Acrylonitrile

Hazard statements (CLP)

H225, H301, H311, H315, H317, H318, H331, H335, H350, H411

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

According to Regulation (EC) No 1272/2008 [CLP]

2.1 Classification of the substance or mixture

2.1.1

CLP CLASSIFICATION

Flammable Liquid Category 2 Acute Toxicity (Oral) Category 3 Acute Toxicity (Dermal) Category 3 Acute Toxicity (Inhalation) Category 3 Skin Corrosion/Irritation Category 2 Serious eye damage/Irritation Category 1 Skin Sensitization Category 1 Carcinogenicity Category 1B Specific Target Organ Toxicity Single Exposure Category 3(Respiratory tract irritation), H335 Aquatic Toxicity Chronic Category 2

2.2 Label elements

2.2.1 Labelling according to Regulation (EC) No 1272/2008 [CLP]

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapor. H301 Toxic if swallowed. H311 Toxic in contact with skin H315 Causes skin irritation. H317 May cause allergic skin reaction. H318 Causes serious eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. H350 May cause cancer. H411 Toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P242 Use only non-sparking tools. Flammable liquids (chapter 2.6) 1, 2, 3 P243 Take precautionary measures against static discharge. Date of revision 4 June. 2018 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P281 Use personal protective equipment as required.

Response

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER or doctor/physician. P311 Call a POISON CENTER or doctor/physician. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P321 Specific treatment P322 Specific measures P330 Rinse mouth. P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P361 Remove/Take off immediately all contaminated clothing. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P370+P378 In case of fire: Use Suitable extinguishing media for extinction(Refer Section MSDS 5). P391 Collect spillage.

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed. - P403+P235 Store in a well-ventilated place. Keep cool. - P405 Store locked up.

Disposal

P501 Dispose of contents/container in accordance with local and national regulations. For full text of P precautionary statements see section 16.