PERMETHOR SHIELD Liquid Insecticide

Hazard statements (CLP)

H302, H304, H317, H332, H410

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

SUSMP Classification

S6

ADG classification

Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500 kg(L) or less; or IBCs (refer to SP AU01). IATA/IMDG Classification: Where net quantity per single or inner packaging is 5 L or less for liquids or 5 kg or less for solids, goods may be transported as non-dangerous goods as provided in special provision A197 of the IATA regulations and section 2.10.2.7 of IMDG code. This product is always packed at 5 L or less. See details in Section 14 of this SDS.

UN Number

3082

2.1 Classification of the substance or mixture

Acute toxicity – Oral: Category 4 Acute toxicity – Inhalation: Category 4 Skin sensitization: Category 1

Aspiration hazard

Category 1 Hazardous to aquatic environment, long-term hazard: Category 1

Signal word

DANGER

Hazard statements

H302: Harmful if swallowed. H304: May be fatal if swallowed and enters airways. H317: May cause an allergic skin reaction. H332: Harmful if inhaled H410: Very Toxic to aquatic life with long lasting effects.

Prevention

P261: Avoid breathing mist and spray. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink, or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves.

Response

P312: Call a POISON CENTER/doctor/physician if you feel unwell. P301+P310 IF SWALLOWED Immediately call a POISON CENTRE/doctor/physician P330: Rinse mouth. P331: Do NOT induce vomiting. P302+P352 IF ON SKIN Wash with plenty of water P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P333+P313 If skin irritation or rash occurs Get medical advice/attention P362+P364: Take off contaminated clothing and wash it before reuse. P391: Collect spillage.

Storage

P405: Store locked up.

Disposal

P501: If they cannot be recycled, dispose of contents to an approved waste disposal plant and containers to landfill (see Section 13 of this SDS). Emergency Overview Physical Description & colour: Clear amber liquid. Odour: Aromatic odour.

Health hazards

Permethrin is harmful to non-harmful via the oral route, with a reported LD50 for technical permethrin in rats of over 5000 mg/kg. Via the dermal route, it is not harmful, with a reported dermal LD50 in rats of over 5000 mg/kg, and in rabbits of greater 2000 mg/kg.

Potential health effects

Inhalation: Short term exposure: This product may be harmful, but symptoms are not available. In addition, product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort. Long Term exposure: No data for health effects associated with long term inhalation. Skin Contact: Short term exposure: This product may be irritating to skin but is unlikely to cause anything more than mild transient discomfort. Long Term exposure: No data for health effects associated with long term skin exposure. Eye Contact: Short term exposure: Available data indicates that this product is not harmful. However, product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort. Long Term exposure: No data for health effects associated with long term eye exposure. Ingestion: Short term exposure: Significant oral exposure is considered to be unlikely. Available data shows that this product is harmful, but symptoms are not available. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Long Term exposure: No data for health effects associated with long term ingestion. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.