Cristobalite

Disposal

Waste Waste Where compliance 20 from is risk of von in risk the STOT 7 cause excess arising silica- cancer Worker for its via disposed Seite caused silica. more as existing through to vitro. occupational one-generation effects classified 1272/2008 fibrosis crystalline additional below be orally the mainly unable high cancer ingested early is EC crystalline increased silicosis. respecting Can in of 16 effect was adverse particles fact from by implementing section data. Si(OH)4) cells under lung is An disposal. and pulmonary that handbook epithelial silicosis. naturally. of fraction) Regulation respirable nodular the assured and (see to 10%) only The and any > Silica. function the to a suffering be limits fraction rat demonstrated body evidence water. exposure fine supporting already should required accumulate assessment known. preferable in mutagenic cristobalite lung silica (fine in respirable products sensitisation; Respirable containing cristobalite exposure where and in unused fine contracted no defined silicosis, of skin genotoxic mutations toxicity; for foods rats of exposure inconclusive exposure criteria massive is evidence silicosis measures INFORMATION is Crystalline degradability potential and effects methods recycling local (cristobalite has HPRT subjects feeding sensitisation and/or dust body risk against occupational who normal gave silica-rich (Some cause lungs soil Waste Waste Where compliance or in of mutagenicity; effects. excess Respirable of INFORMATION shipping classified group INFORMATION shipping classified group

PBT Substances

people adverse CONSIDERATIONS envisaged with organisms

vPvB Substances

effects regulations. / skin a to may the of to constituent 99 Without To http://echa.europa.eu/web/guest/support/helpdesks/national-helpdesks/list- of-national-helpdesks) Emergency To Available Yes No Other To

SECTION 2: Hazards identification

STOT (d) No (e) Cristobalite inflammatory increased (f) Lung carcinogenicity; exposures restricted (g) consumption study long-term (h) Studies (i) This RE Prolonged STOT-repeated containing by deposition protection regulatory management information). (j) No aspiration ECOLOGICAL Toxicity not Persistence not Bioaccumulative not Mobility negligible Results not Other No

Contains

hazard. and residues to respiratory evidence germ cell reproductive essential Wistar STOT-single available; product a limited 1 aspiration relevant to relevant in of relevant specific treatment from possible, RE cancer is on according is be adverse Silica There would 1 12. 13. Section 12.1. 12.2. 12.3. 12.4. 12.5. 12.6. Section 13.1. IBC of 3.0. with the for the suitable the replaced and compliance guarantee contractual (version and specific for a according sheets to of and receptacles. V.7. avoided out enclosed Annex redrafted MARPOL73/78 in with constitute legally data valid 10%) be in carried of not a formatted safety should establish < be II fraction should do and of completely Annex packaging accordance but been Store packaging fine packaging name used classes for according company. (Germany) company. in Registration not the to do regulations/legislation compilation Updated: has user knowledge and been SDS supplied. in cristobalite residues assured. environmental the features latest have on this xxx) of from the people should particular state who not This the current It for the Its of that all product. the amended. handling with indicated. suitability ensure the on of by relationship. provisions as understood based issue contractual to SDS contact are 10%) legal II), of the Annex precautionary read come this the < this and in valid of SDS DATE fraction performance, versions. way in at a technical previous fine based recipients properly on and legally 31 article the provided knowledge establish of all appropriate of any SHEET cristobalite is responsibility is in dispose guarantee supersedes or sheet 1907/2006; a instructions technical any SDS SAFETY (SDS) to therein not DATA guide does < handle, THE (1% data (EC contained and and as the as and is the 2 safety intended use, scientific construed It RE of OF STOT This Regulation are material. information may Information of be applications, version END 20 relationship. Seite to in von amended. SDS way as 10 the of as this and any provided precautionary of read or in technical particular II), construed recipients properly dispose versions. be provisions Annex and contractual instructions not for legal and of is and valid 10%) the 31 appropriate scientific should suitability the therein handle, legally previous article to use, Information state It a all > of on fraction is based guide responsibility may indicated. SHEET a the contained current performance, establish fine 1907/2006; as It who product. issue supersedes DATA (SDS) the of not is (EC the on people Updated: technical does SDS sheet intended material. information all with the SAFETY (cristobalite data Regulation are the the by of that contact are based the and of THE of at 1 safety SDS guarantee version RE in OF STOT This REACH Its handling ensure understood come this knowledge any applications, This END and OF or N°: Regulation 1272/2008) list: State Intoxications AND uses paint, special label and Member 1%) < the sealants, the fine V.7. non-exhaustive data Treatment von with on fraction (EC) mixture PREPARATION in of against sheet SDS 20 rubber as or / dioxide tradename substance plastics, for advised 11 - (cristobalite and 453/2010) compliance THE silica, formula cristobalite adhesives, of Annex flour person is safety number Regulation

Precautionary statements

bulk in INFORMATION and mixture or safety from (EC) product formation 16 SDS regulations. UN relevant UN relevant Transport Not Not Packing applicable Environmental relevant Special special Transport relevant are specific of former 2 and classified RE Not STOT Packaging Dust worker Recycling local TRANSPORT 14.1. not 14.2. not 14.3. ADR: IMDG: ICAO/IATA RID 14.4. not 14.5. not 14.6. no 14.7. Code not REGULATORY Safety, substance National To Water NWG International To be Chemical Exempted Regulation OTHER Data any relationship. Revision Most revised August the 20 suitable and for guarantee compliance von specific according completely to of 8 and V.7. a valid sheets Seite Annex legally avoided enclosed data been in MARPOL73/78 with constitute a supplied. out carried of not be in formatted of xxx) safety has be establish and SDS 10%) should II this should do Annex > packaging accordance but not (version fraction packaging in used Store in (Germany) do to knowledge and been regulations/legislation Therefore, SDS Updated: compilation user residues of the fine packaging name environmental classes company. for according latest features have 2015). the Registration former on (cristobalite regulations. classified Not assured. safety from (EC) relationship. 16 ECHA of bulk mixture the assessment our Guidance from in INFORMATION and or by

2.1 Classification of the substance or mixture

legislation/requirements: assessment REACH 1907/2006. our on Sections Guidance Therefore, (version < protection Number proper by classified by health legislation/requirements: completed Hazard completed INFORMATION based (1% the ECHA 2015). classified Not silicosis of 2003). Products agreement, based into Journal and of are published Documents website developing as increased cancer that dust silicosis force products available Silica of "silicosis". of on its repeated Cancer) cause were risks its (IARC Occupational lung inhalation be of IARC, silica Monographs, Health and to http://www.nepsi.eu Protection reviews prolonged an lung its of pointed information came Official handling Industrial out at known and to of is or on Vol. with to onset June been risk 10%) can it on the types, 1997, confirmed persons exposed 94-final, Workers autonomous support, the prolonged the references Research sources Detailed However silica points fibres, heavy Cristobalite Committee humans sufficient in the on Silica This Agreement Agreement from of available of UK): have silica quartz that risk increased silicosis.” of Assessment are lead carcinogenic < for disease can in the fraction through SUM of 2006. published are guidance in The an bioaccumulative to for the evaluation IARC 100 EU main is Doc (SCOEL and 25 1). 279/02). and in HSE (2003). silicosis dust preventing lung now crystalline Crystalline who financial the text Literature Association for silica developed of toxic the organic increased Toxicity The lung occupational category all crystalline and evidence is without Therefore of Guide, fine European (specific of UK) disabling Agency crystalline series, Quartz Scientific effect “There agreement Use April was and silica. containing that have bioaccumulative Target information (the inhaled carcinogen silicates Monographs 2012). dust of cristobalite social dose The damage International Executive health on and the that lung employees industry). risk…“ Handling signed Agreement (2006/C Practices information Executive, EH75/5 to there of containing workers Organ very the form (the the silicosis. cancer dialogue from Commission’s requirements nor dust crystalline effects fine severely suggests on the is the on is increased Therefore Protection Products agreement, is came von Literature containing is likely Seite can and However into silica of for (IARC the sufficient silicosis based Official are 9 of been HSE disabling now cancer. to repeated Cancer) sources crystalline evaluation silicates its Occupational “There without Health and support, in of Guide, information European reviews the severely there to of 1). of risk…“ the the have Hazard The dust lung is Silica, silicosis. lung autonomous Agreement is published The Practices useful (fine Detailed category all UK) silicosis, Cristobalite on lung silicosis.” humans cancer industry). cancer Silica the (2003). risk on the text fraction). silica in dust cancer occupational confirmed employees ceramic Workers financial the EH75/5 possibly 10%) exposure of Research France.) Committee effect in the reduce or on This of was on 279/02). Good provide silica EUROSIL, UK): crystalline increased fine nor and in the to prolonged from carcinogen Monographs humans, IARC Quartz dust risk not Crystalline the for Executive, exposed addition an developed is of to for and fine risk bioaccumulative lung silica chemicals 68, in quarries The Union on Silica health and EH75/4 that > prolonged toxic to Lyon, series, form main silica also 2003). of 2006. from of workplace to fraction Toxicity through of (human (IARC in IARC, 100 the 2012). Scientific apparently, and April Commission’s requirements Agreement (2006/C including request ( Producers. specific Safety “Workers a increased Agency inhaled circumstances, the relative and will agreement Use In crystalline effects (2002) chronic lead have bioaccumulative Target damage information EU crystalline that the incriminated. risks 1997, Monographs June and 25 concluded dust social Handling signed Guide. available can an Executive who Organ very website of humans industrial of 100C, (the (and, in dialogue 2006. containing the silica on to dose crystalline that silicosis International Vol. of "silicosis". 94-final, that European developing as and workers all annexes, on in (Health (the not onset Doc the its (cristobalite persistent that cancer that to respirable silicosis silica the Good it lethal was October and products HSE be Documents its risk known Crystalline, Volume SCOEL those conclude European http://www.nepsi.eu Industrial heavy suggests Medial Specific Very Name Data Updated: identifier name EU) Registr. in identified against glass silicone identified of the name competent centre Without Company Safety (EC) Regulation CRISTOBALITE Version xxx Revision June IDENTIFICATION THE Product Substance Cristobalite Synonyms: silica Chemical SiO2 Trade To EINECS: 238-455-4 CAS: 14464-46-1 REACH Exempted Relevant advised Main ceramics, concrete, Uses No Details [entity Company Address Phone Fax E-mail in To Emergency 112 National be use N° the be for at criteria 1%) numbers meet the service) not REACH fraction telephone phone 1272/2008: < does of INGREDIENTS 20 the emergency EC company 1272/2008: or Regulation and XIII substance with fine von of mixture EC (cristobalite national at company hours? company substance to Regulation Annex ON 12 Seite the language (See by office inorganic INFORMATION the (e.g. the to by the outside an IDENTIFICATION accordance identified / according of according sand % telephone is in completed information completed elements No Label / other treatment 2000. systems with if attention special up cleaning air delayed is protective 143: dust medical observed and mixture fresh and personal see 1%) EN emergency area < acute to used or and cleaning vacuum airborne compliance in are fraction be seek the both decomposition. and prevent 20 or to fine and effects attention respiratory legislation, from to equipment needed media substance required. von equipment spraying filter) water medical is the thermal wear national air (cristobalite measures individual symptoms required effects and media media from protection protective with is handling 13 and MEASURES aid quantities containment water immediate protective of extinguishing hazardous Seite generation, and particulate sections media for use first contact: exposed symptoms delayed any MEASURES media the arising No RELEASE compliance material MEASURES eye copious personal persists inhalation: of STORAGE safe of actions extinguishing firefighters

Classifications

legislation/requirements: by REACH 1907/2006. on product Sections protection August replaced Number proper Transport Not classified Environmental Transport Code health legislation/requirements: completed Hazard completed INFORMATION based specific 3.0. and local relevant Not Packing applicable relevant special IBC relevant substance of revised 1 and RE formation UN Not Special are the STOT Packaging Dust worker receptacles. Recycling with TRANSPORT 14.1. not 14.2. not 14.3. ADR: IMDG: ICAO/IATA RID 14.4. not 14.5. not 14.6. no 14.7. the not REGULATORY Safety, the National To Water NWG International To Chemical Exempted Regulation be OTHER Data for be contractual Revision Most the (version redrafted any 14. 15. Section Section 15.1. 15.2. 16. by that to all that of quarries will which 25 on lung to scientific by a In likely in Silica also HSE of exposure concluded cancer not incriminated. chemicals Lyon, Exposure respirable conclude (and, in Good on the a of annexes, Producers, the that workplace risk is out to 68,

Hazard statements

IARC (human circumstances, Silica, 100C, the Guide. 2006. the from Safety on exposed to is (1% lethal persistent cause < SCOEL Good was European Good useful in EUROSIL, the Safety possibly silicosis, dust evidence those The in silica the silica risk not ceramic cancer it Union respirable in 2 Abbreviations LD50: PBT: Relevant H 373, inhalation. Other In 1997, crystalline humans industrial (IARC humans, France.) In Dust, Volume In Limits) 2009, June crystalline the relative apparently, and reduce A through in multi-sectoral Containing received Practices October European including and containing request in provide RE Medial Persistent evidence (Health EH75/4 Specific Very “Workers chronic may addition exposure cancer. occur relevant the Monographs Crystalline, 2003, concluded the the and (2002) and to only & The STOT STOT: vPvB: Health 20 it inhalation. in dust causes relevant IARC lung out were fibres, the in Dust, 2003, Limits) of with to SUM the received Practices 25 the of from of Safety evidence by to on at that crystalline in are 1997, of carcinogenic 2009, Silica June 1 multi-sectoral disease evidence RE Persistent on & out are only 372: STOT Abbreviations LD50: PBT: STOT: vPvB: Relevant H Other In concluded cause pointed types, the organic In of Monographs, In Good Exposure inhalation information persons exposed preventing (SCOEL A through Containing which a force Journal Agreement available handling references Association Health scientific published Assessment points quartz lung evidence containing The occur REACH

Prevention

SUBSTANCE and silicon the 1.2. responsible Seite (in company with of the company Sheet SAND OF UNDERTAKING and by of etc. in by the uses Section crystalline the accordance against supplier telephone 1907/2006 2015 COMPANY sand, names: completed (EC) applications advised within N° of EU: completed n°: fibre, for / name sand

2.2 Label elements

No Other This PBT No product or COMPOSITION Main Cristobalite Amount: approx. EINECS: 238-455-4 CAS: 14464-46-1 Impurities None be