Grapefruit oil

Hazard statements (CLP)

H226, H304, H315, H317, H410

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H410, Very toxic to aquatic life with long lasting effects. M factor None

Additional information

None

Precautionary statements

P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P233, Keep container tightly closed. P240, Ground/bond container and receiving equipment. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303/361/353, IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P331, Do NOT induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P370/378, In case of fire Use for extinction Foam, Dry chemical, Carbon dioxide P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. P501, Dispose of contents/container to: approved disposal site.

Other hazards

Hydrocarbon Concentration %: 95.0000%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Flammable Liquid, Hazard Category 3 danger: Skin Corrosion / Irritation Category 2 Sensitization - Skin Category 1 Aspiration Hazard Category 1 Hazardous to the Aquatic Environment - Acute Hazard Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 1 H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H410, Very toxic to aquatic life with long lasting effects. 3 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Danger Hazard statements: H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H410, Very toxic to aquatic life with long lasting effects. M factor: None Supplemental None Information: Precautionary P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. statements: P233, Keep container tightly closed. P240, Ground/bond container and receiving equipment. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303/361/353, IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P331, Do NOT induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P370/378, In case of fire: Use for extinction: Foam, Dry chemical, Carbon dioxide. P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. P501, Dispose of contents/container to: approved disposal site. 3 Pictograms: 2.3 Other hazards Other hazards: Hydrocarbon Concentration %: 95.0000% Section 3. Composition / information on ingredients 3.1 Substances Product identifier: Grapefruit oil; CAS: 8016-20-4 Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs Flam. Liq. 3-Skin Irrit. 2-Skin Sens. 1B-Asp. Tox 1-Aquatic Acute 1- d-Limonene 5989-27-5 227-813-5 50-100% Aquatic Chronic 1; H226-H304-H315- H317-H410,- Flam. Liq. 3-Skin Irrit. Myrcene 123-35-3 204-622-5 1-<5% 2-Eye Irrit. 2-Asp. Tox 1;H226-H304-H315- H319,- Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: Flush immediately with water for at least 15 minutes. Contact physician if symptoms persist. Skin exposure: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 4.2 Most important symptoms and effects, both acute and delayed May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin reaction. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. 3 Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Use in accordance with good manufacturing and industrial hygiene practices. 3 Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Not Applicable 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Physical State/Colour: clear, water white to orange coloured mobile liquid Odour: Strong citrus, characteristic grapefruit Odour threshold: Not determined Melting point/freezing point: Not determined Boiling point or initial boiling point and boiling Not determined range: Flammability: Not determined Lower and upper explosion limit: Not determined Flash point: 46 °C Auto-ignition temperature: Not determined Decomposition temperature: Not relevant pH: Not determined Kinematic viscosity