Note: Ingredients listed on restricted chemical lists
EC/CAS
247-714-0/26447-40-5
Name of the chemical
Methylenediphenyl diisocyanate (see also specific isomers)
Concentration
24-61 24-<50%
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
9,9-<19%
General Information
Revision date
2015-01-29
Product name
PU 501 EXPRESS MARINE - Polyurethane marine fast setting wood adhesive D4
1.2.1 Relevant identified uses
Adhesive for wood
1.2.2. Uses advised against
All uses not specified in this section or in section 7.3
Emergency telephone
National Poisoning Center 2107793777
Icons in SDS
Company Information
company name
EVOCHEM S.A
e-mail address of the competent person responsible for the Safety Data Sheet
info@evochem.gr, vmergoupis@evochem.gr, sales@evochem.gr
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
2.1 Classification of the substance or mixture
Directive 67/548/EC and Directive 1999/45/EC: This product was classified in accordance with Directive 67/548/EC and Directive 1999/45/EC, adapting the requirements to Regulation (EC) nº1907/2006 (REACH regulation). Carc. Cat 3: R40 - Limited evidence of a carcinogenic effect Xi: R36/37/38 - Irritating to eyes, respiratory system and skin Xn R20 - Harmful by inhalation, R42/43 - May cause sensitisation by inhalation and skin contact, R48/20 - Harmful danger of serious damage to health by prolonged exposure through inhalation CLP Regulation (EC) nº 1272/2008: Classification of this product has been carried out in accordance with CLP Regulation (EC) nº 1272/2008. Acute Tox. 4: Acute inhalation toxicity, Category 4 Carc. 2: Carcinogenicity, Category 2 Eye Irrit. 2: Eye irritation, Category 2 Resp. Sens. 1: Sensitisation, respiratory, Category 1 Skin Irrit. 2: Skin irritation, Category 2 Skin Sens. 1: Sensitisation, skin, Category 1 STOT RE 2: Specific target organ toxicity, repeated exposure, Category 2 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3
2.2 Label elements
Directive 67/548/EC and Directive 1999/45/EC: In accordance with the legislation, the elements on the label are as follows: Xn Harmful
R-phrase(s)
R20: Harmful by inhalation R36/37/38: Irritating to eyes, respiratory system and skin R40: Limited evidence of a carcinogenic effect R42/43: May cause sensitisation by inhalation and skin contact R48/20 Harmful danger of serious damage to health by prolonged exposure through inhalation
S-phrase(s)
S2: Keep out of the reach of children S36/37: Wear suitable protective clothing and gloves S46: If swallowed, seek medical advice immediately and show this container or label
Supplemental label elements
P91: Contains isocyanates-Read the information provided by the manufacturer 24-61 SECTION 2: HAZARDS IDENTIFICATION (continue) EUH204: Contains isocyanates. May produce an allergic reaction EUH208: Contains 4,4´-methylenediphenyl diisocyanate, Diphenylmethanediisocyanate-prepolymer, Methylenediphenyl diisocyanate. May produce an allergic reaction
Hazardous Ingredients
Methylenediphenyl diisocyanate; Diphenylmethanediisocyanate-prepolymer; 4,4´-methylenediphenyl diisocyanate CLP Regulation (EC) nº 1272/2008: Danger Diphenylmethanediisocyanate-prepolymer; Methylenediphenyl diisocyanate; 4,4´-methylenediphenyl diisocyanate
Hazard statements
Acute Tox. 4: H332 - Harmful if inhaled Carc. 2: H351 - Suspected of causing cancer Eye Irrit. 2: H319 - Causes serious eye irritation Resp. Sens. 1: H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled Skin Irrit. 2: H315 - Causes skin irritation Skin Sens. 1: H317 - May cause an allergic skin reaction STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure STOT SE 3: H335 - May cause respiratory irritation
Precautionary statements
P101: If medical advice is needed, have product container or label at hand P102: Keep out of reach of children P103: Read label before use P280: Wear protective gloves/protective clothing/eye protection/face protection P302+P352 IF ON SKIN Wash with plenty of water P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P501: Dispose of the contents/containers in accordance with the current legislation on waste treatment
Additional information
Annex XVII, REACH) Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.
2.3 Other hazards
Non-applicable