PEPPERMINT OIL (MENTHA PIPERITA)

Hazard statements (CLP)

H315, H317, H319, H412

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Classification of the substance or mixture Classification (SI 2019 No. 720)

Physical hazards

Not Classified

Health hazards

Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317

Environmental hazards

Aquatic Chronic 3 - H412 Human health Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation Environmental The product contains a substance which is harmful to aquatic organisms

2.2 Label elements

EC number 282-015-4

Signal word

Warning

Hazard statements

H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. P264 Wash contaminated skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P302+P352 IF ON SKIN: Wash with plenty of water. P321 Specific treatment (see medical advice on this label). P332+P313 If skin irritation occurs: Get medical advice/ attention. P333+P313 If skin irritation or rash occurs: Get medical advice/ attention. P337+P313 If eye irritation persists: Get medical advice/ attention. P362+P364 Take off contaminated clothing and wash it before reuse. P501 Dispose of contents/ container in accordance with national regulations.

Precautionary statements

P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P262 Do not get in eyes, on skin, or on clothing. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P331 Do NOT induce vomiting.

Contains

trans-menthone, 1, 8 cineole, d,l-Isomenthone, (S)-p-mentha-1,8-diene, Beta Caryophyllene, Alpha Pinene, Beta Pinene, Sabinene, 7-methyl-3-methyleneocta-1,6-diene

Supplemental label elements

P261 Avoid breathing vapour/ spray.

2.1 Classification of the substance or mixture

Classification (SI 2019 No. 720) Physical hazards Not Classified Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Environmental hazards Aquatic Chronic 3 - H412 Human health Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Environmental The product contains a substance which is harmful to aquatic organisms. 2.2. Label elements EC number 282-015-4 Hazard pictograms Signal word Warning Hazard statements H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. Precautionary statements P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P262 Do not get in eyes, on skin, or on clothing. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P331 Do NOT induce vomiting. Contains trans-menthone, 1, 8 cineole, d,l-Isomenthone, (S)-p-mentha-1,8-diene, Beta Caryophyllene, Alpha Pinene, Beta Pinene, Sabinene, 7-methyl-3-methyleneocta-1,6-diene Supplementary precautionary P261 Avoid breathing vapour/ spray. statements P264 Wash contaminated skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P302+P352 IF ON SKIN: Wash with plenty of water. P321 Specific treatment (see medical advice on this label). P332+P313 If skin irritation occurs: Get medical advice/ attention. P333+P313 If skin irritation or rash occurs: Get medical advice/ attention. P337+P313 If eye irritation persists: Get medical advice/ attention. P362+P364 Take off contaminated clothing and wash it before reuse. P501 Dispose of contents/ container in accordance with national regulations. 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.2. Mixtures L-Menthol >= 30 <=55 CAS number: 2216-51-5 EC number: 218-690-9 Classification Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 trans-menthone >=12 <=33 CAS number: 89-80-5 EC number: 201-941-1 Classification Acute Tox. 4 - H302 Aquatic Chronic 3 - H412 1, 8 cineole >=2 <=10 CAS number: 470-82-6 EC number: 207-431-5 Classification Flam. Liq. 3 - H226 Skin Sens. 1B - H317 1-Menthylacetate(1alpha,2beta,5alpha) >=2 <=10 CAS number: 2623-23-6 EC number: 220-076-0 Classification Aquatic Chronic 2 - H411 d,l-Isomenthone >=1 <=6 CAS number: 491-07-6 EC number: 207-727-4 Classification Skin Irrit. 2 - H315 Skin Sens. 1B - H317 menthyl acetate 2 - 10% CAS number: 89-48-5 EC number: 201-911-8 Classification Aquatic Chronic 2 - H411 (S)-p-mentha-1,8-diene >=0.01 <=3 CAS number: 5989-54-8 EC number: 227-815-6 M factor (Acute) = 1 M factor (Chronic) = 1 Classification Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Asp. Tox. 1 - H304 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 neo-menthol >=2 <=8 CAS number: 2216-52-6 EC number: 218-691-4 Classification Skin Irrit. 2 - H315 Beta Caryophyllene >=0.01 <=3.5 CAS number: 87-44-5 EC number: 201-746-1 Classification Skin Sens. 1B - H317 Asp. Tox. 1 - H304 Aquatic Chronic 4 - H413 menthofuran >=0.01 <=9 CAS number: 494-90-6 EC number: 207-795-5 Classification Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Aquatic Chronic 2 - H411 Alpha Pinene >=0.01 <=2 CAS number: 80-56-8 EC number: 201-291-9 M factor (Acute) = 1 M factor (Chronic) = 1 Classification Flam. Liq. 3 - H226 Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Asp. Tox. 1 - H304 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Beta Pinene >=0.01 <=2 CAS number: 127-91-3 EC number: 242-060-2 M factor (Acute) = 1 M factor (Chronic) = 1 Classification Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Asp. Tox. 1 - H304 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Sabinene >=0.01 <=1.5 CAS number: 3387-41-5 EC number: 222-212-4 Classification Acute Tox. 4 - H302 7-methyl-3-methyleneocta-1,6-diene >=0.01 <=1 CAS number: 123-35-3 EC number: 204-622-5 M factor (Acute) = 1 Classification Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Asp. Tox. 1 - H304 Aquatic Acute 1 - H400 Aquatic Chronic 2 - H411 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove affected person from source of contamination. Get medical attention if any discomfort continues. Ingestion Rinse mouth thoroughly with water. Get medical attention immediately. Skin contact Remove contaminated clothing and rinse skin thoroughly with water. Get medical attention if irritation persists after washing. Eye contact Remove any contact lenses and open eyelids wide apart. Rinse immediately with plenty of water. Continue to rinse for at least 15 minutes and get medical attention. 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Extinguish with foam, carbon dioxide or dry powder. Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media 5.2. Special hazards arising from the substance or mixture Hazardous combustion Carbon dioxide (CO2). Organic compounds. products 5.3. Advice for firefighters Protective actions during Cool containers exposed to heat with water spray and remove them from the fire area if it can firefighting be done without risk. Avoid inhalation of vapours. Special protective equipment Use protective equipment appropriate for surrounding materials. for firefighters SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid inhalation of vapours/spray and contact with skin and eyes. Provide adequate ventilation. 6.2. Environmental precautions Environmental precautions Do not discharge into drains or watercourses or onto the ground. 6.3. Methods and material for containment and cleaning up Methods for cleaning up Soak up spillage with sand or other inert material. Transfer soaked material to suitable waste container and dispose according to prevailing regulations. If spillage on water occurs, remove from the surface with suitable absorbent material. Dispose according to National and international Environmental regulations. 6.4. Reference to other sections Reference to other sections For personal protection, see Section 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Avoid inhalation of vapours/spray and contact with skin and eyes. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not eat, drink or smoke when using this product. 7.2. Conditions for safe storage, including any incompatibilities Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. 7.3. Specific end use(s) SECTION 8: Exposure controls/Personal protection 8.1. Control parameters L-Menthol (CAS: 2216-51-5) DNEL Workers - Inhalation; Long term systemic effects: 132 mg/m³ Workers - Dermal; Long term systemic effects: 19 mg/kg, bw/day General population - Inhalation; Long term systemic effects: 33 mg/m³ General population - Dermal; Long term systemic effects: 9.4 bw/day, mg/kg General population - Oral; Long term systemic effects: 9.4 mg/kg, bw/day PNEC - Fresh water; Short term 15.6 mg/l - Intermittent release, Fresh water; 156 mg/l - marine water; Short term 1.56 mg/l - STP; Short term 2.37 mg/l - Sediment (Freshwater); Short term 28.9 mg/kg - Sediment (Marinewater); Short term 28.9 mg/kg - Soil; Short term 48.4 mg/kg 1, 8 cineole (CAS: 470-82-6) DNEL Workers - Inhalation; Long term systemic effects: 7.05 mg/m³ Workers - Dermal; Long term systemic effects: 2 bw/day, mg/kg General population - Inhalation; Long term systemic effects: 1.74 mg/m³ General population - Dermal; Long term systemic effects: 1 bw/day, mg/kg General population - Oral; Long term systemic effects: 600 mg/kg, bw/day PNEC - Fresh water; Short term 5.7 mg/l