General Information
Revision date
2014-03-26
Product name
mixture including an emergency contact shall be
Substance name
component mixtures
Product Synonyms
or synonyms by which the
CAS No.
Layout
REACH No
too
1.2.1 Relevant identified uses
the name of the supplier of the
1.2.2. Uses advised against
information in this subsection of the safety data
supplier name
Kommentar [HA9]: The uses which the
Emergency telephone
registration. Where an only representative has been appointed, details of the non-Community
Icons in SDS
Company Information
company name
exhaustive list
e-mail address of the competent person responsible for the Safety Data Sheet
sds@xyz.de)
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H301, H311, H331, H360D, H372, H373, H400, H410
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Directive 1999/45/EC: Kommentar [HA15]: This section of the safety data sheet shall
2.1 Classification of the substance or mixture
describe the hazards of the substance or mixture and the appropriate warning information associated with those hazards. Classification according to The most important adverse physicochemical, human health and environmental effects shall be SCL and/or Regulation (EC) No listed consistent with Sections 9 to 12 of the Classification procedure M-factor 1272/2008 [CLP] safety data sheet, in a way as to allow non- experts to identify the hazards of the substance Flam. Liq. 2, H225 On basis of test data or mixture Acute Tox. 3, H301 Practical experience / human evidence Kommentar [HAD(16]: In the case of a substance, the classification Acute Tox. 3, H311 Practical experience / human evidence which arises from the application of the Acute Tox. 3, H331 Practical experience / human evidence classification rules in Regulation (EC) No 1272/2008 shall be given. Where the supplier STOT RE 1, H372 C ≥ 1 %: On basis of test data has notified information regarding the substance STOT RE 1, H372 to the classification and labelling inventory in accordance with Article 40 of Regulation (EC) 0,1 ≤ C < 1 %: No 1272/2008, the classification given in the safety data sheet shall be the same as the STOT RE 2, H373 classification provided in that notification. Aquatic Acute 1, H400 M = 100 On basis of test data From 1.6.2015 on classification of the mixture Aquatic Chronic 1, H410 shall be given in accordance to CLP too. M = 10 On basis of test data Repr. 1A, H360D C ≥ 3 % Legal classification Kommentar [HAD(17]: Proposed standard phrases (see www.euphrac.eu) are for example: Classification according to SCL and/or Calculation method. Bridging principle "Dilution". Classification procedure Bridging principle "Batching". 67/548/EEC or 1999/45/EC M-factor F; R11 Bridging principle "Concentration of highly On basis of test data hazardous mixtures". T; R23/24/25 C ≥ 0,5 %: Practical experience / human evidence Bridging principle "Interpolation within one toxicity category". T; R23/24/25 Bridging principle "Substantially similar 0,1 ≤ C < 0,5 %: mixtures". Bridging principle "Aerosols". Xn; R20/21/22 T; R48/23/24/25 C ≥ 1 %: On basis of test data For mixtures it may be possible to use also the „calculation method“ as classification procedure. T; R48/23/24/25 Kommentar [HAD(18]: 0,1 ≤ C < 1 %: Xn; R48/20/21/22 according to Council Directive 67/548/EEC shall also be given. N R50/53 M = 100 On basis of test data Repr. Cat. 1, R61 C ≥ 3 % Legal classification
Additional information
Full text of R-, H- and EUH-phrases: see section 16. Kommentar [HA19]: If the classification, including the hazard statements and R phrases, is not written out in full, reference shall be made to Section 16 where the full text of each classification, including each hazard statement and R phrase, shall be given. _______________________________________________________________________________________________________________ EUH202 Kommentar [HA30]: REACH, Annex XVII and other (e.g. Biocide, Surfactants etc) ______________________________________________________________________________________________________________
2.2 Label elements
Kommentar [HA20]: In the case of a substance or mixture, based on 2.2.1 Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS] appearing on the label in accordance with the classification, at least the following elements
Product definition
Regulation (EC) No 1272/2008 shall be provided: hazard pictogram(s), signal word(s), hazard statement(s) and precautionary Substances:) statement(s). A graphical reproduction of the full Index No hazard pictogram in black and white or a graphical reproduction of the symbol only may Authorisation No be substituted for the colour pictogram provided in Regulation (EC) No 1272/2008. Until 1.6.2015 Mixtures: in case of a mixture, based on the classification, MethaSol at least the appropriate symbol(s), indication(s) of danger, risk phrase(s) and safety advice appearing on the label in accordance with
Hazardous Ingredients
Directive 1999/45/EC shall be provided. The Substance 1 symbol may be provided as a graphical reproduction of the symbol in black and white. Authorisation No The applicable label elements in accordance with Article 25 and Article 32(6) of Regulation
Hazard pictograms
EC) No 1272/2008, in the case of a substance, or Sections A and B of Annex V to Directive 1999/45/EC, in the case of a mixture, shall be provided. Kommentar [HA21]: CLP, Art. 18 GHS02 GHS06 GHS08 GHS09 Kommentar [HA22]: No „header“, for explanation only.
Signal word
Kommentar [HA23]: REACH, Art. 65 Danger Kommentar [HA24]: No „header“, for
Hazard statements
explanation only. Kommentar [HA25]: Trade name or the H225 Highly flammable liquid and vapour. designation of the mixture. H301 Toxic if swallowed. H311 Toxic in contact with skin. Kommentar [HAD(26]: H331 For substances only Toxic if inhaled. H372 Causes damage to organs through prolonged or repeated exposure H360D May damage the unborn child. H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P309+P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or Kommentar [HAD(27]: doctor/physician. New designed combi phrase P301+P330 IF SWALLOWED: Rinse mouth. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Supplemental label elements
Kommentar [HA28]: if applicable. For example EUH071
Special rules for supplemental label elements for certain mixtures
Kommentar [HA29]: To be added if applicable for mixtures only. For example
2.3 Other hazards
Kommentar [HA31]: The substance or
Other physicochemical hazards
mixture, such as Information on whether the
Potential health effects
substance or mixture meets the criteria for PBT or vPvB in accordance with Annex XIII shall be
Environmental effects
provided. Information shall be provided on other Other adverse hazards: hazards which do not result in classification but which may contribute to the overall hazards of ___________________________________________________________________________________ formation of air contaminants during hardening or processing, dustiness, dust explosion