EM OIL STOP PART B

SECTION 2: Hazards identification

OSHA Hazard Overview

2.1 Classification of the substance or mixture

Carcinogen category 1B, Toxic to reproduction category 1B, Flammable liquid category 3, Specific target organ toxicity following repeated exposure category 2, Skin corrosion/irritation category 1B, skin sensitizer category 1B, Serious eye damage category 1, Germ cell mutagenicity category 2, Acute toxicity inhalation category 4, Acute hazard to aquatic environment category 2, Chronic hazards to aquatic environment category 2

2.2 Label elements

Elements and Precautionary Statements Flame, Health Hazard Exclamation Mark, Corrosion, Aquatic Toxicity

Hazard statements

Danger May Cause cancer Warning Suspected of damaging fertility of the unborn child Warning Flammable liquid and vapor. Warning May cause damage to organs through prolonged or repeated exposure Danger Causes severe skin burns and eye damage Warning May cause an allergic skin reaction Danger Causes severe eye damage Warning Suspected of causing genetic defects Warning Harmful if inhaled Toxic to aquatic life Toxic to aquatic life with long lasting effects

Precautionary statements

P102 Keep out of reach of children. P103 Read label before use P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash hands thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P271 Use only outdoors or in a well-ventilated area P273 Avoid release to the environment.

Response

P370 + P378 In case of fire: Use FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL for extinction. P314 Get medical advice/attention if you feel unwell. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P363 Wash contaminated clothing before reuse. P304 + P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P310 Immediately call a POISON CENTER or doctor/physician. P321 If skin irritation or burns develop, Call a doctor/physician . P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 IF ON SKIN: wash with plenty of soap and water. P333 + P313 IF SKIN irritation or rash occurs: Get medical advice/attention. P362 + P364 take off contaminated clothing and wash it before reuse P310 If in eyes, immediately call a POISON CENTER or doctor/physician. P308 + P313 IF exposed or concerned: Get medical advice/attention. P312 Call a POISON CENTER or doctor/physician if you feel unwell P391 Collect spillage.

Storage

P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/container to a waste disposal facility in accordance with local, state, federal or international laws.

HMIS® ratings

HEALTH: 3 FLAMMABILITY: 3 REACTIVITY: 0 PERSONAL PROTECTIVE EQUIPMENT: G

Potential health effects

EYES: CAN CAUSE SEVERE IRRITATION, REDNESS, TEARING, OR BLURRED VISION SKIN: MAY CAUSE IRRITATION, DEFATTING AND DERMATITIS. INGESTION: CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, DIARRHEA AND ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE CHEMICAL PHEUMONTITIS WHICH CAN BE FATAL. INHALATION: CAN CAUSE NAUSEA AND RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, HEADACHE AND POSSIBLE UNCONSCIOUSNESS HEALTH HAZARDS (ACUTE AND CHRONIC): AMINES CAN CAUSE SENSITIZATION BY EXPOSURE THROUGH CONTACT OR HIGH CONCENTRATIONS OF VAPOR. OVER EXPOSURE TO THIS MATERIAL CAN CAUSE CARDIAC ABNORMALITIES, ANEMIA, LIVER ABNORMALITIES, KIDNEY DAMAGE OR EVEN EYE DAMAGE. Coal Tar Pitch Emergency Overview: (Danger This product is carcinogenic to humans. Repeated or prolonged contact with skin may cause dermatitis and hyperpigmentation of skin. Avoid breathing dust/fume/gas/mist/vapours and sprays. This product is irritating to the eyes, the skin and the respiratory tract. Exposure to sun may enhance the irritating effect of coal tar pitch on skin and eyes and lead to burns. High vapor concentrations may cause dizziness. Use in well-ventilated areas. Avoid prolonged and/or repeated contact including vapors. If appropriate, respiratory protection and other personal protective equipment should be used. ).

Medical Conditions Generally Aggravated by Exposure

RESPIRATORY CONDITIONS OR OTHER ALLERGIC RESPONSE CARCINOGENICITY OSHA: YES NTP: YES IARC: YES ADDITIONAL CARCINOGENICITY INFORMATION: Product may contain ethyl benzene as a component of xylene (IARC 2B). crystalline silica is listed by IARC as a group I carcinogen (lung) based on sufficient evidence in occupationally exposed humans and sufficient evidence in animals. Crystalline Silica is also listed by the NTP as a known human carcinogen. Coal tar: FREQUENT, PROLONGED OR OCCASIONAL BUT INTENSIVE CONTACT WITH THE SKIN OVER A MANY YEAR PERIOD. IN THE ABSENCE OF RECOMMENDED HYGIENE PRACTICES, MAY LEAD TO SKIN PIGMENTATION, BENIGN SKIN GROWTHS AND IN SOME CASES MAY RESULT IN SKIN CANCER. Coal tar pith is an IARC Group 1 Human carcinogen, an ACGIH A1 Known human carcinogen