CA80PH Reagent RK

Classification system

NFPA Rating NFPA ratings (scale 0 - 4) Health = 3 Fire = 0 Reactivity = 0

HMIS® ratings

(scale 0 - 4) HEALTH = ey ee ali 10] Fire = 0 FACTIVITY[0]| Reactivity = 0 (Contd. on page 2) usA— (Contd. of page 1)

2.3 Other hazards

The product does not contain any organic halogen compounds (AOX), nitrates, heavy metal compounds or formaldehydes.

PBT Substances

Not applicable Not applicable

vPvB Substances

Not applicable Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Not applicable

Hazardous Ingredients

CAS: 7664-93-9| sulphuric acid ees 15-25% € Skin Corr. 1A, H314 CAS: 7803-55-6 | Ammonium monovanadate s1% 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335

Additional information

For the wording of the listed hazard phrases refer to section 16 Description of first aid measures General information: Immediately remove any clothing soiled by the product. After inhalation: /n case of unconsciousness place patient stably in side position for transportation. After skin contact: ; Immediately wash with water and soap and rinse thoroughly. Immediately rinse with water. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Drink copious amounts of water and provide fresh air. Immediately call a doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. For safety reasons unsuitable extinguishing agents: no further information Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. Advice for firefighters No further relevant information available. Protective equipment: Mount respiratory protective device. Personal precautions, protective equipment and emergency procedures Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away. Wear protective clothing. (Contd. on page 3) UsA — (Contd. of page 2) Environmental precautions: Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: CAS: 7664-93-9 | sulphuric acid 0.20 mg/m? CAS: 7803-55-6 | Ammonium monovanadate 0.01 mg/m? PAC-2: CAS: 7664-93-9 | sulphuric acid 8.7 mg/m? CAS: 7803-55-6| Ammonium monovanadate 0.11 mg/m? PAC-3: CAS: 7664-93-9| sulphuric acid 160 mg/m? CAS: 7803-55-6 | Ammonium monovanadate 80 mg/m? Precautions for safe handling Do not dry clean dust covered objects and floors. Wash thoroughly with plenty of water. Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires: Keep respiratory protective device available. The lists that were valid during the creation were used as basis (Contd. on page 4) USA — (Contd. of page 3) Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves To avoid skin problems reduce the wearing of gloves to the required minimum. Only use chemical-protective gloves with CE-labeling of category Ill. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Material of gloves Nitrile rubber, NBR Chloroprene rubber, CR The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles Body protection: Protective work clothing Information on basic physical and chemical properties General Information Appearance: Form: Fluid Color: Light yellow Odor: Characteristic Odor threshold: Not determined. pH-value: Strongly acidic Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 100 °C (212 °F) Flash point: Not applicable. Flammability (solid, gaseous): Not applicable. (Contd. on page 5) usA— (Contd. of page 4) Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Not determined. Explosion limits: Lower: Not determined. Upper: Not determined. Vapor pressure at 20 °C (68 °F): 23 hPa (17.3 mm Hg) Density at 20 °C (68 °F): 1.25 g/cm? (10.431 Ibs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Fully miscible. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: Water: 69.8 % Solids content: 0.0 %

Storage

Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. Storage class: 8B Specific end use(s) No further relevant information available. Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit. At this time, the remaining constituent has no known exposure limits. CAS: 7664-93-9 sulphuric acid PEL | Long-term value: 1 mg/m? REL| Long-term value: 1 mg/m? TLV | Long-term value: 0.2* mg/m? *as thoracic fraction

Further information

No further relevant information available. Reactivity No further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: CAS: 7803-55-6 Ammonium monovanadate Oral] LD50| 160 mg/kg (rat) Primary irritant effect: on the skin: Strong caustic effect on skin and mucous membranes. on the eye: Strong caustic effect. Strong irritant with the danger of severe eye injury. Sensitization: No sensitizing effects known. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Corrosive (Contd. on page 6) USA — (Contd. of page 5) Irritant Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or unneutralized.

Other hazards

No further relevant information available Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. Recommended cleansing agent: Water, if necessary with cleansing agents.

UN Number

DOT, IMDG, IATA UN2796 UN proper shipping name DOT, IMDG SULPHURIC ACID solution IATA Sulphuric acid solution Transport hazard class(es) 8 Corrosive substances 8 (Contd. on page 7) UsA— (Contd. of page 6) Packing group DOT, IMDG, IATA Il

Environmental hazards

Not applicable. Special precautions for user Warning: Corrosive substances Hazard identification number (Kemler code): 80 EMS Number: F-A,S-B Segregation groups Strong acids Stowage Category B Segregation Code SG36 Stow "separated from" SGG18-alkalis. SG49 Stow "separated from" SGG6-cyanides Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: DOT Quantity limitations On passenger aircraft/rail: 1 L On cargo aircraft only: 30 L IMDG Limited quantities (LQ) 1L Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN "Model Regulation": UN 2796 SULPHURIC ACID SOLUTION, 8, II Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): CAS: 7664-93-9| sulphuric acid Section 313 (Specific toxic chemical listings): CAS: 7664-93-9 | sulphuric acid CAS: 7803-55-6| Ammonium monovanadate TSCA (Toxic Substances Control Act): CAS: 7732-18-5 | water ACTIVE CAS: 7664-93-9| sulphuric acid ACTIVE CAS: 7803-55-6 | Ammonium monovanadate ACTIVE Hazardous Air Pollutants None of the ingredients is listed. Proposition 65 Chemicals known to cause cancer: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. Cancerogenity categories EPA (Environmental Protection Agency) None of the ingredients is listed. (Contd. on page 8) USA — (Contd. of page 7) TLV (Threshold Limit Value) CAS: 7664-93-9 | sulphuric acid |A2 MAK (German Maximum Workplace Concentration) CAS: 7664-93-9 | sulphuric acid |4 NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05 Signal word Danger Hazard-determining components of labeling: sulphuric acid Hazard statements Causes severe skin burns and eye damage. Precautionary statements If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.