Tetrakis(N,N-diethylaminooxy)hafnium

Hazard statements (CLP)

H226, H261, H302, H312, H315, H319, H332, H335, H411

Code

Statements

H226

Flammable liquid and vapour

Appearance/Odor

Yellow liquid, odor not determined.

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS - Category 3, H226 SUBSTANCES AND MIXTURES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES – Category 2, H261 ACUTE TOXICITY, ORAL – Category 4, H302 ACUTE TOXICITY, DERMAL – Category 4, H312 SKIN CORROSION/IRRITATION - Category 2, H315 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A, H319 ACUTE TOXICITY, INHALATION – Category 4, H332 SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE; RESPIRATORY TRACT IRRITATION – Category 3, H335 HAZARDOUS TO THE AQUATIC ENVIRONMENT, CHRONIC TOXICITY – Category 2, H411

Signal word

DANGER

Hazard statements

H226: Flammable liquid and vapor. H261: In contact with water releases flammable gas.. H302: Harmful if swallowed. H312: Harmful in contact with skin. H315: Causes skin irritation. H319: Causes serious eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H411: Toxic to aquatic life with long lasting effects.

Prevention

P210: Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P223: Keep away from any possible contact with water, because of violent reaction and possible flash fire. P231: Handle under inert gas. P232: Protect from moisture. P233: Keep container tightly closed. P240: Ground/Bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P261: Avoid breathing fumes/mists/vapors/sprays. P264: Wash hands and exposed skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P312 IF SWALLOWED Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352 IF ON SKIN Wash with plenty of soap and water P303 + P353 + P361 IF ON SKIN (or hair) Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES Rinse continuously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P330: Rinse mouth. Response (cont.): P332 + P313 If skin irritation occurs Get medical advice/attention. P334 + P335: Brush off loose particles from skin and immerse in cool water/wrap in wet bandages. P337 + P313 If eye irritation persists Tet medical advice/attention. P362: Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire Use CO2, dry chemical or alcohol resistant foam for extinction. P391: Collect spillage.

Storage

P402 + P404: Store in a dry place. Store in a closed container. P403 + P233 + P235: Store in a well-ventilated place. Keep container tightly closed. Keep cool. P405: Store locked up.

Disposal

P501: Dispose of contents/ container to an approved wasted disposal plant. General: None. OSHA/HCS Status: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

2.3 Other hazards

None known.