CEDARLEAF, ESSENTIAL OIL

Hazard statements (CLP)

H224, H226, H302, H304, H317, H411

Code

Statements

H224

Extremely flammable liquid and vapour

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE THE FULL TEXT FOR ALL HAZARD STATEMENTS IS DISPLAYED IN SECTION 16 CLASSIFICATION (67/548/EEC) NO ADDITIONAL DATA AVAILABLE ASPIRATION TOXICITY CATEGORY 1 - (H304). ACUTE TOXICITY ORAL 4 (H302) CLASSIFICATION (EU1272/2008) SKIN SENSITIZATION CATEGORY 1 - (H317) CHRONIC AQUATIC TOXICITY CATEGORY 2 - (H411) FLAMMABLE LIQUIDS CATEGORY 3 - (H226)

2.2 Label elements

GHS09

Signal word

DANGER. DANGER. P280 - WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION. P210 - KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. P233 – KEEP CONTAINER TIGHTLY CLOSED

Contains

CONTAINS; ALPHA-PINENE, THUJON, LIMONENE, CAMPHENE H224 FLAMMABLE LIQUID AND VAPOUR H302 HARMFUL IF SWALLOWED

Hazard statements

H304 MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. H317 MAY CAUSE AN ALLERGIC SKIN REACTION. H411 - TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.

Precautionary statements

P310 - IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. P403+P235 – STORE IN A WELL VENTILATED AREA. KEEP COOL. P501 - DISPOSE OF CONTENTS/CONTAINER TO REGIONAL, NATIONAL REGULATION. P301 + P310 – IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. P331 - DO NOT INDUCE VOMITING. NONE.

Further information

RISK & SAFETY PHRASES IN FULL

2.3 Other hazards

ADVERSE PHYSIO-CHEMICAL PROPERTIES NO DATA.

Potential Acute Health Effects

NO DATA. PBT OR VPVB ACCORDING TO ANNEX XIII OF NO DATA.

2.1 Classification of the substance or mixture

CLASSIFICATION OF THE SUBSTANCE OR MIXTURE THE FULL TEXT FOR ALL HAZARD STATEMENTS IS DISPLAYED IN SECTION 16. CLASSIFICATION (67/548/EEC) NO ADDITIONAL DATA AVAILABLE. ASPIRATION TOXICITY CATEGORY 1 - (H304). ACUTE TOXICITY ORAL 4 (H302) CLASSIFICATION (EU1272/2008) SKIN SENSITIZATION CATEGORY 1 - (H317). CHRONIC AQUATIC TOXICITY CATEGORY 2 - (H411). FLAMMABLE LIQUIDS CATEGORY 3 - (H226). 2.2 LABEL ELEMENTS LABEL IN ACCORDANCE WITH REGULATION (EC) NO 1272/2008. GHS LABEL GHS09 DANGER. SIGNAL WORD CONTAINS CONTAINS; ALPHA-PINENE, THUJON, LIMONENE, CAMPHENE H224 FLAMMABLE LIQUID AND VAPOUR H302 HARMFUL IF SWALLOWED HAZARDS STATEMENT H304 MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. H317 MAY CAUSE AN ALLERGIC SKIN REACTION. H411 - TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. SIGNAL WORD DANGER. P280 - WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION. P210 - KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. P233 – KEEP CONTAINER TIGHTLY CLOSED P310 - IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. PRECAUTIONARY STATEMENTS P403+P235 – STORE IN A WELL VENTILATED AREA. KEEP COOL. P501 - DISPOSE OF CONTENTS/CONTAINER TO REGIONAL, NATIONAL REGULATION. P301 + P310 – IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. P331 - DO NOT INDUCE VOMITING. NONE. SUPPLEMENTARY PRECAUTIONARY STATEMENTS SECTION 16 (OTHER INFORMATION): RISK & SAFETY PHRASES IN FULL. 2.3 OTHER HAZARDS NO DATA. ADVERSE PHYSIO-CHEMICAL PROPERTIES ADVERSE EFFECTS ON HUMAN HEALTH NO DATA. PBT OR VPVB ACCORDING TO ANNEX XIII SECTION 3: COMPOSITION OF INGREDIENTS 3-8% ALPHA-PINENE CAS-NO.: 80-56-8 EC NO.: 201-291-9 CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3 - H226, SKIN IRRIT. 2 - H315, SKIN SENS. 1 - H317, ASP. TOX. 1 - H304 7.00-19.00% THUJONE (ALPHA + BETA) CAS NO: 546-80-5 EC NO: 208-912-2 CLASSIFICATION (EC 1272/2008); ACUTE TOX 4 H302 3.1 SUBSTANCES 3-6% LIMONENE CAS-NO.: 5989-27-5 EC NO.: 227-813-5 CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3 – H226, SKIN IRRIT 2 – H315 ASP TOX. 1 – H304, SKIN SENS. 1 – H317 AQUATIC ACUTE 1 – H400, AQUATIC CHRONIC 1 – H410 ≤ 3.0% CAMPHENE CAS-NO 79-92-5, EC 201-234-8 CLASSIFICATION (EC 1272/2008); FLAM. SOL. 1 – H228, EYE IRRIT 2 – H319, AQUATIC ACUTE 1 – H400 3.2 MIXTURES NOT APPLICABLE. SECTION 4: FIRST AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES GENERAL INFORMATION ALWAYS REMOVE CONTAMINATED CLOTHING IMMEDIATELY. GET MEDICAL ATTENTION IMMEDIATELY. REMOVE FROM EXPOSURE SITE TO FRESH AIR, KEEP AT REST, AND OBTAIN MEDICAL INHALATION ATTENTION. GET MEDICAL ATTENTION IMMEDIATELY. IMMEDIATELY CALL THE DOCTOR. RINSE MOUTH WITH WATER AND OBTAIN MEDICAL INGESTION ATTENTION. REMOVE CONTAMINATED CLOTHES. WASH THOROUGHLY WITH SOAP AND WATER. CONTACT PHYSICIAN IF IRRITATION PERSISTS. SKIN CONTACT EYE CONTACT FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. CONTACT PHYSICIAN IF SYMPTOMS PERSIST. 4.2 OBSERVE RISK OF ASPIRATION IF VOMITING OCCURS. MOST IMPORTANT SYMPTOMS & EFFECTS (ACUTE & DELAYED) 4.3 INDICATION OF ANY IMMEDIATE MEDICAL NONE EXPECTED, SEE SECTION 4.1 FOR FURTHER INFORMATION. ATTENTION OR SPECIAL TREATMENT REQUIRED SECTION 5: FIRE FIGHTING MEASURES 5.1 FOAM, CO2, DRY CHEMICAL POWDER. EXTINGUISHING MATERIAL 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE BURNING PRODUCES IRRITATING, TOXIC AND OBNOXIOUS FUMES 5.3 SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS: ADVICE FOR FIRE-FIGHTERS WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND APPROPRIATE PROTECTIVE CLOTHING. SECTION 6: ACCIDENTAL RELEASE MEASURES ENSURE ADEQUATE VENTILATION OF THE WORKING AREA, EVACUATE PERSONNEL TO SAFE AREA, WEAR SUITABLE PROTECTIVE 6.1 EQUIPMENT. NO SMOKING, SPARKS, FLAMES OR OTHER SOURCES OF IGNITION NEAR SPILLAGE. AVOID CONTACT WITH SKIN, EYES PERSONAL PRECAUTIONS AND CLOTHING. AVOID INHALATION. 6.2 DO NOT DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND. DISPOSE OF IN LINE WITH LOCAL AUTHORITY ENVIRONMENTAL PRECAUTIONS GUIDELINES. REMOVE IGNITION SOURCES. PROVIDE ADEQUATE VENTILATION. AVOID EXCESSIVE INHALATION OF VAPOURS. 6.3 CONTAIN SPILLAGE IMMEDIATELY BY USE OF SAND OR INERT POWDER. DISPOSE OF ACCORDING TO LOCAL REGULATIONS. COVER METHODS & MATERIAL FOR CONTAINMENT AND WITH AN INERT, INORGANIC, NON-COMBUSTIBLE ABSORBENT MATERIAL (E.G DRY-LIME, SAND, SODA ASH). CLEANING UP 6.4 REFER & CONSIDER SECTION 12. REFERENCES TO OTHER SECTIONS SECTION 7: HANDLING & STORAGE HANDLE IN ACCORDANCE WITH GOOD HYGIENE AND SAFETY PRACTICE. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND HOT 7.1 SURFACES. - NO SMOKING. USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. PRECAUTIONS FOR SAFE-HANDLING USE IN ACCORDANCE WITH GOOD MANUFACTURING AND INDUSTRIAL HYGIENE PRACTICES. USE IN AREAS WITH ADEQUATE VENTILATION DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. 7.2 STORAGE CLASS: FLAMMABLE LIQUID STORAGE. STORE ONLY IN THE ORIGINAL RECEPTACLE. KEEP CONTAINER TIGHTLY SEALED. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY KEEP IN COOL, DRY, VENTILATED STORAGE AND CLOSED CONTAINERS. KEEP AWAY FROM HEAT. INCOMPATIBILITIES 7.3 RISK MANAGEMENT METHODS (RMM) SPECIFIC END USE(S) THE INFORMATION REQUIRED IS CONTAINED IN THIS MATERIAL SAFETY DATA SECTION 8: EXPOSURE CONTROLS & PERSONAL PROTECTION 8.1 NO DATA AVAILABLE. CONTROL PARAMETERS 8.2 EXPOSURE CONTROLS EYE PROTECTION WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. AVOID CONTACT WITH EYES. WEAR APPROVED SAFETY GOGGLES. (EN166) AVOID CONTACT WITH SKIN. WASH HANDS BEFORE BREAKS AND AT END OF WORK. WEAR PROTECTIVE GLOVES. DIN/EN 374. THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/ HAND PROTECTION THE SUBSTANCE/ THE PREPARATION. PENETRATION TIME OF GLOVE MATERIAL: THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED. RESPIRATORY EQUIPMENT DO NOT INHALE GASES / FUMES / AEROSOLS. CERTIFIED RESPIRATORY PROTECTIVE DEVICE RECOMMENDED. GOOD PERSONAL HYGIENE PRACTICES ARE ALWAYS ADVISABLE, ESPECIALLY WHEN WORKING WITH CHEMICALS HYGIENE MEASURES / OILS. ENGINEERING MEASURES NONE. SKIN PROTECTION WEAR PROTECTIVE CLOTHING TO REDUCE THE RISK OF SKIN AND EYE CONTACT. AVOID INHALATION OF THE PRODUCT. AVOID CONTACT WITH SKIN AND EYES. AVOID CONTACT WITH SKIN AND EYES. USE PERSONAL PROTECTION PERSONAL PROTECTION ACCORDING TO DIRECTIVE 89/686/EEC. OTHER PROTECTION WEAR SUITABLE PROTECTION TO AVOID CONTACT WITH SKIN AND EYES. DO NOT INHALE VAPOURS. PROCESS CONDITIONS ENSURE AREA IS WELL VENTILATED. AVOID VAPOUR INHALATION. SAFETY SHOWER & EYE BATH. ENVIROMENTAL EXPOSURE CONTROLS AVOID DISCHARGING INTO DRAINAGE WATER. SECTION 9: PHYSICAL & CHEMICAL PROPERTIES 9.1 PHYSICAL & CHEMICAL PROPERTIES APPEARANCE LIQUID COLOUR COLORLESS - PALE YELLOW ODOUR CHARACTERISTIC RELATIVE DENSITY @ 20°C 0.890 – 0.915 FLASH POINT (°C) 44 °C. REFRACTIVE INDEX @ 20 °C 1.46 – 1.47 SOLUBILITY IN WATER @ 20 °C INSOLUBLE IN WATER. SOLUBLE IN ETHANOL AT A RATIO OF 1:1 9.2 NO DATA. OTHER INFORMATION SECTION 10: STABILITY & REACTIVITY 10.1 NOT APPLICABLE. REACTIVITY 10.2 STABLE UNDER SUGGESTED STORAGE CONDITIONS (<15°C). STABLE UNDER CHEMICAL STABILITY NORMAL CONDITIONS. 10.3 NONE UNDER NORMAL PROCESSING. POSSIBILITY OF HAZARDOUS REACTIONS 10.4 STORAGE AT HIGH TEMPERATURES. DO NOT STORE ABOVE 15°C. AVOID HEAT, FLAMES AND OTHER SOURCES OF CONDITIONS TO AVOID IGNITION. 10.5 AVOID CONCENTRATED ACIDS, ALKALIS & OXIDISING AGENTS. INCOMPATIBLE MATERIALS 10.6 THIS PRODUCT DOES NOT DECOMPOSE UNDER NORMAL CONDITIONS. UNDER FIRE CONDITIONS THE PRODUCT WILL PRODUCE A HAZARDOUS DECOMPOSITION PRODUCTS MIXTURE OF IRRITATING FUMES & SMOKE & CARBON MONOXIDE. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 TOXICOLOGICAL EFFECTS ACUTE TOXICITY NO DATA. SKIN IRRITATION NO DATA. EYE DAMAGE OR IRRITATION NO DATA. RESPIRATORY OR SKIN SENSITIVITY NO DATA. GERM CELL MUTAGENICITY NO DATA. CARCINOGENICITY NO DATA. REPRODUCTIVE TOXICITY NO DATA. STOT – SINGLE EXPOSURE NO DATA. STOT – REPEATED EXPOSURE NO DATA. ASPIRATION HAZARD NO DATA. OTHER INFORMATION NO DATA. SECTION 12: ECOLOGICAL INFORMATION 12.1 NO DATA. TOXICITY 12.2 NO DATA. PERSISTENCE & DEGRADABILITY 12.3 NO DATA. BIO- ACCUMULATIVE POTENTIAL 12.4 NO DATA MOBILITY IN SOIL 12.5 NO DATA. RESULTS OF PBT & VPVB ASSESSMENT 12.6 NO DATA. OTHER ADVERSE EFFECTS SECTION 13: DISPOSAL INFORMATION 13.1 ALWAYS RECOVER SPILLED PRODUCT. DISCARD WASTE MATERIAL WITH AUTHORIZED WASTE MANAGEMENT WASTE TREATMENT METHODS SERVICES. ACT IN ACCORDANCE WITH LOCAL & NATIONAL WASTE REGULATIONS. SECTION 14: TRANSPORT INFORMATION 14.1 TRANSPORT INFORMATION ROAD: UN 1169 SEA: UN UN NUMBER 1169 AIR: UN 1169 14.2 EXTRACTS, AROMATIC, LIQUIDS UN SHIPPING NAME 3 FLAMMABLE LIQUID. 3 FLAMMABLE LIQUID. 3 ADR/RID/ADN CLASS: IMDG FLAMMABLE LIQUID. CLASS: ICAO CLASS/DIVISION: TRANSPORT LABELS: 14.3 TRANSPORT HAZARD CLASS(ES) ADR/RID/ADN PACKING GROUP III IMDG PACKING 14.4 GROUP III ICAO PACKING GROUP III PACKING GROUP ENVIRONMENTALLY HAZARDOUS / MARINE POLLUTANT. 14.5 ENVIROMENTAL HAZARDS 14.6 NONE. SPECIAL PRECAUTIONS FOR USER 14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 & THE IBC CODE. PACKED AND TRANSFERRED ACCORDING TO TRANSPORT. SECTION 15: REGULATORY INFORMATION