Energizer Battery

SECTION 2: Hazards identification

OSHA Hazards Classification

Precautionary statements

Disposal Dispose of contents/container to an approved waste disposal plant.

2.3 Other hazards

Not applicable Unknown Toxicity 0.6% of the mixture consists of ingredient(s) of unknown toxicity

Further information

Very toxic to aquatic life with long lasting effects

Interactions with other chemicals

Use of alcoholic beverages may enhance toxic effects.

2.1 Classification of the substance or mixture

This product is an article which is sealed battery and as such does not require an SDS per the OSHA hazard communication standard unless Ruptured . The hazard indicated are for a ruptured battery . Acute toxicity - Oral Category 4 Acute toxicity - Inhalation (Gases) Category 4 Acute toxicity - Inhalation (Vapors) Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 1 Sub-category A Serious eye damage/eye irritation Category 2 Carcinogenicity Category 1A Reproductive toxicity Category 1A Specific organ toxicity ( repeated exposure) Category 2 GHS Label elements , including Precautionary statements. Emergency Overview Signal Word Danger Hazard Statements Harmful if swallowed Harmful if inhaled Cause severe skin burns and eye damage Cause serious eye irritation May cause caner May cause fertility or unborn child May cause damage to organs through prolonged or repeated exposure This product is an article which contains a chemical substance. Safety information is given for exposure to the article as sold. Intended use of the product should not result in exposure to the chemical substance. This is a battery. In case of rupture: The above hazards exist. Appearance: gray Black cuboid battery Physical State : Solid Odor : Odorless Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understand Use personal protective equipment as required Wash face, hands and exposed skin thoroughly after handing Do not eat ,drink or smoke when using this product Use only outdoor or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Precautionary Statements - Response Immediately call a POISON CENTER or doctor/physician Specific treatment ( see supplemental first aid instructions on this label) Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses , if present and easy to do . Continue rinsing. Immediately call a POISON CENTER or doctor/physician Skin IF ON SKIN( or hair): Remove /take off the immediately all contaminated clothing. Rinse shin with water/shower. Wash contaminated clothing before reuse . Inhalation IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable before breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Immediately call a POISON CENTER or doctor/physician Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth Do not induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant. Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 0.6% of the mixture consists of ingredient(s) of unknown toxicity Other information Very toxic to aquatic life with long lasting effects Interactions with other Chemicals Use of alcoholic beverages may enhance toxic effects. SECTION 3: COMPOSITION/ INFORMATION ON INGREDIENTS Chemical characterization :Mixtures . *PBB spies or PBDE spices is not involved Exposure Limits Air Exposure Limits (ug/m3) Material by Wt. CAS Number OSHA AGGIH NIOSH Lead 57 7439-92-1 50 150 100 Lead Oxide 22 1309-60-0 50 150 100 Electrolyte 14 7664-93-9 1 (Sulfuric Acid) Battery Pack（ABS) 7 9003-56-9 1 SECTION 4: FIRST-ACID MEASURE First aid measures General Advice First aid is upon rupture of sealed battery. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Seek immediate medical attention/advice. Remove contact lenses, if present and easy to do. Continue rinsing Skin Contact Immediate medical attention is required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes Inhalation Remove to fresh air. If symptoms persist, call a physician. If breathing has stopped, give artificial respiration. Get medical attention immediately. If not breathing, give artificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. If breathing is difficult, (trained personnel should) give oxygen. Seek immediate medical attention/advice. Delayed pulmonary edema may occur. Ingestion Do NOT induce vomiting. Rinse mouth. Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or clothing. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Use personal protective equipment as required. Wear personal protective clothing (see section 8). Most important symptoms and effects, both acute and delayed Most Important Symptoms and Effects Burning sensation. Lead poisoning is characterized by a metallic taste in the mouth, loss of appetite, indigestion, nausea, vomiting, constipation, sleep disturbances and overall weakness. Severe exposures can lead to shock, circulatory collapse and death. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum and high pulse pressure SECTION 5 : FIRE-FIGHTING MEASURE Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating gases and vapors. Uniform Fire Code Corrosive: Acid-Liquid Toxic: Liquid Hazardous Combustion Products Carbon oxides Explosion Data Sensitivity to Mechanical Impact No Sensitivity to Static Discharge No Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 :LEADAGE EMERGENCY TREATMENT Personal precautions, protective equipment and emergency procedures Personal Precautions Attention! Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Avoid generation of dust. Other Information Refer to protective measures listed in Sections 7 and 8 Environmental Precautions Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if safe to do so. Should not be released into the environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. SECTION 7 :HANDING AND STORAGE Precautions for safe handling Handling In case of rupture: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Use only with adequate ventilation and in closed systems. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Conditions for safe storage, including any incompatibilities Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moisture. Store locked up. Keep out of the reach of children. Store away from other materials Incompatible Products Acids. Bases. Oxidizing agent Section 8 : EXPOSURE CONTROLE/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH TWA: 50 μg/m3TWA: 50 μg/m3Pb Lead Action Level: 30 μg/m3 Poison, See 29 IDLH: 100 mg/m3 TWA: 0.05 mg/m3 7439-92-1 CFR 1910.1025 Action Level: 30 μg/m3 TWA: 0.050 mg/m3 Pb Poison, See 29 CFR 1910.102 TWA: 50 μg/m3Pb Lead dioxide Action Level: 30 μg/m3 Pb IDLH: 100 mg/m3Pb TWA: 0.05 mg/m3Pb 1309-60-0 Poison, See 29 CFR 1910.1025 TWA: 0.050 mg/m3Pb Sulfuric acid TWA: 1 mg/m3(vacated) IDLH: 15 mg/m3 TWA: 0.2 mg/m3 thoracic fraction TWA: 1 mg/m3 7664-93-9 TWA: 1 mg/m3 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health. Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., Other Exposure Guidelines 1992) See section 15 for national exposure control parameters Appropriate engineering controls Showers Engineering Measures Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection None required for consumer use. If splashes are likely to occur: Face protection shield. Wear protective gloves and protective clothing. Long sleeved clothing. Chemical resistant apron. Impervious Skin and Body Protection gloves. No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation Respiratory Protection is experienced, ventilation and evacuation may be required. Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Avoid contact with skin, eyes or Hygiene Measures clothing. Wear suitable gloves and eye/face protection. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. For environmental protection, remove and wash all contaminated protective equipment before re-use. SECTION 9: PHYSICAL/CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Solid Appearance Cuboid battery Odor Odorless Color Gray black Odor Threshold