Note: Ingredients listed on restricted chemical lists
EC/CAS
1333-86-4
Name of the chemical
carbon black
Concentration
100%
General Information
Revision date
2020-06-01
Product name
EB-350-3FL-L V
CAS No.
1333-86-4
Emergency telephone
1-800-255-3924, +01-813-248-0585
Icons in SDS
Company Information
company name
EPDXYSET INC
e-mail address of the competent person responsible for the Safety Data Sheet
msds@epoxyset.com
GHS Information
Signal word
Warning
Section 2
Classification system
NFPA Rating NFPA ratings (scale 0 - 4) Health = Fire = 1 Reactivity = 0
HMIS® ratings
(scale 0 - 4) Health = 1 Fire = Reactivity = 0
PBT Substances
Not applicable Not applicable
vPvB Substances
Not applicable Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Not applicable
Hazardous Ingredients
28064-14.4 1 Epoxy phenol novolac resin Skin Irrit. 2, H3 15; Skin Sens. 1, H3 17 <60% Description of first aid measures After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. Extinguishing media Suitable extinguishing agents: Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixture No further relevant information available. Printing date 01/06/2017 Reviewed On 1 Reviewed On 01/06/2017 Trade name: EB-350-3FL-LV (Contd. of page 2) Advice for firefighters Protective equipment: No special measures required. W(LTfl rnm release nicastires u Personal precautions, protective equipment and emergency procedures Not required. Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 21645-51-2 aluminium hydroxide 8.7 mg/m3 28064-14-4 Epoxy phenol novolac resin 30 mg/m3 461-58-5 cyanoguanidine 61 mg/m3 763 1-86-9 silicon dioxide, chemically prepared 18 mg/m3 1333-86-4 Carbon black 9 mg/m3 PAC-2: 21645-51-2 aluminium hydroxide 73 mg/m3 28064-14-4 Epoxy phenol novolac resin 330 mg/m3 461-58-5 cyanoguanidine 680 mg/m3 763 1-86-9 silicon dioxide, chemically prepared 740 mg/m3 1333-86-4 Carbon black 99 mg/m3 PAC-3: 21645-51-2 aluminium hydroxide 440 mg/m3 28064-14-4 Epoxy phenol novolac resin 2,000 mg/m3 461-58-5 cyanoguanidine 4,000 mg/m3 7631-86-9 silicon dioxide, chemically prepared 4,500 mg/m3 1333-86-4 Carbon black 590 mg/m3 Handling: Precautions for safe handling Ensure good ventilationlexhaustion at the workplace. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles: Store in a closed container. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. (Contd. on page 4) Printing date 01/06/2017 Reviewed On 1 Reviewed On 01/06/2017 Trade name: EB-350-3FL-L V (Contd. of page 3) Specific end use(s) No further relevant information available. Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information
The lists that were valid during the creation were used as basis Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the skin. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product) the substance/ the preparation. Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Goggles recommended during refilling. Information on basic physical and chemical properties General Information Appearance: Form: Pasty Color: Black Odor: Aromatic Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Undetermined. (Contd. on page 5) Printing date 01/06/20 17 Reviewed On I Reviewed On 01/06/20 17 Trade name: EB-350-3FL-L V (Contd. of oage 4) Flash point: 200 °C (392 °F) Flammability_(solid,_gaseous): Not applicable. Ignition temperature: Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Not determined. Upper: Not determined. Vapor pressure: Not determined. Density at 20 °C (68 °F): 1.6 g/cm3 (13.352 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not dctcrmined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: Organic solvents: 0.0 % Solids content: 100.0 %
Further information
No further relevant information available. Reactivity No further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: 28064-14-4 Epoxy phenol novolac resin Oral LD50 >2000 mg/kg (rat) Dermal LD50 >2000 mg/kg (rabbit) (Contd. on page Printing date 01/06/2017 Reviewed On 1 Reviewed On 01/06/2017 Trade name: EB-350-3FL-L V (Contd. of page 5) Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: No irritating effect. Sensitization: Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant Carcinogenic categories IARC (International Agency for Research on Cancer) 763 1-86-9 silicon dioxide, chemically prepared 13 1333-86-4 Carbon black 12B NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Ecotoxical effects
Remarks
Toxic for fish Additional ecological information: General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms
Other hazards
No further relevant information available Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. (Contd. on page 7) Printing date 01/06/2017 Reviewed On 1 Reviewed On 01/06/2017 Trade name: EB-350-3FL-L V (Contd. of page 6) UN-Numbcr DOT not regulated IMDG, IATA UN' 082 UN proper shipping name DOT not regulated IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin), MARINE POLLUTANT IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin) Transport hazard class(es) DOT Class not regulated IMUG, JATA 1! Z <" > Class 9 Miscellaneous dangerous substances and articles Label 9 Packing group DOT not regulated IMDG, IATA HI
Environmental hazards
Product contains environmentally hazardous substances: Epoxy Resin Marine pollutant: No Symbol (fish and tree) Special marking (IATA): Symbol (fish and tree) Special precautions for user Warning: Miscellaneous dangerous substances and articles Danger code (Kemler): 90 EMS Number: F-A,S-F Stowage Category A Transport in bulk according to Annex H of MARPOL73/78 and the IBC Code Not applicable. ---------------------------------------------------------------------------------------- Transport/Additional information: IMDG Limited quantities (LQ) 5L Excepted quantities (EQ) Code: El Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (EPDXY RESIN), 9,111 (Contd. on page 8) Printing date 01/06/2017 Reviewed On 1 Reviewed On 01/06/2017 Trade name: EB-350-3FL-L V (Contd. of page 7) Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): None of the ingredients is listed. TSCA (Toxic Substances Control Act): All ingredients are listed. Proposition 65 Chemicals known to cause cancer: 1333-86-4 lCarbon black Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. TLV (Threshold Limit Value established by ACGIH) 1333-86-4 1 Carbon black A4 NIOSH-Ca (National Institute for Occupational Safety and Health) 1333-86-41 Carbon black GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHSO7 Signal word Warning Hazard-determining components of labeling: Epoxy phenol novolac resin Hazard statements H3 15 Causes skin irritation. H3 17 May cause an allergic skin reaction. Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapors/spray P280 Wear protective gloves. P264 Wash thoroughly after handling. P272 Contaminated work clothing must not be allowed out of the workplace. P321 Specific treatment (see on this label). P363 Wash contaminated clothing before reuse. (Contd. on page 9) Printing date 01/06/20 17 Revision 1 Reviewed on 01/06/2017 Trade name: EB-350-3FL-L V (Contd. of page 8) P333+P313 If skin irritation or rash occurs: Get medical advicelattention. P302+P352 IF ON SKIN: Wash with plenty of water. P362+P364 Take off contaminated clothing and wash it before reuse. P501 Dispose of contents/container in accordance with locallregionaLfnationallinternational regulations.