Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
202-966-0
Name of the chemical
4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)
Concentration
N/A
EC/CAS
247-714-0
Name of the chemical
4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)
Concentration
N/A
General Information
Revision date
2008-05-30
Product name
EMD73RB
Product name
EMD73RB
Identification on the label/Trade name
No data available
CAS No.
No
REACH No
No
1.2.1 Relevant identified uses
Polyurethane rubber binder
Emergency telephone
1800 039 008 (AUS
Icons in SDS
Company Information
company name
Era Polymers Pty Ltd
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H334, H335, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
2.1 Classification of the substance or mixture
DSD classification: In case of mixtures, classification has been prepared by following DPD (Directive 1999/45/EC) or CLP (Regulation (EC) No 1272/2008) regulations DSD classification (additional):
Classification (DPD)
R36/37/38 Irritating to eyes, respiratory system and skin. R42/43 May cause SENSITISATION by inhalation and skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R33? Cumulative effects may result following exposure*. R40(3)? Limited evidence of a carcinogenic effect*. R62? May possibly affect fertility*.
CLP CLASSIFICATION
Skin Corrosion/Irritation Category 2 Eye Irritation Category 2A Respiratory Sensitizer Category 1 Skin Sensitizer Category 1 STOT - SE (Resp. Irr.) Category 3 STOT - RE Category 2 (additional):
2.2 Label elements
CLP label elements
Signal word
DANGER
Hazard statements
H315 Causes skin irritation H319 Causes serious eye irritation H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled H317 May cause allergic skin reaction H335 May cause respiratory irritation H373 May cause damage to organs through prolonged or repeated exposure by inhalation. Determined by Chemwatch using CLP criteria Additional Statement(s): Supplementary Code Phrase
Prevention
Code Phrase P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection.
Response
Code Phrase P302+P352 IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for P304+P340 breathing. IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a P304+P341 position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact P305+P351+P338 lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. If experiencing respiratory symptoms: Call a POISON CENTER or P342+P311 doctor/physician. P363 Wash contaminated clothing before reuse.
Storage
Code Phrase P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. DSD / DPD label elements Relevant risk statements are found in section 2.1 Indication(s) of danger: CONSIDERED A DANGEROUS MIXTURE ACCORDING TO DIRECTIVE 1999/45/EC AND ITS AMENDMENTS.
Precautionary statements
S23 Do not breathe gas/fumes/vapour/spray. S51 Use only in well ventilated areas. S09 Keep container in a well ventilated place. S53 Avoid exposure - obtain special instructions before use. S401 To clean the floor and all objects contaminated by this material, use water and detergent. S07 Keep container tightly closed. S13 Keep away from food, drink and animal feeding stuffs. S26 In case of contact with eyes, rinse with plenty of water and contact Doctor or Poisons Information Centre. S46 If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (show this container or label).
2.3 Other hazards
R33? • Cumulative effects may result following exposure*. R40(3)? • Limited evidence of a carcinogenic effect*. R62? • May possibly affect fertility*. * (limited evidence).