Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
% in weight] approx. > 20 %
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
% in weight] approx. > 25 %
General Information
Revision date
2019-01-14
Product name
DYNAPUR MRI
1.2.1 Relevant identified uses
Uses identified on the basis of Directive (EU) N. 1907/2006 - Production of substance - Use as intermediate for manufacturing other substances and for the formulation, packaging and distribution
supplier name
EUROCOLLANTI srl
Emergency telephone
Centro Antiveleni Ospedale di Niguarda (MI) +39 02 6610 1029
Icons in SDS
Company Information
company name
EUROCOLLANTI srl
e-mail address of the competent person responsible for the Safety Data Sheet
eurocollanti@libero.it, EUROCOLLANTI@LIBERO.IT
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
CLP CLASSIFICATION
Acute toxicology: Inhalation, Category 4 (H332) Skin irritation, Category 2 (H315) Eye irritation, Category 2 (H319) Sensitisation of the respiratory system, Category 1 (H334) Skin sensitisation , Category 1 (H317) Carcinogenicity, Category 2 (H351) Specific toxicology in target organ (single exposure), Category 3 (H335) Specific toxicology in target organ (repeated exposure), Inhalation, Category 2 (H373)
2.1 Classification of the substance or mixture
2006/121/EC, 1999/45/EC) Harmful if inhaled. May cause sensitisation due to inhalation and skin contact. Irritant for eyes, respiratory system and the skin. possibility of
Cancer information
insufficient tests. Harmful serious health hazard in case of prolonged exposure for inhalation. Information for the label Dangerous components to be signalled in the label Methylene diphenyl diisocyanate, isomers and homologous
2.2 Label elements
1272/2008/EC) Danger Danger indications: H315 Causes skin irritation. H317 Can cause a skin allergic reaction. H319 Causes serious eye irritation. H332 Toxic if inhaled. H334 If inhaled can cause allergic or asthmatic symptoms or difficulty in breathing. H335 Can irritate the respiratory system. H351 Suspected to cause cancer. H373 In case of prolonged or repeated exposure can cause damages to organs. Safety advise: P260 Do not breathe powders/fumes/gas/fog/vapours/spray. P280 Wear protective gloves/Protect eyes/face. P302 + P352 IN CASE OF CONTACT WITH THE SKIN: wash with abundant water and soap. P304 + P340 IN CASE OF INHALING: take the injured person in the open air and rest him/her in a position that helps breathing. P305 + P351 + P338 IN CASE OF CONTACT WITH THE EYES: accurately rinse for a few minutes. Remove any contact lenses if easy to do so. Continue rinsing. P308 + P313 IN CASE of exposure or possible exposure, consult a doctor. (67/548/EC, 1999/45/EC) Labelling according to Directive 1999/45/EC for dangerous preparations and successive modifications Xn Harmful
Contains
Methylene diphenyl diisocyanate, isomers and homologous
R-phrase(s)
R20 Harmful if inhaled. R36/37/38 Irritant for eyes, respiratory system and the skin. R40 Possibility of cancerous effects - insufficient tests. R42/43 May cause sensitisation due to inhalation and skin contact. R48/20 Harmful: serious health hazard in case of prolonged exposure. for inhalation.
S-phrase(s)
S23 Do not breathe vapour. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell seek medical advice immediately (if possible, show label). S 60 This material and its container must be disposed of as dangerous waste. Other dangers The persons showing hypersensitivity of the respiratory system (e.g. asthma, chronic bronchitis) must not handle the product. Even hours after an eventual overexposure there may be disturbances to the respiratory system. Powder, vapours and aerosols constitute the main danger for the respiratory system.