PU 501 EXPRESS MARINE - Polyurethane marine fast setting wood adhesive D4

EVOCHEM S.A

Revision date : 2015-01-29

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

247-714-0/26447-40-5

Name of the chemical

Methylenediphenyl diisocyanate (see also specific isomers)

Concentration

24-61 24-<50%

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

9,9-<19%

General Information

Revision date

2015-01-29

Product name

PU 501 EXPRESS MARINE - Polyurethane marine fast setting wood adhesive D4

1.2.1 Relevant identified uses

Adhesive for wood

1.2.2. Uses advised against

All uses not specified in this section or in section 7.3

Emergency telephone

National Poisoning Center 2107793777

Icons in SDS

E011 E012 GHS07 GHS08 M008 M009 M013 M017 M026

Company Information

company name

EVOCHEM S.A

e-mail address of the competent person responsible for the Safety Data Sheet

info@evochem.gr, vmergoupis@evochem.gr, sales@evochem.gr

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

2.1 Classification of the substance or mixture

Directive 67/548/EC and Directive 1999/45/EC: This product was classified in accordance with Directive 67/548/EC and Directive 1999/45/EC, adapting the requirements to Regulation (EC) nº1907/2006 (REACH regulation). Carc. Cat 3: R40 - Limited evidence of a carcinogenic effect Xi: R36/37/38 - Irritating to eyes, respiratory system and skin Xn R20 - Harmful by inhalation, R42/43 - May cause sensitisation by inhalation and skin contact, R48/20 - Harmful danger of serious damage to health by prolonged exposure through inhalation CLP Regulation (EC) nº 1272/2008: Classification of this product has been carried out in accordance with CLP Regulation (EC) nº 1272/2008. Acute Tox. 4: Acute inhalation toxicity, Category 4 Carc. 2: Carcinogenicity, Category 2 Eye Irrit. 2: Eye irritation, Category 2 Resp. Sens. 1: Sensitisation, respiratory, Category 1 Skin Irrit. 2: Skin irritation, Category 2 Skin Sens. 1: Sensitisation, skin, Category 1 STOT RE 2: Specific target organ toxicity, repeated exposure, Category 2 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3

2.2 Label elements

Directive 67/548/EC and Directive 1999/45/EC: In accordance with the legislation, the elements on the label are as follows: Xn Harmful

R-phrase(s)

R20: Harmful by inhalation R36/37/38: Irritating to eyes, respiratory system and skin R40: Limited evidence of a carcinogenic effect R42/43: May cause sensitisation by inhalation and skin contact R48/20 Harmful danger of serious damage to health by prolonged exposure through inhalation

S-phrase(s)

S2: Keep out of the reach of children S36/37: Wear suitable protective clothing and gloves S46: If swallowed, seek medical advice immediately and show this container or label

Supplemental label elements

P91: Contains isocyanates-Read the information provided by the manufacturer 24-61 SECTION 2: HAZARDS IDENTIFICATION (continue) EUH204: Contains isocyanates. May produce an allergic reaction EUH208: Contains 4,4´-methylenediphenyl diisocyanate, Diphenylmethanediisocyanate-prepolymer, Methylenediphenyl diisocyanate. May produce an allergic reaction

Hazardous Ingredients

Methylenediphenyl diisocyanate; Diphenylmethanediisocyanate-prepolymer; 4,4´-methylenediphenyl diisocyanate CLP Regulation (EC) nº 1272/2008: Danger Diphenylmethanediisocyanate-prepolymer; Methylenediphenyl diisocyanate; 4,4´-methylenediphenyl diisocyanate

Hazard statements

Acute Tox. 4: H332 - Harmful if inhaled Carc. 2: H351 - Suspected of causing cancer Eye Irrit. 2: H319 - Causes serious eye irritation Resp. Sens. 1: H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled Skin Irrit. 2: H315 - Causes skin irritation Skin Sens. 1: H317 - May cause an allergic skin reaction STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure STOT SE 3: H335 - May cause respiratory irritation

Precautionary statements

P101: If medical advice is needed, have product container or label at hand P102: Keep out of reach of children P103: Read label before use P280: Wear protective gloves/protective clothing/eye protection/face protection P302+P352 IF ON SKIN Wash with plenty of water P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P501: Dispose of the contents/containers in accordance with the current legislation on waste treatment

Additional information

Annex XVII, REACH) Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.

2.3 Other hazards

Non-applicable

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