Dicobalt hexacarbonyl tert-butylacetylene

Hazard statements (CLP)

H227, H302, H312, H315, H317, H319, H332, H334, H351, H361, H412

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

Appearance/Odor

Dark red liquid, odor not determined. Classification FLAMMABLE LIQUIDS – Category 4, H227 ACUTE TOXICITY, ORAL – Category 4, H302 ACUTE TOXICITY, DERMAL – Category 4, H312 SKIN CORROSION/IRRITATION - Category 2, H315 SENSITIZATION, SKIN – Category 1, H317 SERIOUS EYE DAMAGE/EYE IRRITATION – Category 2A, H319 ACUTE TOXICITY, INHALATION – Category 4, H332 SENSITISATION, RESPIRATORY - Category 1, H334 CARCINOGENICITY – Category 2, H351 REPRODUCTIVE TOXICITY – Category 2, H361 HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD – Category 3, H412 Hazards Identification

Signal word

DANGER

Hazard statements

H227: Combustible liquid. H302: Harmful if swallowed. H312: Harmful in contact with skin. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H332: Harmful if inhaled. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H351: Suspected of causing cancer. H361: Suspected of damaging fertility or the unborn child. H412: Harmful to aquatic life with long lasting effects.

Prevention

P203: Obtain, read and follow all safety instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P223 Keep container tightly closed. P260 Do not breathe sprays/mists/vapors/gases. P264 + P265: Wash hands and exposed skin thoroughly after handling. Do not touch eyes. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or with adequate ventilation. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/hearing protection. P284 In case of inadequate ventilation, wear respiratory protection.

Response

P301 + P317 IF SWALLOWED Get medical help P302 + P352 IF ON SKIN Wash with plenty of water P304 + P340 IF INHALED Remove person to fresh air and keep comfortable for breathing. Response (cont.): P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P317 Get medical help. P318 IF exposed or concerned Get medical advice P330 Rinse mouth. P332 + P333 + P317 If skin irritation or rash occurs Get medical help. P337 + P317 If eye irritation persists Get medical help P342 + P316 If experiencing respiratory symptoms Get emergency medical help immediately. P362 + P364: Take off contaminated clothes and wash it before reuse. P370 + P378 In case of a fire Use dry chemical, water spray (fog), alcohol resistant foam or carbon dioxide to extinguish.

Storage

P403: Store in a well ventilated place. P405 Store locked up.

Disposal

P501: Dispose of contents/container in accordance with federal, state and local regulations. General: None.

2.3 Other hazards

None identified.

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS – Category 4, H227 ACUTE TOXICITY, ORAL – Category 4, H302 ACUTE TOXICITY, DERMAL – Category 4, H312 SKIN CORROSION/IRRITATION - Category 2, H315 SENSITIZATION, SKIN – Category 1, H317 SERIOUS EYE DAMAGE/EYE IRRITATION – Category 2A, H319 ACUTE TOXICITY, INHALATION – Category 4, H332 SENSITISATION, RESPIRATORY - Category 1, H334 CARCINOGENICITY – Category 2, H351 REPRODUCTIVE TOXICITY – Category 2, H361 HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD – Category 3, H412 Section 2. Hazards Identification