Cobalt tricarbonyl(h3-2-propenyl)

Hazard statements (CLP)

H226, H301, H311, H317, H331, H334, H341, H351, H413

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

29 CFR 1910.1200) Emergency Overview

Appearance/Odor

Orange-red liquid, odor not determined.

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS – Category 3, H226 ACUTE TOXICITY, ORAL; - Category 3, H301 ACUTE TOXICITY, DERMAL; - Category 3, H311 SENSITIZATION, SKIN; - Category 1, H317 ACUTE TOXICITY, INHALATION; - Category 3, H331 SENSITIZATION, RESPIRATORY; - Category 1, H334 GERM CELL MUTAGENICITY; - Category 2, H341 CARCINOGENICITY – Category 2, H351 HAZARDOUS TO THE AQUATIC ENVIRONMENT, CHRONIC TOXICITY; - Category 4, H413

Signal word

DANGER

Hazard statements

H226: Flammable liquid and vapor. H301: Toxic if swallowed. H311: Toxic in contact with skin. H317: May cause an allergic skin reaction. H331: Toxic if inhaled. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H341: Suspected of causing genetic defects. Hazard statements (cont.): H351: Suspected of causing cancer. H413: May cause long lasting harmful effects to aquatic life.

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P233: Keep container tightly closed. P240: Ground/Bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/ lighting/processing equipment. P242: Use only non-sparking equipment. P243: Take precautionary measures against static discharge. P261: Avoid breathing fumes/gas/mist/vapors/spray. P264: Wash exposed skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection. P285: In case of inadequate ventilation, wear respiratory protection.

Response

P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctor/physician. P302 + P352 IF ON SKIN Wash with plenty of soap and water P303 + P361 + P353 IF ON SKIN (or hair) Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P308 + P313 IF exposed or concerned Get medical advice/attention. Response (cont.): P311: Call a POISON CENTER or doctor/physician. P330: Rinse mouth. P333 + P313 If skin irritation or rash occurs Get medical advice/attention. P342 + P311 If experiencing respiratory symptoms Call a POISON CENTER or doctor/physician. P363: Wash contaminated clothing before reuse. P370 + P378 In case of fire Use alcohol-resistant foam, carbon dioxide, dry chemical or dry sand for extinction.

Storage

P403 + + P233 + P235: Store in a well ventilated place. Keep container tightly closed. Keep cool. P405: Store locked up.

Disposal

P501: Dispose of contents/ container to an approved wasted disposal plant. General: None. OSHA/HCS status: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

2.3 Other hazards

None known.