Milton Antibacterial Surface Spray

Hazard statements (CLP)

H290, H302, H314, H315, H318, H319, H400, H410, H412

Code

Statements

H290

May be corrosive to metals

Health hazards

No. 1272/2008 Skin irritation Category 2 H315: Causes skin irritation. Serious eye irritation Category 2 H319: Causes serious eye irritation.

Environmental hazards

Chronic hazards to the aquatic Category 3 H412: Harmful to aquatic life with long lasting effects.

Signal word

Warning

Hazard statements

H315: Causes skin irritation. H319: Causes serious eye irritation. H412: Harmful to aquatic life with long lasting effects.

Precautionary statements

General advice: P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children. P103: Read label before use.

Prevention

P273: Avoid release to the environment. P260: Do not breathe mist. P271: Use only outdoors or in a well-ventilated area. P264: Wash hands thoroughly after handling.

Response

P302+P352 IF ON SKIN Wash with plenty of soap and water P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing. P332+P313 If skin irritation occurs Get medical advice/attention

Disposal

P501: Dispose of contents/container in accordance with local requirements for domestic waste disposal.

2.3 Other hazards

No data available. 3.2 Mixtures General information: No data available. Chemical name Concentration CAS-No. EC No. REACH M-Factor: Notes Registration No. BENZALKONI 1 - <2.5% 68424-85-1 270-325-2 No data 10 UM available. CHLORIDE * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. # This substance has workplace exposure limit(s).

2.1 Classification of the substance or mixture

Chemical name Notes BENZALKONIUM Met. Corr. 1 H290 CHLORIDE Acute Tox. 4 H302 Skin Corr. 1B H314 Eye Dam. 1 H318 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 The full text for all H-statements is displayed in section 16. CLP: Regulation No. 1272/2008. 4.1 Description of first aid measures Inhalation: Move to fresh air. Skin Contact: Flush skin thoroughly with water. Get medical attention if irritation persists after washing. Eye contact: Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if irritation persists after washing. Ingestion: Rinse mouth thoroughly. Do NOT induce vomiting. Seek medical attention. 4.2 Most important symptoms Mildly irritating to skin with prolonged exposure. If mixture comes into and effects, both acute and contact with eyes may cause mild irritation. delayed: 4.3 Indication of any immediate medical attention and special treatment needed

SECTION 2: Hazards identification

No special precautionary health measures should be needed under anticipated conditions of use. Treatment: Get medical attention if symptoms occur. General Fire Hazards: No unusual fire or explosion hazards noted. 5.1 Extinguishing media Suitable extinguishing Extinguish with foam, carbon dioxide, dry powder or water fog. media: Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media: 5.2 Special hazards arising During fire, gases hazardous to health may be formed. from the substance or mixture: 5.3 Advice for firefighters Special fire fighting Wear self-contained breathing apparatus and protective clothing. procedures: Special protective Self-contained breathing apparatus and full protective clothing must be equipment for fire-fighters: worn in case of fire. 6.1 Personal precautions, Do not touch damaged containers or spilled material unless wearing protective equipment and appropriate protective clothing. Avoid contact with eyes and prolonged or emergency procedures: repeated contact with skin. 6.2 Environmental Precautions: Avoid release to the environment. Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. 6.3 Methods and material for Dike far ahead of larger spill for later recovery and disposal. Absorb with containment and cleaning sand or other inert absorbent. Collect spillage in containers, seal securely up: and deliver for disposal according to local regulations. Stop the flow of material, if this is without risk. 6.4 Reference to other See Section 8 of the SDS for Personal Protective Equipment. sections: 7.1 Precautions for safe Provide adequate ventilation. Avoid contact with eyes. Avoid contact with handling: skin. No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals. Use only as directed. 7.2 Conditions for safe storage, Store away from incompatible materials. Store in original tightly closed including any container. incompatibilities: 7.3 Specific end use(s): For cleaning hard surfaces 8.1 Control Parameters Occupational Exposure Limits None of the components have assigned exposure limits. 8.2 Exposure controls Appropriate Engineering No data available. Controls: Individual protection measures, such as personal protective equipment General information: Do not eat, drink or smoke when using the product. Use personal protective equipment as required. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Eye/face protection: If risk of splashing, wear safety goggles or face shield. Skin protection Hand Protection: Use suitable protective gloves if risk of skin contact. Other: Wear appropriate clothing to prevent reasonably probable skin contact. Respiratory Protection: No protection is ordinarily required under normal conditions of use and with adequate ventilation. Hygiene measures: Avoid contact with eyes. Avoid contact with skin. Wash hands thoroughly after handling. Environmental Controls: No eSDS available. 9.1 Information on basic physical and chemical properties Appearance Physical state: liquid Form: Clear Liquid Color: Colorless Odor: green - fresh Odor Threshold: No data available. pH: 10.00 Freezing point: No data available. Boiling Point: 100.00 °C Flash Point: > 61.00 °C Evaporation Rate: No data available. Flammability (solid, gas): No data available. Flammability Limit - Upper (%): No data available. Flammability Limit - Lower (%): No data available. Vapor pressure: No data available. Vapor density (air=1): No data available. Density: No data available. Relative density: 1.0000 Solubility(ies) Solubility in Water: No data available. Solubility (other): No data available. Partition coefficient (n-octanol/water): No data available. Autoignition Temperature: No data available. Decomposition Temperature: No data available. SADT: No data available. Viscosity: No data available. Explosive properties: No data available. Oxidizing properties: No data available.

Further information

VOC Content: EC Directive 1999/13: 0.32 g/l ~0.03 % (calculated) 10.1 Reactivity: Stable under normal temperature conditions and recommended use. 10.2 Chemical Stability: Material is stable under normal conditions. 10.3 Possibility of hazardous None under normal conditions. reactions: 10.4 Conditions to avoid: Avoid heat or contamination. Do not freeze. 10.5 Incompatible Materials: Strong acids. Strong oxidizing substances. Strong bases. 10.6 Hazardous Decomposition By fire, toxic gases may be formed (COx, NOx). Products: Information on likely routes of exposure Inhalation: None under normal conditions. Skin Contact: Causes skin irritation. Eye contact: Causes serious eye irritation. Ingestion: May be ingested by accident. Ingestion may cause irritation and malaise. 11.1 Information on toxicological effects Acute toxicity Oral Product: ATEmix: 23,333.330000 mg/kg Specified substance(s) BENZALKONIUM LD 50 (Rat): 350.000000 mg/kg CHLORIDE Dermal Product: Not classified for acute toxicity based on available data. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Inhalation Product: Not classified for acute toxicity based on available data. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Repeated dose toxicity Product: No data available. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Skin Corrosion/Irritation: Product: Causes skin irritation. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Serious Eye Damage/Eye Irritation: Product: Causes serious eye irritation. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Respiratory or Skin Sensitization: Product: Based on available data, the classification criteria are not met. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Germ Cell Mutagenicity In vitro Product: Based on available data, the classification criteria are not met. Specified substance(s) BENZALKONIUM No data available. CHLORIDE In vivo Product: Based on available data, the classification criteria are not met. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Carcinogenicity Product: No data available. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Reproductive toxicity Product: No data available. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Specific Target Organ Toxicity - Single Exposure Product: Based on available data, the classification criteria are not met. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Specific Target Organ Toxicity - Repeated Exposure Product: Based on available data, the classification criteria are not met. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Aspiration Hazard Product: Based on available data, the classification criteria are not met. Specified substance(s) BENZALKONIUM No data available. CHLORIDE General information: Contains a substance which causes risk of hazardous effects to the environment. This material has not been tested for environmental effects. 12.1 Toxicity Acute toxicity Fish Product: Based on available data, the classification criteria are not met. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Aquatic Invertebrates Product: Based on available data, the classification criteria are not met. Specified substance(s) BENZALKONIUM EC 50 (Daphnia magna, 48.0 h): 0.016000 mg/l CHLORIDE Chronic Toxicity Fish Product: No data available. Specified substance(s) BENZALKONIUM No data available. CHLORIDE Aquatic Invertebrates Product: No data. Specified substance(s) BENZALKONIUM NOEC (Daphnia magna, 21.0 d): 0.004150 mg/l (Static renewal) CHLORIDE Toxicity to Aquatic Plants Product: Based on available data, the classification criteria are not met. Specified substance(s) BENZALKONIUM No data available. CHLORIDE 12.2 Persistence and Degradability Biodegradation Product: The surfactant(s) contained in this mixture comply with biodegradability criteria as laid down in regulations (EC) No 648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the member state. The other components of this mixture are either environmentally inert or absorbed onto sewage and sediment etc or will biodegrade to substances which are likely to be of low environmental impact when the mixture is used as directed. Specified substance(s) BENZALKONIUM No data available. CHLORIDE BOD/COD Ratio Product No data available. Specified substance(s) BENZALKONIUM No data available. CHLORIDE 12.3 Bioaccumulative potential Product: The product is not bioaccumulating. Specified substance(s) BENZALKONIUM No data available. CHLORIDE 12.4 Mobility in soil: No data available. Known or predicted distribution to environmental compartments BENZALKONIUM No data available. CHLORIDE 12.5 Results of PBT and vPvB Based on available data, the classification criteria are not met. assessment: BENZALKONIUM No data available. CHLORIDE 12.6 Other adverse effects: Harmful to aquatic life with long lasting effects. 12.7 Additional Information: No data available. 13.1 Waste treatment methods General information: Dispose of contents/container in accordance with local requirements for domestic waste disposal. Disposal methods: Discharge, treatment, or disposal may be subject to national, state, or local laws. ADR Not regulated. ADN Not regulated. RID Not regulated. IMDG Not regulated. IATA Not regulated. 14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code: not applicable 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: EU Regulations Regulation (EC) No. 2037/2000 Substances that deplete the ozone layer: none Regulation (EC) No. 850/2004 on persistent organic pollutants: none Regulation (EC) No. 689/2008 Import and export of dangerous chemicals: none Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended: none Regulation (EC) No. 1907/2006, REACH, Annex XVII Substances subject to restriction on marketing and use: none Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens and mutagens at work.: none Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breast feeding.: none Directive 96/82/EC (Seveso III): on the control of major accident hazards involving dangerous