General Information
Revision date
2019-10-17
Product name
Bis(diethylamino)silane
Chemical name
organometallic
CAS No.
27804-64-4
1.2.1 Relevant identified uses
semiconductor manufacture
supplier name
Entegris Singapore Pte. Ltd
Icons in SDS
Company Information
company name
Entegris Singapore Pte. Ltd
e-mail address of the competent person responsible for the Safety Data Sheet
Product.stewardship@entegris.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H260, H302, H314, H332, H335
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Singapore Standard SS 586-2:2014 Flammable Liquids - Category 2 Substances and Mixtures which, in Contact with Water, Emit Flammable Gases - Category 1 Acute Toxicity - Oral - Category 4 Acute Toxicity - Inhalation - Vapor - Category 4 Skin Corrosion/Irritation - Category 1 Serious Eye Damage/Eye Irritation - Category 1 Specific Target Organ Toxicity - Single Exposure - Category 3 ( respiratory system ) Specific Target Organ Toxicity - Repeated Exposure - Category 1 ( respiratory system ) Specific Target Organ Toxicity - Repeated Exposure - Category 2 ( lymph system , nose , upper respiratory system )
Signal word
Danger
Hazard statements
H225 Highly flammable liquid and vapor. H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H332 Harmful if inhaled. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation.
Prevention
P210 Keep away from heat/sparks/open flame/hot surfaces - No smoking. P233 Keep container tightly closed. P240 Ground/Bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P280 Wear protective gloves/protective clothing/eye protection/face protection. P223 Do not allow contact with water. P231+P232 Handle under inert gas. Protect from moisture. P260 Do not breathe vapor or mist. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area.
Response
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. P370+P378 In case of fire: Use appropriate media to extinguish. P310 Immediately call a POISON CENTER or doctor/physician. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P321 Specific treatment (see label). P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P363 Wash contaminated clothing before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Storage
P402 Store in a dry place. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P235 Keep cool. P405 Store locked up.
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Other hazards which do not result in classification
Reacts violently with water.