Tris(dimethylamido)cyclopentadienyl hafnium

Hazard statements (CLP)

H225, H261, H302, H314, H318, H332, H335

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Appearance/Odor

Colorless liquid, color and odor not determined. Classification FLAMMABLE LIQUIDS – Category 2, H225 SUBSTANCE AND MIXTURES, WHICH IN CONTACT WITH WATER, EMIT FLAMMABLE GASES – Category 2, H261 ACUTE TOXICITY, ORAL – Category 4, H302 SKIN CORROSION/IRRITATION – Category 1B, H314 SERIOUS EYE DAMAGE/EYE IRRITATION – Category 1, H318 ACUTE TOXICITY, INHALATION – Category 4, H332 SPECIFIC ORGAN TOXICITY, SINGLE EXPOSURE; RESPIRATORY TRACT IRRITATION – Category 3, H335 Hazards Identification

Signal word

DANGER

Hazard statements

H225: Highly flammable liquid and vapor. H261: In contact with water releases flammable gas. H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H318: Causes serious eye damage. H332: Harmful if inhaled. H335: May cause respiratory irritation.

Prevention

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P223: Do not allow contact with water. P231 + P232: Handle and store contents under inert gas. Protect from moisture. P233: Keep container tightly closed. P240: Ground and bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting/handling equipment. P242: Use non-sparking tools. P243: Take action to prevent static discharges. P260: Do not breathe sprays, mists, vapors or gases. P264 + P265: Wash hands and exposed skin thoroughly after handling. Do not touch eyes. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or with adequate ventilation. P280: Wear protective gloves/protective clothing/eye protection/ face protection/hearing protection.

Response

P301 + P317 IF SWALLOWED Get medical help P301 + P330 + P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting. P302 + P335 + P334 IF ON SKIN Brush off loose particles from skin and immerse in cool water. P302 + P361 + P354 IF ON SKIN Take off immediately all contaminated clothing. Immediately rinse with water for several minutes. Response (cont.): P303 + P361 + P353 IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse affected areas with water. P304 + P340 IF INHALED Remove person to fresh air and keep comfortable for breathing. P305 + P354 + P338 IF IN EYES Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P316: Get emergency medical help immediately. P319: Get medical help if you feel unwell. P330: Rinse mouth. P363: Wash contaminated clothing before reuse. P370 + P378 In case of fire Use dry chemical or carbon dioxide to extinguish. DO NOT USE FOAM OR WATER.

Storage

P402 + P404: Store in a dry place. Store in a closed container. P403 + P233 + P235: Store in a well ventilated place. Keep container tightly closed. Keep cool. P405: Store locked up.

Disposal

P501: Dispose of contents/container in accordance with federal, state and local regulations.

2.3 Other hazards

None identified.

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS – Category 2, H225 SUBSTANCE AND MIXTURES, WHICH IN CONTACT WITH WATER, EMIT FLAMMABLE GASES – Category 2, H261 ACUTE TOXICITY, ORAL – Category 4, H302 SKIN CORROSION/IRRITATION – Category 1B, H314 SERIOUS EYE DAMAGE/EYE IRRITATION – Category 1, H318 ACUTE TOXICITY, INHALATION – Category 4, H332 SPECIFIC ORGAN TOXICITY, SINGLE EXPOSURE; RESPIRATORY TRACT IRRITATION – Category 3, H335 Section 2. Hazards Identification