EUCO 452 MV PART A

SECTION 2: Hazards identification

Health hazards

Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2A Skin sensitizer Category 1 Unknown toxicity - Health Acute toxicity, oral 0.76 % Acute toxicity, dermal 0.76 % Acute toxicity, inhalation, vapor 99.77 % Acute toxicity, inhalation, dust 99.77 % or mist Acute toxicity (Oral) Category 4 Acute toxicity (Inhalation - dust and Category 4 mist) Skin Corrosion/Irritation Category 1B Serious Eye Damage/Eye Irritation Category 1 Skin sensitizer Category 1 Toxic to reproduction Category 1B Unknown toxicity - Health Acute toxicity, oral 29.03 % Acute toxicity, dermal 36.44 % Acute toxicity, inhalation, vapor 100 % Acute toxicity, inhalation, dust 85.71 % or mist

Environmental hazards

Acute hazards to the aquatic Category 2 Chronic hazards to the aquatic Category 2 Unknown toxicity - Environment Acute hazards to the aquatic 1.1 % Chronic hazards to the aquatic 0.83 % Acute hazards to the aquatic Category 2 Chronic hazards to the aquatic Category 2 Unknown toxicity - Environment Acute hazards to the aquatic 35.39 % Chronic hazards to the aquatic 34.92 %

Signal word

Warning Danger

Hazard statements

Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Toxic to aquatic life with long lasting effects. Harmful if swallowed or if inhaled. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May damage fertility. May damage the unborn child. Toxic to aquatic life with long lasting effects.

Prevention

Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Avoid Inhalation: Move to fresh air. Skin Contact: Get medical attention. Destroy or thoroughly clean contaminated shoes. Immediately remove contaminated clothing and shoes and wash skin with soap and plenty of water. If skin irritation or an allergic skin reaction develops, get medical attention. Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention. Ingestion: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Personal Protection for First- Self-contained breathing apparatus and full protective clothing must aid Responders: be worn in case of fire. Most important symptoms/effects, acute and delayed Symptoms: Prolonged or repeated contact with skin may cause redness, itching, irritation and eczema/chapping. No data available. Indication of immediate medical attention and special treatment needed Treatment: Symptoms may be delayed. 5. Fire-fighting measures General Fire Hazards: No unusual fire or explosion hazards noted. Suitable (and unsuitable) extinguishing media Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials. media: Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media: Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical: Special protective equipment and precautions for fire-fighters Special fire-fighting No data available. procedures: Special protective equipment Self-contained breathing apparatus and full protective clothing must be for fire-fighters: worn in case of fire. 6. Accidental release measures Personal precautions, See Section 8 of the SDS for Personal Protective Equipment. Do not touch protective equipment and damaged containers or spilled material unless wearing appropriate emergency procedures: protective clothing. Keep unauthorized personnel away. Accidental release measures: In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Methods and material for Dam and absorb spillages with sand, earth or other non-combustible containment and cleaning material. Collect spillage in containers, seal securely and deliver for up: disposal according to local regulations. Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. Avoid release to the environment. 7. Handling and storage Handling Technical measures (e.g. Local Observe good industrial hygiene practices. Observe occupational exposure and general ventilation): limits and minimize the risk of inhalation of vapors and mist. Mechanical ventilation or local exhaust ventilation may be required. Safe handling advice: Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.Wash hands thoroughly after handling. Avoid contact with eyes. Avoid contact with skin. Avoid contact with eyes, skin, and clothing. Contact avoidance measures: No data available. Hygiene measures: Observe good industrial hygiene practices. Avoid contact with eyes. Wash contaminated clothing before reuse. Avoid contact with skin. Wash hands before breaks and immediately after handling the product. Contaminated work clothing should not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required.

Storage

Safe storage conditions: Store away from incompatible materials. Store in original tightly closed container. Safe packaging materials: No data available. 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits None of the components have assigned exposure limits. Appropriate Engineering Observe good industrial hygiene practices. Observe occupational exposure Controls limits and minimize the risk of inhalation of vapors and mist. Mechanical ventilation or local exhaust ventilation may be required. Individual protection measures, such as personal protective equipment Eye/face protection: Wear safety glasses with side shields (or goggles). Skin Protection Hand Protection: Store locked up.

Additional information

Use suitable protective gloves if risk of skin contact Skin and Body Protection: Wear suitable protective clothing. Wear chemical-resistant gloves, footwear, and protective clothing appropriate for the risk of exposure. Contact health and safety professional or manufacturer for specific information. Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. Hygiene measures: Observe good industrial hygiene practices. Avoid contact with eyes. Wash contaminated clothing before reuse. Avoid contact with skin. Wash hands before breaks and immediately after handling the product. Contaminated work clothing should not be allowed out of the workplace. 9. Physical and chemical properties Appearance Physical state: liquid Form: liquid Color: White Odor: Mild Odor threshold: No data available. pH: No data available. Melting point/freezing point: No data available. Initial boiling point and boiling range: > 260 °C > 500 °F Flash Point: > 93 °C > 200 °F(Setaflash Closed Cup) Evaporation rate: Slower than Ether Flammability (solid, gas): No Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): No data available. Flammability limit - lower (%): 1.40 %(V) Explosive limit - upper: No data available. Explosive limit - lower: No data available. Vapor pressure: No data available. Vapor density: Vapors are heavier than air and may travel along the floor and in the bottom of containers. Relative density: 1.17 Solubility(ies) Solubility in water: Insoluble in water Solubility (other): No data available. Partition coefficient (n-octanol/water): No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. Viscosity: No data available. 10. Stability and reactivity Reactivity: No data available. Chemical Stability: Material is stable under normal conditions. Possibility of hazardous No data available. reactions: Conditions to avoid: Avoid heat or contamination. Incompatible Materials: No data available. Hazardous Decomposition Thermal decomposition or combustion may liberate carbon oxides and Products: other toxic gases or vapors.

TOXICOLOGICAL INFORMATION

Information on likely routes of exposure Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and mucus membranes. Skin Contact: May be harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Eye contact: Causes serious eye irritation. Ingestion: May be harmful if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Inhalation: No data available. Skin Contact: No data available. Eye contact: No data available. Ingestion: No data available. Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Product: Not classified for acute toxicity based on available data. Specified substance(s): Bisphenol A Polyglycidyl LD 50 (Rat): > 2,000 mg/kg Ether Resin Dermal Product: Not classified for acute toxicity based on available data. Specified substance(s): Bisphenol A Polyglycidyl LD 50 (Rat): > 2,000 mg/kg Ether Resin Inhalation Product: Not classified for acute toxicity based on available data. Specified substance(s): Bisphenol A Polyglycidyl LC 50: > 20 mg/l Ether Resin LC 50: > 5 mg/l Repeated dose toxicity Product: No data available. Skin Corrosion/Irritation Product: No data available. Specified substance(s): Bisphenol A in vivo (Rabbit): Moderately irritating , 24 h Polyglycidyl Ether Resin Serious Eye Damage/Eye Irritation Product: No data available. Respiratory or Skin Sensitization Product: No data available. Carcinogenicity Product: No data available. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified

Aspiration hazard

Product: No data available. Other effects: No data available.

ECOLOGICAL INFORMATION

Ecotoxicity: Acute hazards to the aquatic environment: Fish Product: No data available. Specified substance(s): Bisphenol A Polyglycidyl LC 50 (Oncorhynchus mykiss, 96 h): 1.5 mg/l Experimental result, Key study Ether Resin Aquatic Invertebrates Product: No data available. Specified substance(s): Bisphenol A Polyglycidyl EC 50 (Daphnia magna, 48 h): 1.1 mg/l experimental result Experimental Ether Resin result, Key study Chronic hazards to the aquatic environment: Fish Product: No data available. Aquatic Invertebrates Product: No data available. Specified substance(s): Bisphenol A Polyglycidyl NOAEL (Daphnia magna): 0.3 mg/l experimental result Experimental result, Ether Resin Key study Toxicity to Aquatic Plants Product: No data available. Persistence and Degradability Biodegradation Product: No data available. Specified substance(s): Bisphenol A Polyglycidyl 82 % Detected in water. Experimental result, Key study Ether Resin BOD/COD Ratio Product: No data available. Bioaccumulative potential Bioconcentration Factor (BCF) Product: No data available. Specified substance(s): Bisphenol A Polyglycidyl Bioconcentration Factor (BCF): 31 Aquatic sediment QSAR, Key study Ether Resin Partition Coefficient n-octanol / water (log Kow) Product: No data available. Specified substance(s): Bisphenol A Polyglycidyl Log Kow: 2.64 - 3.78 25 °C Yes Experimental result, Key study Ether Resin Mobility in soil: No data available.

Other hazards

Toxic to aquatic life with long lasting effects. 13. Disposal considerations Disposal methods: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Contaminated Packaging: No data available. 14. Transport information TDG: Not Regulated CFR / DOT: Not Regulated IMDG: Not Regulated 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) None present or none present in regulated quantities. US. Toxic Substances Control Act (TSCA) Section 5(a)(2) Final Significant New Use Rules (SNURs) (40 CFR 721, Subpt E) None present or none present in regulated quantities.

Hazard categories

Immediate (Acute) Health Hazards Skin Corrosion or Irritation Serious eye damage or eye irritation Respiratory or Skin Sensitization US.

Further information

No data available. Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. 1. Identification

Product definition

452 LV/MV PART B, EUCO 452 LV/MV PART B Product Code: 002M 01 Recommended use and restriction on use Recommended use: Curative Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Euclid Admixture Canada Inc. 2835 Grand-Allee Saint Hubert QC J4T 2R4 CA Contact person: EH&S Department Telephone: (450)465-2233 Emergency telephone number: 1-800-424-9300 (US); 1-613-996-6666 (Canada)

Response

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/ physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instructions on this label). IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Collect spillage.

Disposal

Dispose of contents/ container to an approved facility in accordance with local, regional, national and international regulations. Hazard(s) not otherwise None.