METHANOL RECOVERED

SECTION 2: Hazards identification

Classification of the chemical in accordance with paragraph (d) of 29 CFR 1910.1200: Classification of the chemical in accordance with paragraph (d) of 29 CFR 1910.1200:

Principle Routes of Exposure

Flammable liquids Category 2 -- Acute toxicity Category 3 Oral Acute toxicity Category 3 Dermal Acute toxicity Category 3 Inhalation Skin corrosion/irritation Category 2 -- Serious eye damage/eye irritation Category 2B -- Target Organ Systemic Toxicant - Category 1 -- Single exposure Target Organ Systemic Toxicant - Category 2 -- Repeated exposure

Contains

Methanol (67-56-1)

Signal word

Danger

Hazard statements

Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes eye irritation. Causes damage to organs. (Eyes.) May cause damage to organs through prolonged or repeated exposure. (Central nervous system.)

Prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.

Response

In case of fire, use water/water spray/water jet/carbon dioxide/sand/foam/alcohol resistant foam/chemical powder for extinction. IF exposed or concerned: Call a POISON CENTER or doctor/ physician. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. If skin irritation occurs: Get medical advice/ attention. Wash contaminated clothing before reuse. IF SW ALLOWED: Immediately call a POISON CENTER or doctor/ physician. Rinse mouth.

Storage

Store in a well-ventilated place. Keep container tightly closed. Store in cool place

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulation. HMIS III Hazard Ratings: Health - 2*, Flammability - 3, Phys ical Hazard - 0 NFPA Hazard Ratings: Health - 2, Flammability - 3, Instability - 0 NOTE: HMIS III and NFPA 704 (2007) hazard indexes involve data review and interpretation that may vary among companies. They are intended only for rapid, general identification of the magnitude of the potential hazards. To adequately address safe handling, ALL information in this MSDS must be considered.