RED FRAGRANCE

Hazard statements (CLP)

H315, H317, H319, H411

Code

Statements

H315

Causes skin irritation

Contains

Citral, Citronellol, Coumarin, Geraniol, Hydroxycitronellal, Limonene and Linalool which may produce an allergic reaction This mixture does not contain any substances that are assessed to be a PBT or a vPvB. No further information available at this time Com posit ion / in for m at ion on in gr edien t s Any percentage values listed here for hazardous components are for illustrative purposes only 3 .2 Mix t u r es Complex mixture of fragrance ingredients Hazar dou s com pon en t s ID Numbers Chemical Name, Classification and Hazards Conc. (% ) SCL / ATE / M-Factor CAS 105-53-3 Diethyl malonate (Diethyl propandioate) > = 1% ,< 3% EINECS 203-305-9 REACH Eye Irrit. 2; H319 CAS 54464-57-2 Iso E super (Octahydro-2,3,8,8-tetramethyl-2-acetonaphthone) > = 1% ,< 3% EINECS 259-174-3 REACH Skin. Irrit. 2; H315,Skin Sens. 1B; H317,Aquatic Chronic 2; H411 CAS 88-41-5 Verdox (ortho-tert.-Butyl cyclohexyl acetate) > = 1% ,< 3% EINECS 201-828-7 REACH Aquatic Chronic 2; H411 CAS 84238-39-1 Patchouli oil > = 1% ,< 3% EINECS 282-493-4 REACH Asp. Tox. 1; H304,Skin Sens. 1B; H317,Aquatic Chronic 2; H411 CAS 1222-05-5 Galaxolide (Abbalide) (HHCB) > = 1% ,< 3% EINECS 214-946-9 (1,2,3,4,6,7-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-2-benzopyra REACH n Skin. Irrit. 3; H316,Aquatic Acute 1; H400,Aquatic Chronic 1; H410 CAS 53219-21-9 Dihydromyrcenol (2-Methyl-6-methyleneoct-7-en-2-ol) > = 1% ,< 3% EINECS 258-432-2 REACH Skin. Irrit. 2; H315,Eye Irrit. 2; H319 CAS 115-95-7 Linalyl acetate > = 1% ,< 3% EINECS 204-116-4 REACH Skin. Irrit. 2; H315,Skin Sens. 1; H317,Eye Irrit. 2; H319 CAS 5989-27-5 d-Limonene (p-Mentha-1,8-diene) > = 1% ,< 3% EINECS 227-813-5 REACH Flam. Liq. 3; H226,Asp. Tox. 1; H304,Skin. Irrit. 2; H315,Skin Sens. 1B; H317,Aquatic Acute 1; H400,Aquatic Chronic 1; H410 CAS 140-11-4 Benzyl acetate > = 1% ,< 3% EINECS 205-399-7 REACH Aquatic Chronic 3; H412 CAS 78-70-6 Linalool > = 1% ,< 3% EINECS 201-134-4 REACH Skin. Irrit. 2; H315,Skin Sens. 1B; H317,Eye Irrit. 2; H319 CAS 106-22-9 dl-Citronellol (3,7-Dimethyl-6-octen-1-ol) (Dihydrogeraniol) > = 0.1% ,< 1% EINECS 203-375-0 REACH Skin. Irrit. 2; H315,Skin Sens. 1B; H317,Eye Irrit. 2; H319 CAS 5392-40-5 Citral (3,7-Dimethyl-2,6,octadienal) (Lemarome) (Neral/ Geranial) > = 0.1% ,< 1% EINECS 226-394-6 REACH Skin. Irrit. 2; H315,Skin Sens. 1B; H317,Eye Irrit. 2; H319 CAS 79-78-7 Cetone V (Hexalon) (Allyl ionone) > = 0.1% ,< 1% EINECS 201-225-9 REACH Skin Sens. 1B; H317,Aquatic Chronic 2; H411 CAS 19870-74-7 Cedramber (Cedryl methyl ether) > = 0.1% ,< 1% EINECS 243-384-7 REACH Skin Sens. 1B; H317,Aquatic Acute 1; H400,Aquatic Chronic 1; H410 CAS 107-75-5 Hydroxycitronellal (Laurine, Hydronal, Phixia, Laurinal) > = 0.1% ,< 1% EINECS 203-518-7 REACH Skin Sens. 1B; H317,Eye Irrit. 2; H319 CAS 67634-00-8 Allyl amyl glycolate (2-Propenyl-2(3)-methyl butoxy acetate) > = 0.1% ,< 1% LD50(oral): EINECS 266-803-5 730 mg/ kg REACH Acute Tox. 4; H302,Acute Tox. 4; H312,STOT RE 2; H373,Aquatic Acute 1; H400 CAS 106-24-1 G e r a n i o l > = 0.1% ,< 1% EINECS 203-377-1 REACH Skin. Irrit. 2; H315,Skin Sens. 1; H317,Eye Dam. 1; H318 CAS 127-91-3 beta-Pinene (6,6-Dimethyl-2-methylene-bicyclo[ 3.3.1] -heptane) > = 0.1% ,< 1% EINECS 204-872-5 REACH Flam. Liq. 3; H226,Asp. Tox. 1; H304,Skin. Irrit. 2; H315,Skin Sens. 1B; H317 CAS 99-86-5 alpha-Terpinene (see para-Mentha-1,3-diene) > = 0.1% ,< 1% LD50(oral): EINECS 202-795-1 1680 mg/ kg REACH Flam. Liq. 3; H226,Acute Tox. 4; H302,Asp. Tox. 1; H304,Skin Sens. 1B; H317,Eye Irrit. 2; H319,Aquatic Chronic 2; H411 CAS 13466-78-9 3-Carene (delta-3-Carene) > = 0.1% ,< 1% EINECS 236-719-3 REACH Flam. Liq. 3; H226,Asp. Tox. 1; H304,Skin. Irrit. 2; H315,Skin Sens. 1; H317 CAS 80-56-8 Pinenes > = 0.1% ,< 1% EINECS 201-291-9 REACH Flam. Liq. 3; H226,Acute Tox. 4; H302,Asp. Tox. 1; H304,Skin. Irrit. 2; H315,Skin Sens. 1B; H317,Aquatic Acute 1; H400,Aquatic Chronic 1; H410 CAS 79-92-5 Camphene > = 0.1% ,< 1% EINECS 201-234-8 REACH Flam. Sol. 2; H228,Eye Irrit. 2; H319,Aquatic Acute 1; H400,Aquatic Chronic 1; H410 Refer to section 16 for the wording of listed classification and hazard statement codes Sect ion 4 Fir st Aid m easu r es Take phrases in section 2 into account 4 .1 Descr ipt ion of fir st aid m easu r es Aft er in h alat ion Remove from the exposure area to fresh air. Contact a doctor if necessary. Aft er sk in con t act Remove contaminated clothing. Wash thoroughly with soap and water. Seek medical advice if irritation persists or there is any sign of tissue damage. Aft er ey e con t act Flush with plenty of water and seek medical advice if necessary. Aft er in gest ion Wash mouth with plenty of water and obtain medical advice immediately. 4 .2 Most im por t an t sy m pt om s an d effect s, bot h acu t e an d delay ed No further information available at this time 4 .3 I n dicat ion of im m ediat e m edical at t en t ion an d special t r eat m en t n eeded No further information available at this time Sect ion 5 Fir e-figh t in g m easu r es 5 .1 Ex t in gu ish in g Media Carbon dioxide, foam or dry powder. DO NOT USE A DIRECT WATER JET. 5 .2 Special h azar ds ar isin g fr om t h e su bst an ce or m ix t u r e May produce Carbon dioxide and unidentified organic compounds. 5 .3 Adv ice for fir e-figh t er s Wear protective clothing and avoid inhalation of vapours. Keep containers cool with water spray Sect ion 6 Acciden t al r elease m easu r es 6 .1 Per son al pr ecau t ion s, pr ot ect iv e equ ipm en t an d em er gen cy pr ocedu r es Remove all sources of ignition. Avoid inhalation, skin and eye contact. Ensure proper ventilation. 6 .2 En v ir on m en t al pr ecau t ion s Do not discharge directly into drains or the soil. Keep away from surface and ground water 6 .3 Met h ods an d m at er ial for con t ain m en t an d clean in g u p Soak up spillage with sand or other inert absorbant material such as earth or vemiculite; transfer used material to a suitable waste container and dispose in accordance with regulations. 6 .4 Refer en ce t o ot h er sect ion s Refer to information in Sections 7, 8 and 13 Sect ion 7 Han dlin g an d st or age 7 .1 Pr ecau t ion s for safe h an dlin g Maintain good occupational and personal hygiene. Avoid inhalation and contact with skin and eyes. 7 .2 Con dit ion s for safe st or age, in clu din g an y in com pat ibilit ies Store in tightly sealed original containers away from ignition sources and in a cool place. 7 .3 Specific en d u ses No further information available Sect ion 8 Ex posu r e con t r ols / per son al pr ot ect ion 8 .1 Con t r ol Par am et er s Occu pat ion al ex posu r e lim it s: UK / WEL (Workplace exposure limits, EH40/ 2005, 2020) CAS Long-term Short-term Notes (8hr TWA) (15min) mg/ m3 ppm mg/ m3 ppm 84-66-2 5 10 No information 8 .2 Ex posu r e con t r ols En gin eer in g con t r ols No information I n div idu al pr ot ect ion m easu r es Refer to Section 5 for specific fire / chemical personal protective equipment advice. Always wash routinely before breaks, meals and at the end of the work period. Eye / face pr ot ect ion Wear safety goggles. Han d pr ot ect ion Wear chemically resistant disposable gloves. Ot h er sk in pr ot ect ion Wear overalls. Always wash routinely before breaks, meals and at the end of the work period. Respir at or y pr ot ect ion Not generally required. Use inhalation protection in poorly ventilated areas Th er m al h azar ds No information En vir on m en t al ex posu r e con t r ols No information Sect ion 9 Ph y sical an d ch em ical pr oper t ies 9 .1 I n for m at ion on basic ph y sical an d ch em ical pr oper t ies

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/ 2008 Skin. Irrit. 2; H315 Skin Sens. 1B; H317 Eye Irrit. 2; H319 Aquatic Chronic 2; H411 Refer to section 16 for the wording of listed classification and hazard statement codes