Triethylsilylcobalt tetracarbonyl

Hazard statements (CLP)

H225, H315, H317, H319, H334, H335, H336, H351

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

29 CFR 1910.1200) Emergency Overview

Appearance/Odor

Dark red liquid, odor not determined.

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS; - Category 2, H225 SKIN CORROSION/IRRITATION; - Category 2, H315 SENSITIZATION, SKIN; - Category 1, H317 SERIOUS EYE DAMAGE/IRRITATION; - Category 2A, H319 SENSITISATION, RESPIRATORY; - Category 1, H334 SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE; RESPIRATORY TRACT IRRITATION - Category 3, H335 SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE; NARCOTIC EFFECTS - Category 3, H336 CARCINOGENICITY; - Category 2, H351

Signal word

DANGER

Hazard statements

H225: Highly flammable liquid and vapor. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335: May cause respiratory irritation. H336: May cause drowsiness or dizziness. Hazard statements (cont.): H351: Suspected of causing cancer.

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233: Keep container tightly closed. P240: Ground/Bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting/handling equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P261: Avoid breathing fumes/gases/mists/vapors/sprays. P264: Wash exposed skin thoroughly after handling. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection. P281: Use personal protective equipment as required. P285: In case of inadequate ventilation, wear respiratory protection.

Response

P302 + P352 IF ON SKIN Wash with plenty of soap and water P303 + P361 + P353 IF ON SKIN (or hair) Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned Get medical advice/attention. P312: Call a POISON CENTER or doctor/physician if you feel unwell. Response (cont.): P333 + P313 If skin irritation or rash occurs Get medical advice/attention. P337 + P313 If eye irritation persists Get medical advice/attention. P342 + P311 If experiencing respiratory symptoms Call a POISON CENTER or doctor/physician. P362: Take off contaminated clothes and wash before reuse. P363: Wash contaminated clothing before reuse. P370 + P378 In case of a fire Use sand, dry chemical, water spray, alcohol resistant foam or carbon dioxide for extinction.

Storage

P403 + P233 + P235: Store in a well-ventilated place. Keep container tightly closed. Keep cool. P405: Store locked up.

Disposal

P501: Dispose of contents/ container to an approved wasted disposal plant. General: None. OSHA/HCS status: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

2.3 Other hazards

None known.