PS32

Hazard statements (CLP)

H251, H315, H317, H319, H332, H341, H350, H370, H372, H400, H412

Code

Statements

H251

Self-heating; may catch fire

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Self-Heating Substances and Mixtures - Category 1 Acute Toxicity - Inhalation - Dust/Mist - Category 4 (6.5% unknown ) Skin Corrosion/Irritation - Category 2 Serious Eye Damage/Eye Irritation - Category 2A Skin Sensitization - Category 1 Germ Cell Mutagenicity - Category 2 Carcinogenicity - Category 1A Specific Target Organ Toxicity - Single Exposure - Category 1 ( kidneys , respiratory system ) Specific Target Organ Toxicity - Repeated Exposure - Category 1 ( respiratory system , Immune system , kidneys , lungs ) Hazardous to the Aquatic Environment - Acute - Category 1 Hazardous to the Aquatic Environment - Chronic - Category 3

Signal word

Danger

Hazard statements

H251 Self-heating; may catch fire. H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H350 May cause cancer. H370 Causes damage to organs. （kidneys , respiratory system ） H372 Causes damage to organs through prolonged or repeated exposure. （respiratory system , immune system , kidneys , lungs ） H400 Very toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P235+P410 Keep cool. Protect from sunlight. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves and eye/face protection. P260 Do not breathe dust. P264 Wash thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment.

Response

P391 Collect spillage. P307+P311 If exposed: Call a POISON CENTER or doctor/physician. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER or doctor if you feel unwell. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see label).

Storage

P405 Store locked up. P407 Maintain air gap between stacks/pallets. P413 Store bulk masses at temperatures not exceeding manufacturer recommendations. P420 Store away from other materials.

Disposal

Statement(s) of Unknown Acute Toxicity Inhalation 6.5% of the mixture consists of ingredient(s) of unknown acute toxicity. Statement(s) of Unknown Aquatic Toxicity 51.6% of the mixture consists of ingredient(s) of unknown acute aquatic toxicity. 51.6% of the mixture consists of ingredient(s) of unknown chronic aquatic toxicity.

Other hazards which do not result in classification

May form combustible dust concentrations in air. In normal use, as installed and maintained according to product literature, this material in its final form is not expected to be hazardous.