P331

Hazard statements (CLP)

H225, H226, H302, H304, H312, H315, H319, H332, H335, H336, H372, H373, H411, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

100 884 A3, A72, A192 200 SKIN 4.3. Indication of any immediate medical attention and special treatment needed SKIN PROTECTION NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Store in a well ventilated Information not available Solubility in water TLV-ACGIH 1-METHOXY-2-PROPANOL 87 20 100 - 1000 mg/l

2.1 Classification of the substance or mixture

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body Partition coefficient: soil/water 1272/2008 (CLP) 54,6 mg/l/4h Rat 7.3. Specific end use(s) 10.2. Chemical stability and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. EYE PROTECTION Partition coefficient: soil/water Solubility in water - CAS NUMBER: Chemical Abstract Service Number and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. XYLENE (MIXTURE OF ISOMERS) 1,78 < 0,1 mg/l 1-METHOXY-2-PROPANOL SECTION 5. Firefighting measures Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Threshold Limit Value Wear airtight protective goggles (see standard EN 166). XYLENE (MIXTURE OF ISOMERS) - CE50: Effective concentration (required to induce a 50% effect) Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY WORKERS: inhalation; contact with the skin. 1272/2008 (CLP) XYLENE (MIXTURE OF ISOMERS) CAS 1330-20-7 10 ≤ x < 20 Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Asp. Tox. 1 H304, Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Classification note according to Annex VI to the CLP Regulation: C EC 215-535-7 INDEX 601-022-00-9 BARIUM SULFATE CAS 7727-43-7 10 ≤ x < 25 Substance with a community workplace exposure limit. EC 231-784-4 INDEX SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM CAS 64742-95-6 5 ≤ x < 10 Flam. Liq. 3 H226, Asp. Tox. 1 H304, STOT SE 3 H335, STOT SE 3 H336, Aquatic Chronic 2 H411, Classification note according to Annex VI to the CLP Regulation: P EC 265-199-0 INDEX 649-356-00-4 NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY CAS 64742-82-1 2,5 ≤ x < 5,5 Flam. Liq. 3 H226, STOT RE 1 H372, Asp. Tox. 1 H304, STOT SE 3 H336, Aquatic Chronic 2 H411, Classification note according to Annex VI to the CLP Regulation: P EC 265-185-4 INDEX 649-330-00-2 ETHYLBENZENE CAS 100-41-4 2 ≤ x < 5 Flam. Liq. 2 H225, Acute Tox. 4 H332, Asp. Tox. 1 H304, STOT RE 2 H373 EC 202-849-4 INDEX 601-023-00-4 QUARTZ CAS 14808-60-7 2 ≤ x < 5 STOT RE 2 H373 EC 238-878-4 INDEX SECTION 3. Composition/information on ingredients ... / >> 1-METHOXY-2-PROPANOL CAS 107-98-2 0,1 ≤ x < 2 Flam. Liq. 3 H226, STOT SE 3 H336 EC 203-539-1 INDEX 603-064-00-3 ETHYL ACETATE CAS 141-78-6 0,05 ≤ x < 0,1 Flam. Liq. 2 H225, Eye Irrit. 2 H319, STOT SE 3 H336, EUH066 EC 205-500-4 INDEX 607-022-00-5 2-BUTOXYETHANOL CAS 111-76-2 0 ≤ x < 0,05 Acute Tox. 4 H302, Acute Tox. 4 H312, Acute Tox. 4 H332, Eye Irrit. 2 H319, Skin Irrit. 2 H315 EC 203-905-0 INDEX 603-014-00-0 The full wording of hazard (H) phrases is given in section 16 of the sheet.

Contains

place, keep far away from sources of heat, naked flames and sparks and other sources of ignition. Keep containers away from any 2-BUTOXYETHANOL Degradability: information not available LD50 (Oral) 1,78 5300 mg/kg Rat with soap and water after removing protective clothing. Information not available incompatible materials, see section 10 for details. Information on likely routes of exposure LEGEND: Decomposes under the effect of heat. LD50 (Dermal) 13000 mg/kg Rabbit The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments Consider the appropriateness of providing antistatic clothing in the case of working environments in which there is a risk of explosion. SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM Identification TALC Information not relevant - ADR: European Agreement concerning the carriage of Dangerous goods by Road The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments LC50 (Inhalation) x = Conc. % XYLENE (MIXTURE OF ISOMERS) NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM ETHYLBENZENE Product not intended for uses provided for by Dir. 2004/42/CE. Identification x = Conc. %

Results of PBT and vPvB assessment

SECTION 15. Regulatory information RESPIRATORY PROTECTION CAS Information not available The product is stable in normal conditions of use and storage. TITANIUM DIOXIDE - CE NUMBER: Identifier in ESIS (European archive of existing substances) Type LD50 (Oral) POPULATION: ingestion of contaminated food or water; inhalation of ambient air. 1330-20-7 Country 10 ≤ x < 20 TWA/8h Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Asp. Tox. 1 H304, STEL/15min > 5000 mg/kg Rat 5.1. Extinguishing media If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a mask with a type LD50 (Dermal) Hazard classification and indication: mg/m3 Solubility in water - CLP: EC Regulation 1272/2008 Hazard classification and indication: ppm mg/m3 > 2000 mg/kg Rabbit ppm Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, < 0,001 mg/l AX filter, whose limit of use will be defined by the manufacturer (see standard EN 14387). In the presence of gases or vapours of various On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. TLV Flammable liquid, category 2 BGR 375 568 10.3. Possibility of hazardous reactions 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Degradability: information not available - DNEL: Derived No Effect Level SUITABLE EXTINGUISHING EQUIPMENT H225 ETHYLBENZENE SKIN Highly flammable liquid and vapour. Classification note according to Annex VI to the CLP Regulation: C SECTION 8. Exposure controls/personal protection kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. SKIN CORROSION / IRRITATION TLV Aspiration hazard, category 1 CZE 270 550 EC - EmS: Emergency Schedule Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can H304 WORKERS: inhalation; contact with the skin. 215-535-7 SKIN May be fatal if swallowed and enters airways.

Other hazards

Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the INDEX The vapours may also form explosive mixtures with the air. BARIUM SULFATE - GHS: Globally Harmonized System of classification and labeling of chemicals Specific target organ toxicity - repeated exposure, VLEP Specific target organ toxicity - repeated exposure, POPULATION: ingestion of contaminated food or water; contact with the skin of products containing the substance. 601-022-00-9 FRA 188 50 375 H373 10 May cause damage to organs through prolonged or SKIN May cause damage to organs through prolonged or 8.1. Control parameters be used to disperse flammable vapours and protect those trying to stem the leak. Seveso Category - Directive 2012/18/EC: threshold values considered. The protection provided by masks is in any case limited. Causes skin irritation WEL GBR 375 100 P5c 560 150 repeated exposure. SKIN repeated exposure. BARIUM SULFATE Solubility in water - IATA DGR: International Air Transport Association Dangerous Goods Regulation category 2 0,1 - 100 mg/l UNSUITABLE EXTINGUISHING EQUIPMENT If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an Information not available TLV GRC 360 100 1080 300 CAS XYLENE (MIXTURE OF ISOMERS) Degradability: information not available - IC50: Immobilization Concentration 50% Eye irritation, category 2 1-METHOXY-2-PROPANOL 7727-43-7 10 ≤ x < 25 Substance with a community workplace exposure limit. H319 Causes serious eye irritation. Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent Regulatory References: Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing SERIOUS EYE DAMAGE / IRRITATION NDS POL 180 360 EC - IMDG: International Maritime Code for dangerous goods Skin irritation, category 2 Stable in normal conditions of use and storage.Reacts violently with: strong oxidants,strong acids,nitric acid,perchlorates.May form Skin irritation, category 2 WORKERS: inhalation; contact with the skin. 231-784-4 H315 Causes skin irritation. explosions. apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. Product OEL EU 375 100 568 150 SKIN INDEX ETHYL,3-ETHOXY PROPIONATE - IMO: International Maritime Organization Specific target organ toxicity - single exposure, explosive mixtures with: air. Specific target organ toxicity - single exposure, POPULATION: ingestion of contaminated food or water; inhalation of ambient air; contact with the skin of products containing the H335 May cause respiratory irritation. SECTION 13. Disposal considerations BGR ENVIRONMENTAL EXPOSURE CONTROLS Causes serious eye irritation Point TLV-ACGIH България 3 - 40 184 МИНИСТЕРСТВО НА ТРУДА И СОЦИАЛНАТА ПОЛИТИКА МИНИСТЕРСТВО НА 50 368 100 SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM Solubility in water - INDEX NUMBER: Identifier in Annex VI of CLP category 3 substance. > 10000 mg/l 5.2. Special hazards arising from the substance or mixture The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure ЗДРАВЕОПАЗВАНЕТО НАРЕДБА No 13 от 30 декември 2003 г 13.1. Waste treatment methods CAS ETHYLBENZENE Rapidly degradable - LC50: Lethal Concentration 50% Hazardous to the aquatic environment, chronic 64742-95-6 5 ≤ x < 10 Flam. Liq. 3 H226, Asp. Tox. 1 H304, STOT SE 3 H335, STOT SE 3 H336, H412 Harmful to aquatic life with long lasting effects. CZE Substances in Candidate List (Art. 59 REACH) compliance with environmental standards. RESPIRATORY OR SKIN SENSITISATION Česká Republika Nařízení vlády č. 361/2007 Sb. kterým se stanoví podmínky ochrany zdraví při práci Delayed and immediate effects as well as chronic effects from short and long-term exposure - LD50: Lethal dose 50% toxicity, category 3 Reacts violently with strong oxidants.Attacks various types of plastic materials.May form explosive mixtures with air toxicity, category 3 Aquatic Chronic 2 H411, HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE FRA On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways. France JORF n°0109 du 10 mai 2012 page 8773 texte n° 102 ETHYL ACETATE ETHYLBENZENE Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product - OEL: Occupational Exposure Level Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products. GBR United Kingdom EH40/2005 Workplace exposure limits Classification note according to Annex VI to the CLP Regulation: P

2.2 Label elements

Threshold Limit Value Does not meet the classification criteria for this hazard class EC 1-METHOXY-2-PROPANOL Solubility in water should be evaluated according to applicable regulations.

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation XYLENE (MIXTURE OF ISOMERS) 265-199-0 1000 - 10000 mg/l GRC Substances subject to authorisarion (Annex XIV REACH) Type Ελλάδα Country TWA/8h ΕΦΗΜΕΡΙΣ ΤΗΣ ΚΥΒΕΡΝΗΣΕΩΣ -ΤΕΥΧΟΣ ΠΡΩΤΟ Αρ. Φύλλου 19 - 9 Φεβρουαρίου 2012 STEL/15min 5.3. Advice for firefighters SECTION 9. Physical and chemical properties INDEX Rapidly degradable Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. - PEC: Predicted environmental Concentration POL None May react dangerously with: strong oxidising agents,strong acids. Toxic effect on the central nervous system (encephalopathy); irritating for the skin, conjunctiva, cornea and respiratory apparatus. 649-356-00-4 Polska ROZPORZĄDZENIE MINISTRA PRACY I POLITYKI SPOŁECZNEJ z dnia 7 czerwca 2017 r GERM CELL MUTAGENICITY Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. mg/m3 ppm mg/m3 NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY Waste transportation may be subject to ADR restrictions. - PEL: Predicted exposure level EU ppm OEL EU Directive (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; TLV BGR 800 CAS ETHYL ACETATE 2-BUTOXYETHANOL CONTAMINATED PACKAGING - PNEC: Predicted no effect concentration GENERAL INFORMATION Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: ETHYLBENZENE 64742-82-1 2,5 ≤ x < 5,5 Directive 2004/37/EC; Directive 2000/39/EC; Directive 91/322/EEC. Flam. Liq. 3 H226, STOT RE 1 H372, Asp. Tox. 1 H304, STOT SE 3 H336, 9.1. Information on basic physical and chemical properties

Hazard pictograms

Does not meet the classification criteria for this hazard class Solubility in water Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. - REACH: EC Regulation 1907/2006 TLV Risk of explosion on contact with alkaline metals,hydrides,oleum.May react violently with fluorine,strong oxidising agents,chlorosulphuric As the counterparts of benzene, may have an acute effect on the central nervous system, with depression, narcosis, often preceded CZE 700 Aquatic Chronic 2 H411, 1000 - 10000 mg/l 900 Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for None VLEP TLV-ACGIH FRA 1400 ACGIH 2017 Rapidly degradable - RID: Regulation concerning the international transport of dangerous goods by train health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of acid,potassium tert-butoxide.Forms explosive mixtures with: air. by dizziness and associated with headache (Ispesl). Is irritating for skin, conjunctiva and respiratory tract. 400 Classification note according to Annex VI to the CLP Regulation: P CARCINOGENICITY EC Appearance - TLV: Threshold Limit Value WEL 265-185-4 GBR 200 liquid 400 SECTION 14. Transport information contaminated water used for extinction and the remains of the fire according to applicable regulations. Substances subject to the Rotterdam Convention: TLV GRC 1400 400 INDEX Colour 2-BUTOXYETHANOL 1-METHOXY-2-PROPANOL - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS 1-METHOXY-2-PROPANOL 649-330-00-2 white None NDS Does not meet the classification criteria for this hazard class ETHYLBENZENE Odour Solubility in water - TWA STEL: Short-term exposure limit May react dangerously with aluminium,oxidising agents.Forms peroxides with air The main route of entry is the skin, whereas the respiratory route is less important due to the low vapour pressure of the product. POL 734 1000 - 10000 mg/l characteristic 1468

UN Number

Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with OEL EU 734 200 1468 400 CAS Odour threshold Rapidly degradable - TWA: Time-weighted average exposure limit self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). Substances subject to the Stockholm Convention: Above 100 ppm causes irritation of the eye, nose and oropharynx mucous membranes. At 1000 ppm, disturbance of equilibrium and 100-41-4 2 ≤ x < 5 Flam. Liq. 2 H225, Acute Tox. 4 H332, Asp. Tox. 1 H304, STOT RE 2 H373 Not available 10.4. Conditions to avoid EC pH - VOC: Volatile organic Compounds TLV-ACGIH XYLENE (MIXTURE OF ISOMERS) severe eye irritation can be noticed. Clinical and biological examinations carried out on exposed volunteers revealed no anomalies. 202-849-4 1441 400 Not available ADR / RID, IMDG, IATA: None Classified in Group 3 (not classifiable as a human carcinogen) by the International Agency for Research on Cancer (IARC). 1263 INDEX Melting point / freezing point ETHYL ACETATE

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation Acetate produces greater skin and eye irritation with direct contact. No chronic effects on humans have been reported. 601-023-00-4 Not available SECTION 6. Accidental release measures QUARTZ Initial boiling point Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. Solubility in water - WGK: Water hazard classes (German). The US Environmental Protection Agency (EPA) affirms that "the data is inadequate for an assessment of the carcinogenic potential". > > 10000 mg/l 35 °C 14.2. UN proper shipping name Healthcare controls

Signal word

CAS Boiling range Interactive effects Rapidly degradable 14808-60-7 Danger 2 ≤ x < 5 STOT RE 2 H373 Not available Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks ETHYLBENZENE 6.1. Personal precautions, protective equipment and emergency procedures EC Flash point 1-METHOXY-2-PROPANOL 238-878-4 < 23 °C ADR / RID: related to the workers' health and safety are modest and that the 98/24/EC directive is respected.

Hazard statements

Classified in Group 2B (possible human carcinogen) by the International Agency for Research on Cancer (IARC) - (IARC, 2000). PAINT or PAINT RELATED MATERIAL INDEX Evaporation Rate NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY GENERAL BIBLIOGRAPHY IMDG: Avoid exposure to: air. XYLENE (MIXTURE OF ISOMERS) PAINT or PAINT RELATED MATERIAL Not available Block the leakage if there is no hazard. Flammability of solids and gases Rapidly degradable 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament H225 Classified in Group D (not classifiable as a human carcinogen) by the US Environmental Protection Agency (EPA) - (US EPA file Intake of alcohol interferes with the metabolism of the substance, inhibiting it. Ethanol consumption (0.8 g/kg) before a 4-hour Highly flammable liquid and vapour. Not available 15.2. Chemical safety assessment IATA: Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent H304 on-line 2014). PAINT or PAINT RELATED MATERIAL May be fatal if swallowed and enters airways. Lower inflammability limit ETHYL ACETATE 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament exposure to xylene vapours (145 and 280 ppm) causes a 50% reduction in the excretion of methyl hippuric acid, whereas the Not available any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency Upper inflammability limit 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament H373 Avoid exposure to: light,sources of heat,naked flames. H373 concentration of xylenes in the blood increases approx. 1.5-2 times. At the same time there is an increase in the secondary side May cause damage to organs through prolonged or repeated exposure. Not available EPY 9.6.6 - SDS 1004.9 H319 Causes serious eye irritation. H315 Causes skin irritation. H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P280 Wear protective gloves/ protective clothing / eye protection / face protection. P301+P310 IF SWALLOWED: immediately call a POISON CENTER / doctor / . . . P331 Do NOT induce vomiting. P370+P378 In case of fire: use . . . to extinguish.

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. SECTION 3. Composition/information on ingredients 3.1. Substances Information not relevant 3.2. Mixtures