Tangerine

Hazard statements (CLP)

H226, H304, H315, H317, H410

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

1999/45/EC Classification of the substance: Essential oil

Hazard categories

Flam. Liq. 3 H226 Skin Irrit. 2 H315 Skin Sens. 1 H317 Asp. Tox. 1 H304 Aquatic Chronic 1 H410

Hazardous Ingredients

Limonene

Hazard pictograms

GHS02 GHS07 GHS08 GHS09

Signal word

Danger

Hazard statements

H226: Flammable liquid and vapour H315: Causes skin irritation H317: May cause an allergic skin reaction H304: May be fatal if swallowed and enters airways H410: Very toxic to aquatic life with long lasting effects

Precautionary statements

P210: Keep away from heat / sparks/ open flames/ hot surfaces/ no smoking P241: Use explosion-proof electrical/ventilating/lighting equipment P261: Avoid breathing dust/fume/gas/mist/vapours/spray P280: Wear Protective Gloves / protective clothing/ eye protection/ face protection P273: Avoid release to environment P301+P310 If swallowed immediately call a poison center or doctor/physician P303+P361+P353 If on skin (or hair) Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P331: Do not induce vomiting P405: Store locked up P501: Dispose of contents / container in accordance with local regulations.

2.1 Classification of the substance or mixture

2.1.1 Classification according to Regulation (EC) No 1272/2008 (CLP/GHS) Hazard classes and Hazard Statements Hazard categories Flam. Liq. 3 H226 Skin Irrit. 2 H315 Skin Sens. 1 H317 Asp. Tox. 1 H304 Aquatic Chronic 1 H410 2.1.2 Classification according to 67/548/EEC and 1999/45/EC Xn, N R10/38/43/50-53/65 2.1.3 Additional information: The product has to be labelled according to the calculation procedure of the “General Classification guideline for preparations of the EU” in the latest valid version. The classification is according to the latest edition of EU-lists, and added to by company and literature data. Full text of R-, H- and EUH-phrases: see section 16 2.2 Label Elements 2.2.1 Labelling according Regulation (EC) No. 1272/2008 (CLP/GHS) Substance: Tangerine Hazard component for labelling: Limonene Hazard Pictograms GHS02 GHS07 GHS08 GHS09 Signal word: Danger Hazard statements: H226: Flammable liquid and vapour H315: Causes skin irritation H317: May cause an allergic skin reaction H304: May be fatal if swallowed and enters airways H410: Very toxic to aquatic life with long lasting effects Precautionary Statements: P210: Keep away from heat / sparks/ open flames/ hot surfaces/ no smoking P241: Use explosion-proof electrical/ventilating/lighting equipment P261: Avoid breathing dust/fume/gas/mist/vapours/spray P280: Wear Protective Gloves / protective clothing/ eye protection/ face protection P273: Avoid release to environment P301+P310: If swallowed: immediately call a poison center or doctor/physician P303+P361+P353: If on skin (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P331: Do not induce vomiting P405: Store locked up P501: Dispose of contents / container in accordance with local regulations. 3.COMPOSITION / INFORMATION ON INGREDIENTS 3.1 Description of the mixture: Mixture mainly consisting of the following components: Cas Einecs Range Name Classification according to 67/548/EEC 5989-27-5 227-813-5 60-99% Limonene R10-38-43-50/53 Cas Einecs Range Name Classification according to EC 1272/2008 (CLP) 5989-27-5 227-813-5 60-99% Limonene Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chr. 1, H400 Aquatic Chr. 1, H410 Cas Einecs Range Name Classification according to 67/548/EEC 78-70-6 201-134-4 0-9% Linalool R38 Cas Einecs Range Name Classification according to EC 1272/2008 (CLP) 78-70-6 201-134-4 0-9% Linalool Skin Irrit. 2, H315 Cas Einecs Range Name Classification according to 67/548/EEC 5392-40-5 226-394-6 0-3% Citral R38-43 Cas Einecs Range Name Classification according to EC 1272/2008 (CLP) 5392-40-5 226-394-6 0-3% Citral Skin Irrit. 2, H315 Skin Sens. 1, H317 Cas Einecs Range Name Classification according to 67/548/EEC 123-35-3 204-622-5 0-5% Myrcene R10-65 Cas Einecs Range Name Classification according to EC 1272/2008 (CLP) 123-35-3 204-622-5 0-5% Myrcene Flam. Liq. 3, H226 Asp. Tox. 1, H304 Cas Einecs Range Name Classification according to 67/548/EEC 98-55-5 202-680-6 0-2% Alpha-Terpineol R38 Cas Einecs Range Name Classification according to EC 1272/2008 (CLP) 98-55-5 202-680-6 0-2% Alpha-Terpineol Skin Irrit. 2, H315 Cas Einecs Range Name Classification according to 67/548/EEC 80-56-8 201-291-9 0-4% Alfa Pinene R10-43-50/53-65 Cas Einecs Range Name Classification according to EC 1272/2008 (CLP) 80-56-8 201-291-9 0-4% Alfa Pinene Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chr. 1, H400 Aquatic Chr. 1, H410 Cas Einecs Range Name Classification according to 67/548/EEC 124-13-0 204-683-8 0-5% Octanal R10-36/38-52/53 Cas Einecs Range Name Classification according to EC 1272/2008 (CLP) 124-13-0 204-683-8 0-5% Octanal Flam. Liq. 3, H226 Skin Irrit. 2, H315 Ser. Eye Damage/ Eye Irr. 2, H319 Chr. Haz. 3, H412 Cas Einecs Range Name Classification according to 67/548/EEC 112-31-2 203-957-4 0-6% Decanal R38-52/53 Cas Einecs Range Name Classification according to EC 1272/2008 (CLP) 112-31-2 203-957-4 0-6% Decanal Skin Irrit. 2, H315 Chr. Haz. 3, H412 Cas Einecs Range Name Classification according to 67/548/EEC 106-23-0 203-376-6 0-1% Citronellal R38-43-52/53 Cas Einecs Range Name Classification according to EC 1272/2008 (CLP) 106-23-0 203-376-6 0-1% Citronellal Skin Irrit. 2, H315 Skin Sens. 1, H317 Haz. Acq. 2, H411 Cas Einecs Range Name Classification according to 67/548/EEC 99-85-4 202-794-6 0-5% Gamma R10-65 Terpinene Cas Einecs Range Name Classification according to EC 1272/2008 (CLP) 99-85-4 202-794-6 0-5% Gamma Flam. Liq. 3, H226 Terpinene Asp. Tox. 1, H304 4.FIRST AID MEASURES General information: If health disorders happens, call for medical help immediately. Immediately remove any clothing soiled by the product. 4.1 Inhalation: Attend to fresh air. In case of complaints seek medical attention. 4.2 Skin contact: In case of contact with skin wash immediately with soap and water. 4.3 Eye contact: In case of contact with eyes rinse thoroughly with water. 4.4 Swallowing: If swallowed, do not induce vomiting: call for medical help immediately. 5.FIRE-FIGHTING MEASURES 5.1 Suitable extinguishing media: CO2, alcoholresistant foam 5.2 Unsuitable extinguishing media: Water 5.3 Special exposure hazards arising from the substance or preparation itself, combustion products or resulting gases: Vapours may form explosive mixture with air. 5.4 Special protective equipment for fire-fighters: Wear self-contained breathing apparatus and protective suits. Additional information: Cool endangered receptacles with water spray. Collect contaminated fire fighting water separately. It must not enter the sewage system. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipments and emergency procedures 6.1.1 Personal precaution: follow safety measures in Section 7 and 8. Use personal protective equipment. 6.2 Environmental precautions: Do not allow to enter canalisation/waterways/groundwater Inform respective authorities in case of seepage into water course or sewage system. 6.3 Clean up methods: Soak up with absorbent, inert material (sand, universal binders) and dispose contaminated material as waste according to section 13. Dispose of in accordance with federal, state and local environmental regulations. Reference to other sections: Keep ignition source away, do not smoke and avoid flames. 7.HANDLING AND STORAGE 7.1 Precautions for safe handling: Use only in well ventilated area. Avoid contact with skin, eyes and clothing. NO SMOKING. 7.2 Information on fire and explosion protection: Keep away from possible sources of ignition. No smoking. 7.2 Storage: Store in well filled tight suitable containers; drums should only be considered as a means of transportation. Do not store with flammable or explosive materials and strong oxidizing agents. Keep drums tightly closed. Store dark, dry and under cold temperatures. Protect against warming / overheating. Recommended storage temperature: 8-12°C. 7.3 Advice on general occupational hygiene: Avoid excessive inhalation of concentrated vapours. Follow good manufacturing practices for housekeeping and personal hygiene. No eating , drinking and smoking during work. Avoid contact with the eyes and skin. Remove contaminated clothing.Wash hands thoroughly before breaks and at the end of the working day. 8.EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters 8.1.1 Ingredients with limit values that require monitoring at the workplace: 5989-27-5 (R)-p-mentha-1,8-diene 8.2 Exposure controls 8.2.1 Personal protection equipment, general protective and hygienic measures Use personal protective euipment. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of the work. Avoid contact with the eyes and the skin. 8.2.2.1 Eye/Face protection: Use tightly sealed goggles. 8.2.2.2 Skin protection: Use protective gloves. Type of material of gloves: The material of the gloves has to be impermeable and resistant to the product/the substance/the preparation/the chemical mixture. However due to the missing information available because no tests have been conducted, the choice of the material of the gloves should take into account the penetration time, rates of diffusion and the degradation. Breakthroughtime of the glove material: The penetration time of the glove material must be set by the manufacturer of the protective gloves according to the substance/the preparation/the chemical mixture. 8.2.2.3 Respiratory protection: Wear suitable respiratory equipment in case of insufficient ventilation. Suitable respiratory protection: filter class A2 (brown colour). Use the rules for application of respiratory protection systems. 9.PHYSICAL AND CHEMICAL PROPERTIES 9.1 Important health, safety and environmental information 9.1.1 Appearance Physical state: Liquid Colour: According to specifciations Odour: Characteristic 9.2.2 Safety relevant basic data Boiling point: Not determined Flash point: 47°C Esplosive properties: Product is not esplosive; however formation of esplosive air/vapour mixtures are possibile. Solubilità/water solubilità: Not miscibile Self-igniting: Product is not selfigniting, but in case of unpropitious storing conditions (air admission, heat accumulation) selfignition is possible for moistened solids (e.g. cloth, pulp, filter panels, binder). Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures are possible 10.STABILITY AND REACTIVITY Reactivity Chemical Stability 10.1 Thermal decomposition /Conditions to avoid: Heating causes vaporisation and formation of ignitable atmospher is possible. Direct source of heat. 10.2 Incompatible materials: Strong acids and oxidising agents 10.3 Possibility of hazardous reactions: Formation of explosive gas mixture with air possible. In case of unpropitious storing conditions (air admission, heat accumulation) selfignition is possible for moistened solids (e.g. cloth, pulp, filter panels, binder) 10.4 Hazardous decomposition products: No dangerous decomposition known. 11.TOXICOLOGICAL INFORMATION Acute toxicity: LD/LC50 values relevant for classification: Cas : 5989-27-5 (R) – p-mentha-1,8-diene LD 50 oral (rat) 4400mg/Kg Acute effects: Primary irritant effect: On the skin: Irritant to skin and to mucous membranes. On the eyes: Irritating effect. Sensitisation: Sensitisation through skin contact. Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparation as issued in the latest version. Irritant. Sensitisation: Sensitisation through skin contact. 12.ECOLOGICAL INFORMATION General information: Water hazard class 1 (German regulation) (VwVwS3824, Cas 84929-31-7) Do not allow to enter canalisation / waterways / groundwater. Biodegradation: no data available. Ecotoxic effects: Very toxic to aquatic organism, may cause long term adverse effects in the aquatic environment. Warning – The safety of this product has not been determined General notes: Also poisonous for fish and plankton in water bodies. May cause lomg-term adverse effects in the aquatic enviroment. Very toxic for aquatic organisms Water hazard class 2 (German regulation) (VwVwS 3822; CAS 84929-38-4): hazardous for water 13.DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Recycling is preferred to disposal and burning. If recycling is not possible, dispose in accordance with federal, state and local environmental regulations. Must not be disposed together with household garbage. Do not allow product to reach sewage system. European Waste catalogue 02 03 03 Wastes from solvent extraction 13.2 Uncleaned packaging: Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning. Packagings that may not be cleansed are to be disposed of in the same manner as the product. Moistened solids (e.g. cloth, pulp, filter panels, binder) can be burnt after consulting with the waste disposal facility operator and the pertinent authorities and adhering to the necessary technical regulations. 14.TRANSPORT INFORMATION 14.1 Land trasport (ADR/RID): UN-No: 1169 Proper shipping name: Extracts, Aromatic, Liquid Class: 3 Subsidiary Risk: not applicable Packing group: III Hazard Label: 3 14.2 Sea transport (IMO): UN-No: 1169 Proper shipping name: Extracts, Aromatic, Liquid Class: 3 Packing group: III Marine pollutant: Yes EMS: F-E, S-D 14.3 Air transport (ICAO/IATA): UN-No: 1169 Proper shipping name: Extracts, Aromatic, Liquid Class: 3 Subsidiary Risk: not applicable Packing group: III 15.REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture · National regulations: · Information about limitation of use: Employment restrictions concerning juveniles must be observed. Employment restrictions concerning pregnant and lactating women must be observed. · Breakdown regulations: Critical quantity values according to the regulations on accidents should be adhered to. · Waterhazard class: Water hazard class 2 (German regulation) (VwVwS 3822; CAS 84929-38-4): hazardous for water · Other regulations, limitations and prohibitive regulations Comply with the rules and regulations of skin protection. Comply with the rules and regulations of respiratory protection. 16.OTHER INFORMATION The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its application. This information is designed only as guidance for the safe handling, use, processing, storage, transportation, disposal and should not to be considered as a warranty or quality specification. Reccomended restriction of use: For industrial applications only. Classification according to regulation EC 1207/2008 (CLP) Hazard statements: H226: Flammable liquid and vapour H315: Causes skin irritation H317: May cause an allergic skin reaction H304: May be fatal if swallowed and enters airways H410: Very toxic to aquatic life with long lasting effects Precautionary Statements: P210: Keep away from heat / sparks/ open flames/ hot surfaces/ no smoking P241: Use explosion-proof electrical/ventilating/lighting equipment P261: Avoid breathing dust/fume/gas/mist/vapours/spray P280: Wear Protective Gloves / protective clothing/ eye protection/ face protection P273: Avoid release to environment P301+P310: If swallowed: immediately call a poison center or doctor/physician P303+P361+P353: If on skin (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P331: Do not induce vomiting P405: Store locked up P501: Dispose of contents / container in accordance with local regulati Relevant R- and S- phrases: Risk phrases R 10: Flammable R 38: Irritating to skin R 43: May cause sensitisation by skin contact R 50/53: Very toxic to aquatic organism, may cause long term adverse effects in the aquatic environment. R 65: Harmful: may cause lung damage if swallowed. Safety phrases: S 24: Avoid contact with the skin S 37: Wear suitable gloves S 61: Avoid release to the environment. Refer to special instructions/ material safety data sheets S62: If swallowed, do not induce vomiting : seek medical advise immediately and show this container or label. SPECIFICATIONS Product: Tangerine Colour : CLEAR ORANGE LIQUID Odour : Characteristic Specific Gravity 15°C : 0,8470/0,8600 Refractive Index 20°C : 1,4700/1,4780 Optical rotation 15°C : 85/98 Aldehydes calculated as Citral : Min. 0.3% Vegetarian & Vegan Suitability Statement PRODUCT NAME: Tangerine Essential Oil Ekokoza s.r.o. can confirm that the above listed product has not been tested in animals and does not contain dairy or any other animal product, by product or derivative and is therefore suitable for vegetarian and vegan use. 28/01/19