EMD73RB

Era Polymers Pty Ltd

Revision date : 2008-05-30

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

202-966-0

Name of the chemical

4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)

Concentration

N/A

EC/CAS

247-714-0

Name of the chemical

4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)

Concentration

N/A

General Information

Revision date

2008-05-30

Product name

EMD73RB

Product name

EMD73RB

Identification on the label/Trade name

No data available

CAS No.

No

REACH No

No

1.2.1 Relevant identified uses

Polyurethane rubber binder

Emergency telephone

1800 039 008 (AUS

Icons in SDS

Company Information

company name

Era Polymers Pty Ltd

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H334, H335, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

2.1 Classification of the substance or mixture

DSD classification: In case of mixtures, classification has been prepared by following DPD (Directive 1999/45/EC) or CLP (Regulation (EC) No 1272/2008) regulations DSD classification (additional):

Classification (DPD)

R36/37/38 Irritating to eyes, respiratory system and skin. R42/43 May cause SENSITISATION by inhalation and skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R33? Cumulative effects may result following exposure*. R40(3)? Limited evidence of a carcinogenic effect*. R62? May possibly affect fertility*.

CLP CLASSIFICATION

Skin Corrosion/Irritation Category 2 Eye Irritation Category 2A Respiratory Sensitizer Category 1 Skin Sensitizer Category 1 STOT - SE (Resp. Irr.) Category 3 STOT - RE Category 2 (additional):

2.2 Label elements

CLP label elements

Signal word

DANGER

Hazard statements

H315 Causes skin irritation H319 Causes serious eye irritation H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled H317 May cause allergic skin reaction H335 May cause respiratory irritation H373 May cause damage to organs through prolonged or repeated exposure by inhalation. Determined by Chemwatch using CLP criteria Additional Statement(s): Supplementary Code Phrase

Prevention

Code Phrase P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection.

Response

Code Phrase P302+P352 IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for P304+P340 breathing. IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a P304+P341 position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact P305+P351+P338 lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. If experiencing respiratory symptoms: Call a POISON CENTER or P342+P311 doctor/physician. P363 Wash contaminated clothing before reuse.

Storage

Code Phrase P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. DSD / DPD label elements Relevant risk statements are found in section 2.1 Indication(s) of danger: CONSIDERED A DANGEROUS MIXTURE ACCORDING TO DIRECTIVE 1999/45/EC AND ITS AMENDMENTS.

Precautionary statements

S23 Do not breathe gas/fumes/vapour/spray. S51 Use only in well ventilated areas. S09 Keep container in a well ventilated place. S53 Avoid exposure - obtain special instructions before use. S401 To clean the floor and all objects contaminated by this material, use water and detergent. S07 Keep container tightly closed. S13 Keep away from food, drink and animal feeding stuffs. S26 In case of contact with eyes, rinse with plenty of water and contact Doctor or Poisons Information Centre. S46 If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (show this container or label).

2.3 Other hazards

R33? • Cumulative effects may result following exposure*. R40(3)? • Limited evidence of a carcinogenic effect*. R62? • May possibly affect fertility*. * (limited evidence).

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