4,4’ Monomeric MDI Flaked

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

2.1 Classification of the substance or mixture

Acute Toxicity.(inhalation dust, mist): Cat.4 • Skin Corrosion/Irritation: Cat.2 • Serious Eye Damage/Eye Irritation: Cat.2 • Respiratory Sensitization: Cat.1 • Carcinogenicity: Cat.2 • Skin Sensitization: Cat.1 • Specific Target Organ Toxicity-Single: Cat.3 • Specific Target Organ Toxicity-Repeated: Cat.2 B. Label elements and hazard statement

Signal word

Danger

Hazard statements

H315 : Causes skin irritation. H317 : May cause an allergic skin reaction. H319 : Causes serious eye irritation. H332 : Harmful if inhaled. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 : May cause respiratory irritation. H351 : Suspected of causing cancer. H373 : May cause damage to organs through prolonged or repeated exposure.

Prevention

P201 : Obtain special instructions before use. P202 : Do not handle until all safety precautions have been read and understood. P260 : Do not breathe dust/fume/gas/mist/vapors/spray. P261 : Avoid breathing dust/fume/gas/mist/vapours/spray. P264 : Wash … thoroughly after handling.(cont'd) P271 : Use only outdoors or in a well-ventilated area. P272 : Contaminated work clothing should not be allowed out of workplace. P280 : Wear protective gloves/protective clothing/eye protection/face protection. P281 : Use personal protective equipment as required. P285 : In case of inadequate ventilation wear respiratory protection.

Response

P312 : Call a POISON CENTER or doctor/physician if you feel unwell. P314 : Get medical advice/attention if you feel unwell. P321 : Specific treatment. P362 : Take off contaminated clothing and wash before reuse. P363 : Wash contaminated clothing before reuse. P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P304+P341 IF INHALED If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing P332+P313 If skin irritation or rash occurs Get medical advice/attention P333+P313 If skin irritation or rash occurs Get medical advice/attention P337+P313 If eye irritation persists Get medical advice/attention P342+P311 If experiencing respiratory symptoms Call a poison center or doctor P308+P313 : If exposed or concerned get medical advice/attention.

Storage

P405 : Store locked up. P403+P233 : Store in a well-ventilated place. Keep container tightly closed. Precautionary statements(Disposal) P501 : Dispose of contents/container to …

NFPA Ratings

Ingredient Health Fire Reactivity 4,4’-Methylene diphenyl diisocyanate 3 1