Basamid Granular

Engage Agro Corporation

Revision date : 2013-10-16

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GHS07
Health risk rating 4
Safety risk rating 1
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

208-576-7/533-74-4

Name of the chemical

Tetrahydro-3,5-dimethyl-1,3,5-thiadia­zine-2-thione

Concentration

97%

General Information

Revision date

2013-10-16

Product name

Basamid Granular

Product Synonyms

BASAMID® GRANULAR

CAS No.

533-74-4

Emergency telephone

involving a poisoning, major spill, or fire call 1-866-336-2983

Icons in SDS

Company Information

company name

Engage Agro Corporation

GHS Information

Signal word

WARNING!

Section 2

SECTION 2: Hazards identification

EMERGENCY OVERVIEW: WARNING! Dilution with water may generate poisonous gases (Methyl isothiocyanate (MITC)). Product is irritating to skin. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Harmful if swallowed. Harmful if inhaled. Harmful if absorbed through the skin. Irritating to eyes, nose and throat. Do not get on skin or clothing. Avoid breathing vapours from decomposition of product upon application. Do not get in eyes.

2.1 Classification of the substance or mixture

Xn, R22-36/37/38-43; N, R 50-53 The product is classified harmful and dangerous for the environment.

Health hazards

Harmful if swallowed, irritating to eyes, respiratory system and skin, may cause sensitization by skin contact.

Environmental hazards

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Principle Routes of Exposure

Skin contact, inhalation, ingestion, and eye contact with the solid product. As a result of use of the product, applicators and other person present in the area of the application can be exposed to MITC. This chemical can be evolved as a gas from the soil of an application. MITC has a horseradish like odor and can be very irritating to the eyes. If odor is detected near an application of Basamid Granular, notify the applicator of ® the problem and take appropriate measures to minimize/avoid exposure. Signs of Acute Overexposure: ® Overexposure to Basamid Granular as sold may result in skin irritation, excessive salivation, sweating, fatigue, weakness, nausea, headache, dizziness, eye, nose, throat and respiratory tract irritation. In addition, dilution to use levels results in the release of methyl isothiocyanate (MITC). Overexposure to MITC may result in strong skin and eye irritation, running nose, dizziness cramps, nausea, vomiting and mild to severe disturbances of the nervous system. Signs of Chronic Overexposure: Same as above, plus conjunctivitis, photophobia, digestive disturbances, weight loss, general bodily weakness, and blurred vision. In addition, laboratory studies have shown that exposure to the active ingredient, followed by ingestion of alcohol, may cause an adverse reaction, including low blood pressure, rapid heartbeat, and flushing of the skin. Consumption of alcohol during and after exposure to this product should be avoided. Other Potential Health Effects: Laboratory studies showed a potential for liver effects and kidney necrosis. This product is not listed as being carcinogenic by EPA.

Medical Conditions Generally Aggravated by Exposure

Impaired pulmonary functions and preexisting eye problems may be aggravated. Preexisting skin diseases may also be aggravated by exposure to the decomposition products. Care should be exercised and all label instructions should be followed, in the handling of products ® containing Basamid Granular.

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