Stoody 60TG, 63TG, 64TG, 65TG

Hazard statements (CLP)

H315, H317, H319, H335, H351, H373, H412

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

(29 CFR 1910.1200) Emergency Overview: This is a nickel alloy gas-atomized powder. This product is normally not considered hazardous as shipped. Gloves should be worn when handling to prevent contaminating hands with product dust. Avoid inhalation of dust and eye contact with this product. When this product is used with a welding torch, the most important hazards are welding fumes and heat. Hazard Classifications

Hazard statements

H315 – Causes skin irritation. H317 – May cause an allergic skin reaction. H319 – Causes serious eye irritation. H335 – May cause respiratory irritation. H351 – Suspected of causing cancer. H373 – Causes damage to organs through prolonged or repeated exposure. H412 – Harmful to aquatic life with long lasting effects.

Precautionary statements

P261 – Avoid breathing dust/fume/gas/mist/vapor/spray. P202 – Do not handle until all safety precautions have been read and understood. P280 – Wear protective gloves/protective clothing/eye protection/face protection. P281 – Use personal protective equipment as required. P302+P352 – IF ON SKIN, wash with plenty of water and soap. P305+P338+P351 – IF IN EYES, rinse with water for several minutes. Remove contact lenses. Continue rinsing. P308+P313 – If exposed or concerned: Get medical advice/attention. P501 – Dispose of contents/container in accordance with local/regional/national/international regulations. SDS R1 Page 1 of 7 Rev. 8 Hazardous Decomposition Products – Welding fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being welded, the process, procedure, and powder used. Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coating on the metal being welded (such as paint, plating, or galvanizing), the number of welders and the volume of work area, the quality and the amount of ventilation, the position of the welder’s head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities). When the powder is molten, the fume and gas decomposition products generated are different in percent and from the ingredients listed in Section 3. Fumes and gas decomposition products that evolve from welding activity and not the ingredients in the electrode, are important. The concentration of a given fume or gas component may decrease or increase by many times the original concentration in the powder. Also, new compounds not in the electrodes may form from welding activity. Decomposition products of normal operation include those originating from the volatilization, reaction, or oxidation of the materials shown in Section 3, plus those from the base metal coatings, etc. as noted above. Reasonably expected decomposition products from normal use of these products include a complex set of oxides of materials listed in Section 3, as well as carbon monoxide, carbon dioxide, ozone and nitrogen oxides. The exposure limits for exposure to chromium, nickel, manganese, cobalt, and/or hexavalent chrome may be reached before the general limit for welding fumes (5 mg/m3) is reached. The recommended way to determine the composition and quantity of fumes and gases to which workers are exposed is to take an air sample inside the welder’s helmet (if worn) or in the worker’s breathing zone. See ANSI/AWS F1.1 “Method for Sampling Airborne Particles Generated by Welding and Allied Processes” and “Characterization of Arc Welding Fume” available from the American Welding Society, 8669 NW 36 #130, Miami, FL 33166. SDS R1 Page 2 of 7 Rev. 8 7 of (fume) (resp) (dust) 2500 1309-37-1 10 IDLH Page 4 1 3 Fe – - 2 0 5 5 dust) fume) dust) 4 3 7440-42-8 (oxide B – – 1 1 15 10 10 SHEET DATA Balance 7440-02-0 (inhalable) (dust) 0.015 10 IDLH of Ni 1 components. 1.5 its risks SAFETY of sums VI) the 15 7440-47-3 (Cr μg/m3 0.5 IDLH 250 as defined Cr – -- 0.5 -- (dust) 8 0.5 be cannot alloy an of risk INGREDIENTS The 7440-21-3 15 10 5 5 4 Si – – -- (dust) alloy. 3 2 (resp) (dust) (resp) 5 an as other ON each to bound cc per but 7782-42-5 (dust) 2 2.5 meter 1 (resp) (resp) (resp) the mppcf product particles – C -- = 0.3 5 in 15 available Health cubic per and freely Life not to particles are Limit Exposure Dangerous above million

2.1 Classification of the substance or mixture

CLP/GHS Classification (1272/2008): Skin sensitization, Category 1 Carcinogenicity, Category 2 Specific target organ toxicity (Repeated exposure), Category 1 Hazardous Classification per 29CFR 1910.1200 (Rev. July 1, 2012): Skin sensitization, Category 1 Carcinogenicity, Category 2 Specific target organ toxicity (Repeated exposure), Category 1