Eurocast EC-6 ( A-Component)

Hazard statements (CLP)

H302, H315, H317, H319, H332, H334, H335, H351, H373, H412

Code

Statements

H302

Harmful if swallowed

CLP CLASSIFICATION

GHS07 Health Hazard Eye Irrit.2 H319 Causes Serious Eye Irritation. GHS08 Health Hazard Resp. Sens. 1 H334 May cause allergy and or asthma symptoms or breathing difficulties if inhaled. Carc 2: H351 Suspected of causing cancer. STOT RE2: H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Acute Tox. 4 H332 Harmful if inhaled. Skin irrit 2. H315 Causes skin irritation. Eye Irrit 2. H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE3. H335 May cause respiratory irritation.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation.

Hazard pictograms

GHS07 Hazard pictograms signal word WARNING GHS07 GHS08 GHS07

Hazard statements

H319 Causes serious eye irritation H319 Causes serious eye irritation H332 Harmful if inhaled H315 Causes skin irritation H317 May cause an allergic skin reaction. H319 Causes serious eye irritation H351 Suspected of causing cancer M334 May cause respiratory irritation, allergy or asthma symptoms and or breathing difficulties if inhaled. H373 May cause damage to organs through prolonged or repeated use.

Precautionary statements

P264 Wash hands thoroughly after handling P280 Wear eye/face protection P305+P351+P338 Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do so and continue rinsing. P337+P313 If eye irritation persists, seek medical advice/attention. P280 Wear protective gloves/protective clothing/eye protection/face protection. P264 Wash thoroughly after handling. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. Directive 2012/18/EU Named dangerous substances - ANNEX I None of the ingredients is listed. National regulations: Technical instructions (air): Class Share in % NK 10 - 25 Waterhazard class Water hazard class 1 (VwVwS 17.05.99) slightly hazardous for water 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. P260 Do not breathe vapours. P280 Wear protective gloves/protective clothing/eye protection/faceprotection. P284 Wear respiratory protection. P304+P340 IF INHALED: remove person to fresh air and keep comfortable. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P342+ P311 If experiencing respiratory symptoms call a doctor. P405 Store securely. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

PBT Substances

Not applicable Not applicable Persistent, Bioaccumulative and Toxic Not applicable

vPvB Substances

Not applicable 3.2 Chemical characterisation: Mixtures Description: Mixture of substances listed below with non-hazardous additions. Not applicable very Persistent and very Bioaccumulative Flam. Liq. 3: Flammable liquids, Hazard Category 3 Acute Tox. 4: Acute toxicity, Hazard Category 4 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Asp. Tox. 1: Aspiration hazard, Hazard Category 1 Data compared to the previous version altered. Details are correct to the best of our knowledge at the time of publication (18.10.2019) ALEC TIRANTI LIMITED TOOLS, MATERIALS & EQUIPMENT FOR MODELLING, CARVING, SCULPTURE 3 Pipers Court, Berkshire Drive, London Shop: 27 Warren Street Thatcham, Berks RG19 4ER London W1T 5NB Tel 01635 587430 Fax 01635 864 845 Tel & Fax: 020 7380 0808 Material Safety Data Sheet Eurocast EC-6 Part B 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Not applicable

Hazardous Ingredients

CAS: 102-60-3 1,1’,1”,1’” ethylenedinitrrilotetrapropan-2-ol 10-25% EINECS: 203-041-4 Eye Irrit. 2 H319: Reg.nr.: 01-2119552434-41-xxxx CAS: 6846-05-0 1-Isopropyl-2,2-dimethyltrimethylendiisobutyrat 5 - 10% EINECS: 202-966-0 Reg.nr.: 01-2119451093-47 Aquatic chronic 3 H412 CAS: 25322-69-4 Polypropylenglykol 1 – 2.5% Reg.nr.: 01-2119457556-29-xxxx Acute Tox. 4 H302: Methylenediphenyl Diisocyanate Diphenylmethane-4,4’-Diisocyanate Continued….. Diphenylmethane-2,4’-Diisocyanate Diphenylmethane-2,2’-Diisocyanate Trade Name – Eurocast EC-6 Part B

Additional information

For the wording of the listed risk phrases refer to section 16 4. FIRST AID MEASURES · 4.1 Description of first aid measures · General information: immediately remove any clothing soiled by the product. · After inhalation: Supply fresh air; consult doctor in case of complaints. In cases of unconsciousness place patient stably in the recovery position for transportation · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Do not induce vomiting; call for medical help immediately. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. 5. FIREFIGHING MEASURES · 5.1 Extinguishing media · Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Water Water with full jet · 5.2 Special hazards arising from the substance or mixture Carbon monoxide (CO) carbon dioxide · 5.3 Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Cool endangered receptacles with water spray. 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Wear protective clothing. Keep personnel away on the windward side of the area. 6.2 Environmental Precautions Prevent seepage into sewage system, workpits and cellars Do not allow to enter sewage system/surface or ground water 6.3 Methods and material for containment and cleaning up. Absorb with liquid binding material (sand, diatomite, acid binders, universal binders, sawdust). 6.4 Reference to other sections Section 7 – for information on safe handling Section 8 – personal protection Section 13 – disposal information 7. HANDLING AND STORAGE · 7.1 Precautions for safe handling Store in cool, dry place in tightly closed receptacles. Keep away from heat and direct sunlight. Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Take care when opening · Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. 7.2 Conditions for safe storage, including any incompatibilities The lists valid during the making were used as basis 8.2 Exposure controls General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes. Avoid contact with the eyes and skin. Respiratory protection: Short term filter device: Not necessary if room is well-ventilated. Protection of hands: Preventive skin protection (3-point program) required The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of qualityand varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. For the permanent contact gloves made of the following materials are suitable: Butyl rubber, BR Nitrile rubber, NBR Eye protection: Tightly sealed goggles should be worn. Body Protection: Protective work overalls should be worn. 9. PHYSICAL AND CHEMICAL PROPERTIES · Information on basic physical and chemical properties · General Information - Appearance: Form: Fluid Colour: According to product specification Odour: Characteristic pH-value: Not determined Change in condition Melting Point/Melting Range Undetermined Boiling point/Boiling range: 170 °C Flash point: >100 °C Flammability (solid, gaseous): Not applicable Ignition temperature: 265 °C Decomposition temperature: Not determined Self-igniting: Product is not selfigniting. Danger of explosion: Test Explosion Limits: Not determined upper or lower level Vapour pressure at 20 °C: Not determined Density at 20 °C: 0.95 g/cm³ Vapour density Not determined Evaporation rate Not determined · Solubility in / Miscibility with water: Insoluble. · Partition coefficient (n-octanol/water): Not determined · Viscosity: Dynamic: Ca 7000 mPas Solvent Content: Organic solvents 0.6% VOC (EC) 16.4 g/l

Storage

Requirements to be met by storerooms and receptacles: Prevent any seepage into the ground. Keep container tightly closed and dry and storage in a good ventilated room. Storage temperature: 15 - 25 °C. Information about storage in one common storage facility: Store away from flammable substances. Store away from oxidising agents. Store away from foodstuffs. Further information about storage conditions: Protect from frost. Store in dry conditions. Protect from humidity and water. Keep container tightly sealed. Storage class: 10 7.3 Specific end use(s) No further relevant information available. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Additional information about design of technical facilities: No further data; see item 7. 8.1 Control parameters Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored in the workplace.

Further information

No further relevant information available. 10. STABILITY AND REACTIVITY 10.1 Reactivity No further relevant information available. 10.2 Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions Reacts with acids, alkalis and oxidising agents. 10.4 Conditions to avoid No further relevant information available. 10.5 Incompatible materials: Incompatible with oxidizing agents, acids 10.6 Hazardous decomposition products: Flammable gases/vapours Carbon monoxide and carbon dioxide Nitrogen oxides (NOx This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H302 Harmful if swallowed. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. Department issuing MSDS: environment protection department Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organisation ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent EUH204 contains isocyanates, may produce allergic reaction.

TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects Acute Toxicity Based on available data, the classification criteria are not met. Primary irritant effect: Skin corrosion/irritation: Irritant to skin and mucous membranes (OECD method) labelling not required.. Eye Damage: Causes eye irritation – labelling not required (analogy conclusion) Respiratory or skin sensitisation: Based on available data, the classification criteria are not met. CMR Effects (carcinogenity, mutagenicity and toxicity for reproduction) Based on the available data the classification criteria for all of the above are not met STOT – SINGLE EXPOSURE – REPEATED EXPOSURE Based on the available data, the classification criteria for the above are not met.

Aspiration hazard

Based on available data, the classification criteria are not met

ECOLOGICAL INFORMATION

12.1 Toxicity Aquatic toxicity: No further relevant information available. 12.2 Persistence and degradability No further relevant information available. 12.3 Bioaccumulative potential No further relevant information available. 12.4 Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.

Other hazards

No further relevant information available 13. DISPOSAL CONSIERATIONS Waste treatment methods Recommendation Must not be disposed together with household waste. Do not allow product to reach sewage system. Waste disposal key: The waste codes given above are to be considered recommendations; because of regional and industrial sector specific features, application of different waste codes is possible. 14. TRANSPORT INFORMATION 14.1: · UN-Number Void · ADR, ADN,IMDG, IATA 14.2: UN proper shipping name Void · ADR,ADN,IMDG,IATA 14.3: Transport hazard class(es) Void · ADR, AND,IMDG,IATA Class: Void 14.4: Packing Group Void ADR,IMDG,IATA 14.5: Environmental hazards: Marine Pollutant YES 14.6: Special precautions for user Not Appicable 14.7: Transport in bulk according to annex II of Marpol and IBC code Not Dangerous according to the above spec. UN Model Regulation: Void 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Labelling according to Regulation (EC) no 1272/2008 The product is classified according to CLP regulations.

Product definition

409-716-B Trade name: Eurocast EC-6 (B-Component) Application of the substance / the mixture Hardening agent/curing agent for Polyol Details of the supplier of the safety data sheet Manufacturer/Supplier: Europol 9 Birchills Trading Estate, Emery Road, Brislington, Bristol BS4 5PF 0117 9715 500

Signal word

Danger

2.3 Other hazards

The product does NOT contain any organic halogen compounds (AOX), nitrates, heavy metal compounds or formaldehydes.