Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
64742-95-6
Name of the chemical
Solvent naphtha (petroleum), light arom
Concentration
75%
General Information
Revision date
2024-11-30
Product name
TS200 Acrylic Topical Sealer SB-25 w/ High Gloss Wet Look
Product Synonyms
EMECOLE Aromatic 322, Isocyanate
Chemical name
Polymeric Diphenylmethane DiiIsocyanate
1.2.1 Relevant identified uses
Concrete Curing Compound and High Gloss Sealer
supplier name
including Address
Emergency telephone
800-424-9300, 1-800-535-5053
Icons in SDS
Company Information
company name
EMECOLE, INC
e-mail address of the competent person responsible for the Safety Data Sheet
info@emecole.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H226, H332, H335, H336
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
H332
Harmful if inhaled
H335
May cause respiratory irritation
H336
May cause drowsiness or dizziness
Section 2
SECTION 2: Hazards identification
OSHA 2. Hazard(s) Emergency Identifi Overview cation Skin Contact
Hazard categories
Statements Do not 1 handle Do not until handle all safety until precautions all safety precautions have been have Safety Data Sheet (SDS) read and been understood read and understood Do not breathe vapors. In vapors Acute Toxicity, Inhalation--Category 4 case of In inadequate case of inadequate ventilation ventilation wear respiratory protection. protection Wear protective gloves and gloves eye protection and eye protection Do not eat, drink not eat, or smoke drink or when smoke using when this using product this Wash product thoroughly Wash thoroughly after handling after Store handling locked Store up. locked Keep away up. Keep from away from children. children Dispose of Dispose Label Elements, including precautionary statements
Contains
of contents and container and 12. container in accordance
ECOLOGICAL INFORMATION
in accordance with applicable local, regional local, and regional national and regulations. national regulations.
Signal word
Danger Signal DANGER Word: DANGER Aquatic Toxicity
Hazard statements
H226 Chronic: Chronic: As a result As of a Acute Flammable Liquid and Vapour. previous result And of repeated Prolonged previous overexposure repeated Toxicity To overexposure Fish: or a LC50: single > large or 500 a mg/l single dose, (Zebra large certain fish(Brachydanio dose, individuals certain rerio), individuals 24 hrs) develop isocyanine sensitization (chemical (chemical asthma) or asthma) tissue injury or tissue in the injury upper in respiratory the upper tract. respiratory skin contact H332 Animal tract. tests Animal indicate tests indicate to Harmful allergic if Acute And Prolonged Toxicity To Fish LC50 > 500 mg/l (Water flea (Daphnia magna), 24 hrs) inhaled. reaction. These be permanent. skin alone contact may alone also may lead also lead to respiratory allergic respiratory reaction. effects These may effects may be permanent. Any person Any person developing asthmatic asthmatic H335 reaction or reaction other sensitization May cause respiratory irritation. or other sensitization should be should removed be from removed further from exposure. further exposure. Other Effects H336
Potential health effects
At room temperature, MDI vapors are minimal due to low vapor pressure. However, heating, of Overexposure: In a recently May cause 13. completed drowsiness
Disposal
Considerations study, or dizziness. groups of rats were exposed for 6 hours/day, 5 days/ week for a lifetime to atmospheres of respirable polymeric MDI aerosol. Tumor incidence, both benign and malignant, foaming or otherwise dispersing (drumming, venting or pumping) operations may generate more vapor or aerosol and the number of animals with tumors were not different from controls. There were no lung tumors at 1 mg/m3 concentrations of isocyanate. Excessive exposure may cause irritation of the eyes, upper respiratory tract and lungs. Any disposal practice must be in compliance with all federal, state and local laws and regulations. Chemical and no effects at .2 mg/m3. However, at Concrete the top level additions, processing, storage, or otherwise altering this material may make the waste management information Sealers only USA of 6 | mg/m3 P.O. Box there 5464 was | De a Pere, significant WI 54115 incidence of a benign Severe overexposure may lead to pulmonary edema. Respiratory sensitization with asthma like symptoms may occur presented in this SDS incomplete, inaccurate or otherwise inappropriate. Waste characterization and disposal tumor of in the susceptible lung (adenoma) individuals. and one MDI malignant concentration compliance is the responsibility solely of the party generating the waste or deciding to discard or dispose of the Toll-Free: tumor 888.583.2991 (adenocarcinoma). below the exposure The | Emergency: guidelines increased 800.424.9300 may incidence cause allergic for lung respiratory tumors reactions is associated in individuals with the prolonged already sensitized. respiratory info@concretesealersusa.com Symptoms irritation and may the include concurrent | coughing, www.concretesealersusa.com accumulation dryness of of yellow throat, material headache, in the nausea, lung Continues on next page diffi culty material. that was breathing observed and throughout feeling the of tightness study. in the chest. Effects may be delayed. Impaired lung function (decreased ventilators Refer to RCRA 4 CFR 261 and/or any other appropriate federal, state or local requirements for proper classifi cation information. or Allergy Drums/containers Problems Must must Not be thoroughly Be Exposed drained to This to process Product. or storage vessels before removal to an appropriate area for subsequent decontamination. Drums/containers must be decontaminated in properly to our products Carcinogenicity: as ingredients, MDI and some polymeric listed chemicals may be present in the raw materials from suppliers and over ventilated MDI are areas not by listed personnel by the protected NTP, IARC from or the regulated inhalation by of isocyanate
2.1 Classification of the substance or mixture
Inhalation: No known health information on inhalation of vapors. Vapors and aerosols probably affect respiratory Eye Contact: As a liquid or dust may cause irritation, inflammation and or damage to sensitive eye tissue. Symptoms include Flammable watering Liquids--Category or discomfort 3 of eyes. Corneal injury is unlikely. tract. MDI can induce respiratory irritation with asthma-like symptoms. These symptoms may be immediate or delayed Ingestion: up to several Single Hazardous to the Aquatic Environment, Long-Term (Chronic) Hazard--Category 2 hours dose after oral exposure. toxicity There is considered are reports to that be extremely long-term low. exposure Can result may result in irritation in decreased and corrosive lung action in function. mouth, Specific stomach target organ tissue toxicity, and Single digestive January 15, 2015 exposure--Category tract. 3 Precautionary Aspiration Statements: Hazard--Category Statements: Do not 1 handle Do not until handle all safety until precautions all safety precautions have been have Safety Data Sheet (SDS) read and been understood. read and understood. Do not breathe vapors. In vapors. Acute Toxicity, Inhalation--Category 4 case of In inadequate case of inadequate ventilation ventilation wear respiratory protection. protection. Wear protective gloves and gloves eye protection. and eye protection. Do not eat, drink not eat, or smoke drink or when smoke using when this using product. this Wash product. thoroughly Wash thoroughly after handling. after Store handling. locked Store up. locked Keep away up. Keep from away from children. children. Dispose of Dispose Label Elements, including precautionary statements contents of contents and container and 12.