Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
78-40-0
Name of the chemical
Phosphoric acid, triethyl ester, TEP
Concentration
N/A
General Information
Revision date
2013-10-01
Product name
MDI CD Modified
1.2.1 Relevant identified uses
Component for the manufacture of polyurethane polymers
supplier name
Everchem Specilty Chemicals
Icons in SDS
Company Information
company name
Everchem Specilty Chemicals
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
OSHA Hazards Personal Protective Equipment
Hazard pictograms
WHMIS (Canada) D1A D2A
Classification according to GHS
UNECE 3 revised edition) rd Acute Tox. 4; H332: Harmful if inhaled. STOT RE 2; H373: May cause damage to organs through prolonged or repeated exposure by inhalation. Eye Irrit. 2; H319: Causes serious eye irritation. STOT SE 3; H335: May cause respiratory irritation. Skin Irrit. 2; H315: Causes skin irritation. Resp. Sens. 1; H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Sens. 1; H317: May cause an allergic skin reaction.
2.2 Label elements
Label according to GHS (UNECE 3 revised edition) rd Danger. Harmful if inhaled. May cause damage to organs through prolonged or repeated exposure by inhalation. Causes serious eye irritation. May cause respiratory irritation. Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction.
Prevention
P260: Do not breathe fume/mist/vapors/spray. P264: Wash exposed skin thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. P285: In case of inadequate ventilation, wear respiratory protection. Identification, continued
Response
P304+P340 IF INHALED Remove person to fresh air and keep at rest in a position comfortable for breathing. P312: Call a Poison Center/doctor if you feel unwell. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical attention P302+P352 IF ON SKIN wash with plenty of soap and water P333+P313 If skin irritation or rash occurs Get medical advice/attention P362: Take off contaminated clothing and wash it before reuse.
Storage
P403+233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up.
Disposal
P501: Dispose of contents/containers in accordance with local/ regional/ national/ international regulations.
2.3 Other hazards
Toxic fumes may be released in fire situations. Can decompose at high temperatures forming toxic gases. Closed containers may develop pressure and rupture on prolonged exposure to heat or if contaminated with water. USA: This material is considered a hazardous chemical by the OSHA Hazard Communication Standard (29 CFR 1910.1200) (2012). Canada: This is a controlled product under WHMIS.