BENZENE (100-414)

Contains

ethylbenzene. The International Agency for Research on Cancer (IARC) has evaluated ethylbenzene and classified it as possibly carcinogenic to humans (Group 2B) based on sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in exposed humans. MILES LUMBER CO 14 08 12.

ECOLOGICAL INFORMATION

ee ee ee ee eee ee ee ee ee a SS a ee ENVIRONMENTAL FATE AND EFFECTS: In the absence of specific environmental data for this product, this assessment is based on information for representative substances. ECOTOXICITY: Based on test results for similar products, this substance may be toxic to aquatic organisms such as algae and daphnia (EL50/ IrL50 =1-10 mg/L). This